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荧光粉的发光性能对其形貌非常敏感,特别是荧光粉的尺寸.场发射显示器所需的荧光粉应是微米级的球状,然而可控的微米级荧光粉受到很少的关注.因此,本实验通过改进的共沉淀法制备合成了几微米的近球型红色Y2O3:Eu3+荧光粉.该产品在1050℃,pH值为5.5时,形貌均匀,粒径分布为0.9~3.1 μm,且发光亮度较商用的增加50%以上.结果表明,通过改良的共沉淀法可以制备出一种高质量的FED荧光粉.

参考文献

[1] Hirai T.;Komasawa I.;Hirano T. .Preparation of Y2O3 : Eu3+ phosphor fine particles using an emulsion liquid membrane system[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2000(10):2306-2310.
[2] Yoo JS.;Lee JD. .THE EFFECTS OF PARTICLE SIZE AND SURFACE RECOMBINATION RATE ON THE BRIGHTNESS OF LOW-VOLTAGE PHOSPHOR[J].Journal of Applied Physics,1997(6):2810-2813.
[3] Wang, LL;Hou, ZY;Quan, ZW;Li, CX;Yang, J;Lian, HZ;Yang, PP;Lin, J .One-Dimensional Ce3+- and/or Tb3+-Doped X-1-Y2SiO5 Nanofibers and Microbelts: Electrospinning Preparation and Luminescent Properties[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2009(14):6731-6739.
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