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采用等电位空心阴极辉光放电技术对纯钛进行W-Mo二元共渗,通过扫描电子显微镜(SEM)、能谱仪(EDS)、X射线衍射仪(XRD)、显微硬度计对试样的结构形貌、渗层成分分布及相组成、硬度进行研究.利用摩擦磨损试验仪对试样的摩擦学性能进行研究,利用电化学腐蚀工作站,研究了W-Mo合金渗层在常温静态条件下,在3.5% NaCl腐蚀介质中的耐蚀性能.结果表明,经W-Mo共渗处理后纯钛表面形成了一层均匀致密的W-Mo改性层,渗层最大厚度达到16.6 μm,最大硬度达到1196HV0.1,是基体的6.85倍.W-Mo共渗后改性层主要由W、Mo、MoTi、TixW1-x相组成.由于表面硬度的大幅提升,试样表面的耐磨性也显著提高,最低摩擦系数仅为0.23,较原始试样的0.516明显减小.测得的试样最低腐蚀速率为0.0016 mm/a,是原始试样的1/230,耐蚀性能也显著提高.

参考文献

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