材料期刊网

1.重庆大学,材料科学与工程学院,重庆,400030

{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":4,"startPagecode":1},"records":[{"abstractinfo":"亲和配基的选择与筛选是发展新的亲和色谱填料或构建一个新的亲和色谱体系所必须解决的首要问题.该文结合作者所在实验室的工作,对配基的选择、筛选与应用方面的一些进展进行了简要评述.作者所在实验室针对特定蛋白质和多肽的多肽亲和配基的筛选,开展了反义肽简并性的研究,发展了基于反义肽的组合化学筛选新方法.与常规的组合合成法相比,该方法简单、快捷、有效,极大地减小了合成和筛选的工作量,降低了筛选后亲和组分结构鉴定的难度.所建立的筛选策略已应用于流感病毒、严重急性呼吸道综合征(SARS)病毒亲和抑制剂的筛选和用于人β-干扰素测定的石英晶体微天平(QCM)生物传感器的构建,均取得了有意义的结果.","authors":[{"authorName":"赵睿","id":"37895abf-685a-4ecd-b3ab-5c837f07c95d","originalAuthorName":"赵睿"},{"authorName":"刘国诠","id":"b35c9260-7ce8-45d3-a7c9-75a2a1973c2d","originalAuthorName":"刘国诠"}],"doi":"10.3321/j.issn:1000-8713.2007.02.004","fpage":"135","id":"504905c5-64ce-472b-b1ee-a1d1f1708740","issue":"2","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"b27ced42-adad-4156-84c7-2ac00fc82835","keyword":"亲和色谱","originalKeyword":"亲和色谱"},{"id":"953cda96-6b40-46b0-87d8-9f114dcb2431","keyword":"配基","originalKeyword":"配基"},{"id":"3ad3d216-c13f-47e1-8143-0730dcd234f2","keyword":"筛选","originalKeyword":"筛选"},{"id":"65f6b7cf-02e0-4ec6-ad5b-08e145468fd5","keyword":"应用","originalKeyword":"应用"}],"language":"zh","publisherId":"sp200702004","title":"亲和色谱中配基的筛选与应用","volume":"25","year":"2007"},{"abstractinfo":"以吡唑并[1,5-α]吡啶-3-甲醛和N-甲酰基哌嗪为原料,经过还原胺化、水解和N-烷基化反应,合成了3-(4-苄基哌嗪-1-基甲基)吡唑并[1,5-α]吡啶、3-[4-(4-氯苄基)哌嗪-1-基甲基]吡唑并[1,5-α]吡啶和3-[4-(4-甲氧基苄基)哌嗪-1-基甲基]吡唑并[1,5-α]吡啶,通过1H NMR、ESI MS等技术手段对中间体及3个目标化合物进行了表征,并通过体外受体结合实验,测定3个目标化合物对多巴胺D42受体的亲和常数(K)分别为1.6、7.2、65 nmol/L;对D2受体的亲和常数分别为1920、5320和9800 nmol/L;对D3受体的亲和常数分别为1710、4270和5600 nmol/L.结果表明,3-(4-苄基哌嗪-1-基甲基)吡唑并[1,5-α]吡啶对多巴胺D4受体具有较高的亲和性与选择性,是多巴胺D4受体潜在的配基.","authors":[{"authorName":"李谷才","id":"5f3abf72-2de1-4534-ba42-d58eadf5377f","originalAuthorName":"李谷才"},{"authorName":"孙磊","id":"f415f2fc-3916-43df-93ee-2c05ccda5e93","originalAuthorName":"孙磊"},{"authorName":"陈波","id":"e71b0991-3bd3-4243-b9f3-e1d84e9d1ffa","originalAuthorName":"陈波"},{"authorName":"钟怀玉","id":"78d8a436-10d6-4c36-ba9b-dfae73cfdcf2","originalAuthorName":"钟怀玉"}],"doi":"10.3724/SP.J.1095.2014.30428","fpage":"702","id":"149c818a-34d3-4b7f-8257-cb20bdd0a050","issue":"6","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"56b09411-2d9a-48b6-b471-34ca763d0e2f","keyword":"吡唑并[1,5-α]吡啶","originalKeyword":"吡