欢迎登录材料期刊网

材料期刊网

高级检索

本文选取三个煤样,在滴管炉(DTF)上制取了五种焦样,应用差示扫描量热(DSC)法对其在70~500℃的比热容进行了测定,并与根据经典煤焦比热模型计算得到的数值进行了比较.实验煤焦比热容的实验值与计算值都随温度升高单调增加,从70℃的0.9 kJ/(kg·K)左右增大到500℃时的1.4~1.7 kJ/(kg·K)左右,一般实验值要略大于理论值.1100℃下的焦样,比热容均比1300℃下的焦样要大,且原煤中挥发分含量Vdaf越高,对应的两个热解温度水平下的焦样的比热值相差越大.

参考文献

[1] Eisermann W;Johnson P;Conger W L .Estimating Thermodynamic Properties of Coal,Char,Tar and Ash[J].Fuel Processing Technology,1980,3(01):39-53.
[2] David Marrick .Mathematical Models of the Thermal De-composition of Coal[J].Fuel,1983,62(05):540-546.
[3] Danniel J Maloney;Ramanathan Sampath .Heat Capac-ity and Thermal Conductivity Considerations for Coal-Particles During the Early Stages of Rapid Heating-[J].Combustion and Flame,1999,116:94-104.
[4] Jerzy Tomeczek;Henryk Palugniok .Specific Heat Capae-ity and Enthalpy of Coal Pyrolysis at Elevated Tempera-tures[J].Fuel,1996,75(09):1089-1093.
[5] Heidenreich C.A.;Zhang D.K.;Yan H.M. .Mathematical modelling of pyrolysis of large coal particles - estimation of kinetic parameters for methane evolution[J].Fuel,1999(5):557-566.
[6] 郑嘉明;阮湘泉;郭崇涛 .DSC法测定煤的比热[J].煤化工,1996,75(02):18-21.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%