聚对二氧环己酮（PPDO）是一种具有良好生物降解性和生物相容性的脂肪族聚酯醚，其独特的醚酯结构又赋予了材料高强度和良好的柔韧性，是一种理想的生物医用材料。综述了近年来针对PPDO单体合成、开环聚合、PPDO结构与性能，纳米复合、淀粉共聚等方面的相关研究成果。随着单体对二氧环己酮（PDO）合成技术的突破而导致成本的大幅度下降、PDO开环聚合可控性的实现以及PPDO纳米复合材料的原位合成对性能的有效改善，必将推进该聚合物在一次性使用塑料领域的广泛应用。
Poly（p-dioxanone） （ PPDO）, a kind of aliphatic poly（ester-ether） with good biodegradability, biocompatibilty and bioabsorbability, has been successfully used as biomaterials. Its excellent mechanical performance and unique recyclability make it a promising candidate for replacing the existing disposable plastic products. Synthesis, crystalline structures and properties of PPDO, especially the crystallization behavior, thermal stability and degradation, rheological behavior and mechanical properties of PPDO, are reviewed. PPDO/clay nanocomposites and PPDO/starch blends are also discussed.
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