本文采用TG-DSC、XRD及TEM等表征手段,系统研究软研磨处理对拜耳石的微结构及热解行为的影响.结果表明,软研磨减小拜耳石晶粒尺寸、引起它的晶格畸变、加速拜耳石向热稳定相的转变.相比于未经研磨的拜耳石,软研磨处理使得拜耳石热解时向热稳定相α-Al2O3开始转变及转化完成的温度分别降低了800℃和150℃,热解过程未出现θ-Al2O3过渡态,而是经历α-Al(OH)3→γ-AlOOH→γ-Al2O3→α-Al2O3晶型转变途径.也即,软研磨处理明显降低了拜耳石向稳定相α-Al2O3转变的热解温度,改变其热解途径.
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