唑并[1,5-α]吡啶"},{"id":"93563d6f-e4da-48b6-bccc-4a267b8ac0f7","keyword":"多巴胺D4受体","originalKeyword":"多巴胺D4受体"},{"id":"63fd0054-aae5-4dd1-a5af-55e225055156","keyword":"配基","originalKeyword":"配基"},{"id":"c9e10530-3707-49a3-9484-b4cdfe1a7ad0","keyword":"体外受体结合分析","originalKeyword":"体外受体结合分析"}],"language":"zh","publisherId":"yyhx201406012","title":"吡唑并[1,5-α]吡啶类化合物的合成及其体外受体结合分析","volume":"31","year":"2014"},{"abstractinfo":"在基因治疗中,质粒是一种常用的非病毒型载体.由于目前市场上对质粒的需求量很大,因此有必要开发大规模的质粒制备技术.该文以双孔型流通色谱介质为基质,以巯基吡啶为配基,制得了液相色谱固定相,并考察了其对质粒DNA的纯化效果,分析了分离机理.结果表明:该分离介质对质粒的纯化是基于疏水作用;当上样量为10 mL(质粒质量浓度为0.30 mg/mL)、流速高达4 mL/min时,质粒仍然能以100%的收率实现纯化,其纯度为100%.该色谱介质对RNA的柱容量高达2.2 mg/mL.","authors":[{"authorName":"李渊","id":"89b3a160-bd32-497e-b59b-c1e79e16cb78","originalAuthorName":"李渊"},{"authorName":"窦国胜","id":"47dd9527-28e8-4b8a-b872-85d3994dd3ff","originalAuthorName":"窦国胜"}],"doi":"10.3321/j.issn:1000-8713.2007.06.006","fpage":"820","id":"c75d1683-323b-4ecc-be31-a85eba592199","issue":"6","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"c3699dda-5b66-4710-b1af-9a0709fe9f2d","keyword":"巯基吡啶配基","originalKeyword":"巯基吡啶配基"},{"id":"b155e9ee-e3d4-4006-9d1d-1836d1a01155","keyword":"双孔型流通色谱固定相","originalKeyword":"双孔型流通色谱固定相"},{"id":"81c0eef6-09fb-4db7-9208-a8e2bc0b87e5","keyword":"质粒","originalKeyword":"质粒"},{"id":"8c2d2750-2649-49e1-a824-5f4a00077c2a","keyword":"快速纯化","originalKeyword":"快速纯化"}],"language":"zh","publisherId":"sp200706006","title":"巯基吡啶配基液相色谱固定相的制备及其对质粒的快速纯化","volume":"25","year":"2007"},{"abstractinfo":"以L-丝氨酸(Ser)为配基,1,6-己二胺为间隔臂,制备了一种新型PVDF中空纤维亲和膜用于人血浆中内毒素的脱除.通过FTIR、XPS对PVDF中空纤维膜,亲水化改性膜以及亲和膜的结构进行了表征;探讨了离子强度、pH值对亲和膜吸附内毒素能力的影响以及内毒素分子在亲和膜上的吸附动力学.实验考察了自制的亲和膜组件用于人血浆中内毒素的脱除效果.结果表明,亲和膜对内毒素的吸附能力为0.058 EU/cm2;自制的亲和膜组件对内毒素含量为0.42 EU/mL的人血浆样品清除率为43.8%;亲和膜对人血浆样品的其它生化指标的影响不大.","authors":[{"authorName":"徐堃","id":"cfd27b95-19da-490d-92e4-814e9a642ef2","originalAuthorName":"徐堃"},{"authorName":"黄曼","id":"0c55c01b-bd9e-4b70-bb19-ed72f9a7dcc2","originalAuthorName":"黄曼"},{"authorName":"吴礼光","id":"76ef7334-c532-48c0-93fd-c166045ffdf7","originalAuthorName":"吴礼光"},{"authorName":"徐秋萍","id":"5bb8a4c0-3cf5-401f-b699-a4a9d865d1ef","originalAuthorName":"徐秋萍"},{"authorName":"张林","id":"c66f50cf-34dc-4943-8eb5-c861c94a45f4","originalAuthorName":"张林"},{"authorName