在含硅酸钠10g/L、六偏磷酸钠2g/L、柠檬酸钠2g/L和添加剂4 g/L的电解液中,以微弧氧化技术在Ti75钛合金的表面成功制备了微弧氧化膜.采用涡流测厚仪、扫描电镜、X射线衍射仪、显微硬度计等手段研究了微弧氧化电压和时间对钛合金微弧氧化膜厚度的影响,分析了氧化膜层的表面形貌、组成、硬度、耐蚀性能及高温性能.结果表明,微弧氧化膜层主要由金红石型和锐钛矿型二氧化钛组成.氧化电压升高,膜层厚度增加;氧化时间延长,初期膜层厚度增加明显,20 min后膜厚增加减缓.经微弧氧化处理后,钛合金的硬度、耐蚀性能和高温抗氧化性能均得到了明显改善.
参考文献
[1] | 唐元广 .TC4钛合金微弧氧化膜的制备表征及阴极微弧放电机制研究[D].长春:吉林大学,2009. |
[2] | 张毅斌.船用钛合金表面改性技术研究进展[J].材料开发与应用,2009(05):70-74. |
[3] | Zhecheva A;Sha W;Malinov S;Long A .Enhancing the microstructure and properties of titanium alloys through nitriding and other surface engineering methods[J].Surface & Coatings Technology,2005(7):2192-2207. |
[4] | Sundaram VS .Diamond like carbon film as a protective coating for high strength steel and titanium alloy[J].Surface & Coatings Technology,2006(6):2707-2711. |
[5] | Tian YS;Chen CZ;Li ST;Huo QH .Research progress on laser surface modification of titanium alloys[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2005(1/2):177-184. |
[6] | 张永忠,黄灿,MEACOCK Chris,VILAR Rui.TA15钛合金表面激光熔化沉积Ti-Cr二元合金涂层[J].金属热处理,2010(01):67-72. |
[7] | 刘天国,张海金.钛及钛合金阳极氧化[J].航空精密制造技术,2004(04):17-18,22. |
[8] | 孙志华,刘佑厚,张晓云,汤智慧,刘明辉.钛及钛合金的电镀工艺述评[J].腐蚀与防护,2005(11):493-496. |
[9] | BRUNELLI K;DABALA.M;DUGHIERO F et al.Diffusion treatment of Ni-B coatings by induction heating to harden the surface of Ti-6Al-4V alloy[J].Materials Chemistry and Physics,2009,115(01):467-472. |
[10] | S.S. Mahmoud .Electroless deposition of nickel and copper on titanium substrates: Characterization and application[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2009(1/2):595-601. |
[11] | 杨青松,董作敬,李平.钛合金微弧氧化技术在修造船中的应用[J].中国修船,2010(04):22-25. |
[12] | GNEDENKOV S V;GORDIENKO P S;S1NEBRYUKHOV S L et al.Antiscuff coatings obtained by microarc oxidation of titanium alloys[J].Russian Journal of Applied Chemistry,2000,73(01):6-9. |
[13] | 宾远红,刘英,李卫,郑洋.ZE10镁合金微弧氧化膜层的制备及耐蚀性研究[J].电镀与涂饰,2011(05):35-38. |
[14] | 冯君艳 .AZ91D镁合金微弧氧化膜耐蚀性表征方法的对比研究[D].兰州理工大学,2010. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%