欢迎登录材料期刊网

材料期刊网

高级检索

采用热分解法制备Ti/IrO2-HfO2二元氧化物涂层电极.通过X射线衍射(XRD)研究了不同Ir/Hf配比涂层的结构特征;采用循环伏安(CV)方法分析了不同电极涂层的比电容、“内/外活性”及电极稳定性,并初步讨论了电极稳定性与涂层结构间的关系.结果表明,添加Hf可改善涂层结构、提高比电容及电极稳定性、且当涂层中HfO2达到50 mol%时电极活性最高、稳定性最佳.

参考文献

[1] 白少金,魏宗平,王欣,邵艳群,唐电.添加纳米IrO2的新型涂层IrO2-Ta2O5钛阳极的制备及性能[J].中国有色金属学报,2011(03):669-674.
[2] Vazquez-Gomez L;Horvath E;Kristof J;Redey A;De Battisti A .Investigation of IrO2-SnO2 thin film evolution from aqueous media[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2006(3):1178-1184.
[3] Mario H P;Santana;Luiz A .De Faria.Oxygen and chlorine evolution on RuO2 + TiO2 + CeO2 + Nb2O5 mixed oxide electrodes[J].Electrochimica Acta,2006,51(17):3578-3585.
[4] Trasatti S .Electrocatalysis:understanding the success of DSA(R)[J].Electrochimica Acta,2000,45(15/16):2377-2385.
[5] Hou Y Y;Hu J M;Liu L et al.Effect of calcination temperature on electrocatalytic activities of Ti/IrO2 electrodes in methanol aqueous solutions[J].Electrochimica Acta,2006,51(28):6258-6267.
[6] Hu J M;Zhang J Q;Meng H M et al.Electrochemical activity,stability and degradation characteristics of IrO2-based electrodes in aqueous solutions containing C1 compounds[J].Electrochimica Acta,2005,50(27):5370-5378.
[7] LI Baosong,LIN An,GAN Fuxing.Improvement of stability of trivalent chromium electroplating of Ti based IrO2+Ta2O5 coating anodes[J].稀有金属(英文版),2006(z1):645-649.
[8] D.Rajkumar;Byung Joo Song;Jong Guk Kim .Electrochemical degradation of Reactive Blue 19 in chloride medium for the treatment of textile dyeing wastewater with identification of intermediate compounds[J].Dyes and Pigments,2007(1):1-7.
[9] C. P.De Pauli;S. Trasatti .Composite materials for electrocatalysis of O_2 evolution: IrO_2 + SnO_2 in acid solution[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,2002(0):145-151.
[10] Kristóf J;Mink J;Battisti et al.Emission FTIR studies on the formation mechanism of IrO2/TiO2 based coatings[J].Electrochimica Acta,1994,39(11-12):1531-1535.
[11] Benedetti A;Riello P;Battaglin G et al.Physicochemical properties of thermally prepared Ti-supported IrO2 + ZrO2 electrocatalysts[J].Journal of Electroanalytical Chemistry,1994,376(1-2):195-202.
[12] Terezo A J;Pereira E C .Fractional factorial design applied to investigate properties of Ti/IrO2-Nb2O5 electrodes[J].Electrochimica Acta,2000,45(25-26):4351-4358.
[13] Ye Z G;Meng H M;Sun D B .New degradation mechanism of Ti/IrO2 + MnO2 anode for oxygen evolution in 0.5M H2SO4 solution[J].Electrochimica Acta,2008,53(18):5639-5643.
[14] 李贝贝,邵艳群,朱君秋,唐电.Ti/Ir0.4Sn0.6O2电极材料的电容性能[J].材料热处理学报,2012(02):17-20.
[15] Jia-Jia Zhang;Ji-Ming Hu;Jian-Qing Zhang;Chu-Nan Cao .IrO2-SiO2 binary oxide films: Geometric or kinetic interpretation of the improved electrocatalytic activity for the oxygen evolution reaction[J].International journal of hydrogen energy,2011(9):5218-5226.
[16] Wang J;Li H P;Stevens R .Hafnia and hafnia-toughened ceramics[J].Journal of Materials Science,1992,27(20):5397-5430.
[17] Li C W;McKerns M M;Fultz B .A Raman spectrometry study of shonon anharmonicity of zirconia at elevated temperatures[J].Journal of the American Ceramic Society,2011,94(01):224-229.
[18] 王欣,魏宗平,唐电.添加Sn制备三元IrO2-Ta2O5-SnO2/Ti涂层[J].材料热处理学报,2010(09):104-106.
[19] S. Siracusano;V. Baglio;A. Stassi;R. Ornelas;V. Antonucci;A.S. Arico .Investigation of IrO_2 electrocatalysts prepared by a sulfite-couplex route for the O_2 evolution reaction in solid polymer electrolyte water electrolyzers[J].International journal of hydrogen energy,2011(13):7822-7831.
[20] Pourbaix M.Atlas of Electrochemical Equilibria in Aqueous Solutions(2nd Edition)[M].Houston USA:National Association of Corrosion Engineers,1974
[21] de Oliveira-Sousa A;da Silva M A S;Machado S A S et al.Influence of the preparation method on the morphological and electrochemical properties of Ti/IrO2-coated electrodes[J].Electrochimica Acta,2000,45(27):4467-4473.
[22] Grupioni A A F;Arashiro E;Lassali T A F .Voltammetric characterization of an iridium oxide-based system:the pseudocapacitive nature of the Ir0.3Mn0.7 O2 electrode[J].Electrochimica Acta,2002,48(04):407-418.
[23] Ardizzone S;Fregonara G;Trasatti S ."Inner" and "outer" active surface of RuO2 electrodes[J].Electrochimica Acta,1990,35(01):263-267.
[24] Justin C. Hackley;Theodosia Gougousi .Properties of atomic layer deposited HfO_2 thin films[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2009(24):6576-6583.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%