":"陈欢林","id":"d9df0c2d-e611-447a-b32a-d48ad4bcbccc","originalAuthorName":"陈欢林"}],"doi":"10.3969/j.issn.1007-8924.2011.02.006","fpage":"28","id":"8d56feeb-3c7b-4e05-bed5-ce88704266df","issue":"2","journal":{"abbrevTitle":"MKXYJS","coverImgSrc":"journal/img/cover/MKXYJS.jpg","id":"54","issnPpub":"1007-8924","publisherId":"MKXYJS","title":"膜科学与技术 "},"keywords":[{"id":"22a9c227-0fa9-4cab-98c3-d874e244fb0a","keyword":"内毒素","originalKeyword":"内毒素"},{"id":"43e4b3e8-d5d0-4373-9fb6-49f55b495912","keyword":"亲和膜","originalKeyword":"亲和膜"},{"id":"f036ac46-f68a-434b-905a-46178332888a","keyword":"PVDF","originalKeyword":"PVDF"},{"id":"ef5dda4d-47e4-4efb-b6bf-de0a5d475bbf","keyword":"丝氨酸","originalKeyword":"丝氨酸"},{"id":"754fbe96-c105-4835-b56a-af0c492a6e82","keyword":"人血浆","originalKeyword":"人血浆"}],"language":"zh","publisherId":"mkxyjs201102006","title":"丝氨酸配基PVDF亲和膜脱除人血浆中内毒素的研究","volume":"31","year":"2011"},{"abstractinfo":"以醋酸纤维滤棒为基质,染料Cibacron Blue F3GA为配基,合成了一种新的染料亲和介质;分别以牛血清白蛋白(BSA)和人血清白蛋白(HSA)为对象,用静态法进行了吸附实验,得到了相应的亲和等温吸附曲线;对曲线按Langmuir模型和Freundlich模型分别进行拟合;结果表明,醋酸纤维滤棒染料亲和介质对BSA和HSA的等温吸附遵循Freundlich模型.采用该亲和介质装柱并分离实际样品人血浆,可得到纯化的人血清白蛋白.","authors":[{"authorName":"李京华","id":"5eb30a65-2228-4747-8ad3-3252371189e5","originalAuthorName":"李京华"},{"authorName":"王俊德","id":"5cd92691-fb3c-40d6-8e04-8a9b3c9e8afa","originalAuthorName":"王俊德"},{"authorName":"刘学良","id":"b703b69a-7f3d-49d8-804b-622bb4848f9c","originalAuthorName":"刘学良"}],"doi":"10.3321/j.issn:1000-8713.2002.05.009","fpage":"419","id":"f16796c8-4335-4a22-a5fc-086098657e28","issue":"5","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"57eb9752-4893-4f0b-b6e5-d0702a3b5538","keyword":"醋酸纤维滤棒","originalKeyword":"醋酸纤维滤棒"},{"id":"9ad7419d-bdff-42af-bf5a-d885ca2ba3f9","keyword":"Cibacron Blue F3GA","originalKeyword":"Cibacron Blue F3GA"},{"id":"2511993a-18e5-4698-87fe-912fce2b36e7","keyword":"白蛋白","originalKeyword":"白蛋白"},{"id":"36c2683b-2b98-4afa-abe4-8d47e4cf1937","keyword":"亲和","originalKeyword":"亲和"},{"id":"fd7b16c4-0b22-4ee7-8dec-80c2ca8e51a4","keyword":"Freundlich模型","originalKeyword":"Freundlich模型"}],"language":"zh","publisherId":"sp200205009","title":"白蛋白在以染料为配基的醋酸纤维滤棒上的等温吸附行为","volume":"20","year":"2002"},{"abstractinfo":"通过几步大分子反应过程，将双齿席夫碱(SB)配基键合在聚苯乙烯(PS)侧链，制得了双齿席夫碱配基功能化的聚苯乙烯 PS-SB.