将环氧树脂与丙烯酸酯类单体、有机硅接枝共聚,制得有机硅/环氧改性水性丙烯酸树脂.在采用傅里叶红外光谱(FT-IR)对聚合物结构表征的基础上,采用动态光散射粒径仪(DLS)、热重分析仪(TGA)及原子力显微镜(AFM)对共聚物的水分散体及其涂膜进行了分析表征;同时考察了引发剂偶氮二异丁腈用量、环氧树脂加料方式及用量、有机硅用量等因素对乳液和涂膜性能的影响.结果表明:当引发剂用量为3％(占丙烯酸单体总质量,下同),环氧树脂(E-44)用量为4％,有机硅用量为3％时,合成的水性树脂乳液呈白色泛蓝光,具有良好的贮存稳定性,且涂膜的附着力、硬度、耐水性及耐热性等良好.
参考文献
| [1] | Schauer E.;Berglund L.;Pena G.;Marieta C.;Mondragon I..Morphological variations in PMMA-modified epoxy mixtures by PEO addition[J].Polymer: The International Journal for the Science and Technology of Polymers,20024(4):1241-1248. |
| [2] | Yen, MS;Tsai, PY.Effects of Soft Segments on the Surface Properties of Polydimethylsiloxane Waterborne Polyurethane Prepolymer Blends and Treated Nylon Fabrics[J].Journal of Applied Polymer Science,20106(6):3550-3558. |
| [3] | 温振华;张三平;周婵;田丰;胡章枝.有机硅氧烷改性丙烯酸乳液合成及性能研究[J].涂料工业,2011(8):61-63,79. |
| [4] | 南璇;张保利;孔志元;朱柯;殷武;何庆迪;史立平.有机硅丙烯酸乳液的混拼研究[J].涂料工业,2003(6):25-26. |
| [5] | M. Mazurek;D. J. Kinning;T. Kinoshita.Novel Materials Based on Silicone-Acrylate Copolymer Networks[J].Journal of Applied Polymer Science,20012(2):159-180. |
| [6] | Hong-Soo Park;In-Mo Yang;Jong-Pyo Wu;Myung-Soo Kim;Hyun-Sik Hahm;Seong Kil Kim;Hee-Woo Rhee.Synthesis of Silicone-Acrylic Resins and Their Applications to Superweatherable Coatings[J].Journal of Applied Polymer Science,20017(7):1614-1623. |
| [7] | Yu-Chin Lai;Edmond T. Quinn;Paul L. Valint Jr..Silicone hydrogels based on methacrylate-capped multi-block polyurethanepolysiloxane prepolymers[J].Polymer Preprints,20011(1):217-218. |
| [8] | Guillaume Tillet;Bernard Boutevin;Bruno Ameduri.Chemical reactions of polymer crosslinking and post-crosslinking at room and medium temperature[J].Progress in Polymer Science,20112(2):191-217. |
| [9] | 孙兴春;邱藤;李效玉.A-172/丙烯酸酯接枝改性水性环氧树脂的制备与性能[J].北京化工大学学报（自然科学版）,2010(2):59-64. |
| [10] | 刘文艳;孙建中;周其云.有机硅改性水性环氧树脂的合成与表征[J].高校化学工程学报,2007(6):1044-1048. |
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