使大分子配体PS-SB 与 Eu(Ⅲ)离子螯合配位，制备了二元高分子-稀土发光配合物 PS-(SB)3-Eu (Ⅲ)，也以邻菲罗啉(Phen)为小分子第二配体，制备了三元高分子-稀土发光配合物 PS-(SB)3-Eu(Ⅲ)-(Phen)1.研究结果表明，键合的双齿席夫碱(SB)配基兼具有螯合配位与传能敏化双重功能，所制备的高分子-稀土配合物均能发射出很强的 Eu(Ⅲ)离子的特征荧光.大分子配体 PS-SB 本身具有强的荧光发射，但与 Eu(Ⅲ)离子配位后，其自身的荧光发射大为减弱，通过配合物分子内能量转移，可强烈地敏化 Eu(Ⅲ)离子发光.","authors":[{"authorName":"徐迪","id":"9ffe5195-abe9-4cc6-85d3-1fcadbeb0b9e","originalAuthorName":"徐迪"},{"authorName":"陈萍虹","id":"ec557abb-4fbf-4407-b4f7-2b9a47440ac9","originalAuthorName":"陈萍虹"},{"authorName":"门吉英","id":"c0e712ef-5210-4035-a315-f582a1a7dd78","originalAuthorName":"门吉英"},{"authorName":"高保娇","id":"e6e31c24-bceb-4e12-89e9-247dcf0e77a7","originalAuthorName":"高保娇"}],"doi":"10.3969/j.issn.1001-9731.2015.22.005","fpage":"22027","id":"d2c39bb6-d2bc-4054-8774-bb1faf2788c9","issue":"22","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"11e51952-71f1-4cd5-b637-0b6d4e513dbf","keyword":"聚苯乙烯","originalKeyword":"聚苯乙烯"},{"id":"8180be57-ac3c-44f5-a9b1-2c37745fe372","keyword":"双齿席夫碱","originalKeyword":"双齿席夫碱"},{"id":"74b49251-ee70-4576-92dd-73c7848a1417","keyword":"高分子-稀土配合物","originalKeyword":"高分子-稀土配合物"},{"id":"f1c2b50b-5027-45e7-a222-542a9787442b","keyword":"Eu(Ⅲ)离子","originalKeyword":"Eu(Ⅲ)离子"},{"id":"8c0697dc-697d-452a-a3cc-633ebda5e487","keyword":"敏化作用","originalKeyword":"敏化作用"}],"language":"zh","publisherId":"gncl201522005","title":"双齿席夫碱配基功能化的聚苯乙烯与 Eu（Ⅲ）离子配合物的制备及其发光特性?","volume":"","year":"2015"},{"abstractinfo":"以硅胶为基质、氨基己酸为配基制备了一种新型弱阳离子交换/疏水(WCX/HIC)双功能混合模式色谱固定相.该固定相配基具有一定的疏水性且含有羧基,在高盐浓度下表现为HIC的性质,可作为HIC固定相使用;在低盐浓度条件下表现为离子交换的性质,可作为WCX固定相使用.分别考察了该介质在WCX和HIC两种模式下对标准蛋白质的分离性能,并与商品柱进行比较.结果表明,所合成的WCX/HIC双功能固定相在WCX和HIC两种模式下对蛋白质均有较高的分离度和选择性,且分离能力与商品柱相当,两种模式下标准蛋白质的质量和活性回收率均大于93％,表明该柱具有“一柱二用”的功能,适于生物大分子的分离纯化.基于此双功能色谱柱构建的在线单柱二维液相色谱(2DLC-1C)可在60 min内实现8种蛋白质的快速分离.在70 min内完成了对蛋清中溶菌酶的二维纯化,纯度可达到98.3％.该技术中一根色谱柱可当作两根色谱柱使用,对蛋白质组学研究和重组蛋白药物的生产具有重要的应用价值.","authors":[{"authorName":"王建山","id":"93233f29-979f-44c0-94a6-4ff7bca80045","originalAuthorName":"王建山"},{"authorName":"夏红军","id":"1ccee9ed-9d94-4e67-9552-5065ce1ea7d2","originalAuthorName":"夏红军"},{"authorName":"万广平","id":"c5385930-da67-49be-9ee8-6fc25eb2bdc1","originalAuthorName":"万广平"},{"authorName":"刘家玮","id":"67cb80ad-50ee-4d70-be45-166949470e51","originalAuthorName":"刘家玮"},{"authorName":"白泉","id":"90bbc3ec-91a1-4c6d-b92a-808a2cd59192","originalAuthorName":"白泉"}],"doi":"10.3724/SP.J.1123.2016.08019","fpage":"1228","id":"b599e099-06af-460a-b17b-edd63cf54832","issue":"12","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"637f4a98-6a2d-4d90-bf55-43aa8a04c41f","keyword":"固定相","originalKeyword":"固定相"},{"id":"0f3ef02b-fb26-473e-8cd5-2a1696907b58","keyword":"混合模式色谱","originalKeyword":"混合模式色谱"},{"id":"1d74ea30-47f6-4b75-8524-da012861956e","keyword":"离子交换色谱","originalKeyword":"离子交换色谱"},{"id":"1e2d2bff-c1d3-4e6d-bc83-d832b53adb6e","keyword":"疏水色谱","originalKeyword":"疏水色谱"},{"id":"9afb6512-3761-4142-8974-f24c24684229","keyword":"二维液相色谱","originalKeyword":"二维液相色谱"}],"language":"zh","publisherId":"sp201612015","title":"氨基己酸为配基的新型弱阳离子交换/疏水双功能色谱固定相对蛋白质的分离纯化","volume":"34","year":"2016"},{"abstractinfo":"以1,4-二氯甲氧基丁烷为氯甲基化试剂,制备了氯甲基化聚苯乙烯(CMPS),使CMPS的氯甲基与对羟基苯甲醛(HBA)发生亲核取代反应,将苯甲醛(BA)键合在聚苯乙烯侧链,制得改性聚苯乙烯PS-BA;使PS-BA的醛基与3-氨基吡啶(AP)的伯氨基发生席夫碱反应,在聚苯乙烯侧链合成与键合了双齿席夫碱(SB)配基,制得了侧链键合有双齿席夫碱配基的功能化聚苯乙烯PS-SB.采用红外光谱(FTIR)和核磁共振氢谱(1H NMR)对其结构进行了表征.以大分子PS-SB为第一配体,以邻菲罗啉(Phen)为第二配体,与Eu(Ⅲ)离子配位,分别制得了二元和三元高分子-稀土配合物PS-(SB)3-Eu(Ⅲ)和PS-(SB) 3-Eu(Ⅲ)-(Phen),初步探索了配合物的荧光发射性能.实验结果表明,对于CMPS与HBA之间的亲核取代反应,使用极性较强的N,N-二甲基乙酰胺为溶剂比较适宜,80℃为适宜的反应温度.大分子配体PS-SB对Eu(Ⅲ)离子的荧光发射可产生明显的敏化作用,二元和三元高分子-稀土配合物均发射出较强的Eu(Ⅲ)离子的特征荧光.","authors":[{"authorName":"徐迪","id":"f4eb7122-28ee-446a-a5e7-3ec6a654fd80","originalAuthorName":"徐迪"},{"authorName":"高保娇","id":"0c1d5826-e4ba-4358-a516-080aecf3352b","originalAuthorName":"高保娇"},{"authorName":"陈萍虹","id":"f0301515-7356-4f58-803e-4cf8c992210c","originalAuthorName":"陈萍虹"}],"doi":"10.11944/j.issn.1000-0518.2015.02.140176","fpage":"183","id":"fd4f8316-8f3c-4641-875d-1ba50cbd52c9","issue":"2","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"67772c80-5ecf-43df-b0de-861c8798b615","keyword":"聚苯乙烯","originalKeyword":"聚苯乙烯"},{"id":"feda25f8-28f8-4ad8-a434-73990651c6e4","keyword":"高分子-稀土配合物","originalKeyword":"高分子-稀土配合物"},{"id":"535cfa47-8c83-430e-8b47-54b96f05b0d5","keyword":"对羟基苯甲醛","originalKeyword":"对羟基苯甲醛"},{"id":"fde96e6c-1fce-4dac-8a0c-9375ff65040b","keyword":"氨基吡啶","originalKeyword":"氨基吡啶"},{"id":"74df80d7-0207-42f2-a77e-5e426fa22130","keyword":"双齿席夫碱配基","originalKeyword":"双齿席夫碱配基"},{"id":"ac056269-3b89-4b55-ac1a-405decae6f7f","keyword":"敏化作用","originalKeyword":"敏化作用"}],"language":"zh","publisherId":"yyhx201502009","title":"侧链键合双齿席夫碱配基的聚苯乙烯的制备与表征及其Eu(Ⅲ)配合物荧光发射性能之初探","volume":"32","year":"2015"},{"abstractinfo":"使氯甲基化聚砜(CMPSF)的氯甲基与乙醛酸(GA)的羧基发生酯化反应,将乙醛(AL)基团键合在聚砜侧链,制得改性聚砜PSF-AL;接着,又使3-氨基吡啶(AP)的伯氨基与PSF-AL的醛基发生席夫碱反应,在聚砜侧链合成与键合了具有特定结构的双齿席夫碱配基AA,从而获得了双齿席夫碱配基功能化聚砜PSF-AA,采用红外光谱(FTIR)和核磁共振氢谱(1H NMR)等技术手段对其结构进行了表征.以功能化聚砜PSF-AA为大分子配体,与Tb(Ⅲ)离子及Eu(Ⅲ)离子分别配位,制得了二元高分子-稀土配合物PSF-(AA)3-Tb(Ⅲ)和PSF-(AA) 3-Eu(Ⅲ),初步探索了两种配合物的光致发光性能.重点研究了功能化聚砜PSF-AA的制备反应,考察与分析了主要因素对CMPSF与GA之间酯化反应的影响规律,优化了反应条件.CMPSF与GA之间的酯化反应属氯烷的亲核取代反应,实验结果表明,适宜的溶剂为极性较强的N,Ⅳ-二甲基乙酰胺,75℃为适宜的反应温度.大分子配体PSF-AA对Eu(Ⅲ)离子不产生敏化作用,而对Tb(Ⅲ)离子的荧光发射则产生强烈的敏化作用,配合物PSF-(AA) 3-Tb(Ⅲ)发射出较强的Tb(Ⅲ)离子的特征荧光,即表现出发射绿光的光致发光性能.","authors":[{"authorName":"张丹丹","id":"ee2038d5-21ea-4dd4-829c-cb5c586d518f","originalAuthorName":"张丹丹"},{"authorName":"查显宇","id":"52c8b197-79ee-46b3-898e-3f0a9a67a98a","originalAuthorName":"查显宇"},{"authorName":"高保娇","id":"5d2d0dee-b3ed-4d93-bd28-153ced052b2a","originalAuthorName":"高保娇"}],"doi":"10.11944/j.issn.1000-0518.2016.01.150162","fpage":"53","id":"9119a8c9-156a-4f8f-bc47-f86cec103e85","issue":"1","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"339f85b5-51b3-4b5e-8950-1dad97a1ff61","keyword":"聚砜","originalKeyword":"聚砜"},{"id":"2fdbd12a-41b9-4d0b-ab41-405f300f58c3","keyword":"高分子-稀土配合物","originalKeyword":"高分子-稀土配合物"},{"id":"a051aced-28af-4871-8779-15244d3bb8ec","keyword":"双齿席夫碱配基","originalKeyword":"双齿席夫碱配基"},{"id":"130f7903-5a21-4ce1-b9c1-50c1f3117edb","keyword":"敏化作用","originalKeyword":"敏化作用"},{"id":"5393d4d7-19b8-4524-aa07-47b4be0523c6","keyword":"铽离子","originalKeyword":"铽离子"}],"language":"zh","publisherId":"yyhx201601007","title":"在聚砜侧链合成与键合双齿席夫碱配基及功能化聚砜-Tb(Ⅲ)离子配合物荧光发射性能初探","volume":"33","year":"2016"},{"abstractinfo":"","authors":[{"authorName":"刘晓川","id":"ad235d5f-35ff-420f-8a40-8c9592af548a","originalAuthorName":"刘晓川"}],"doi":"10.3321/j.issn:1000-8713.2006.01.020","fpage":"73","id":"a159f463-285a-47e4-9818-f7cc29b8ae70","issue":"1","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"b9bc1003-d054-482d-bf98-ce440416b5d0","keyword":"","originalKeyword":""}],"language":"zh","publisherId":"sp200601020","title":"硼酸作为亲和色谱配基的研究进展","volume":"24","year":"2006"}],"totalpage":4,"totalrecord":38}