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在氩气保护下将ZnS与KCl的混合粉体焙烧合成了ZnS基蓝光粉,并研究了焙烧温度及KCl添加量对荧光粉蓝光性能的影响.结果表明,在337nm波长的紫外光激发下,该荧光粉发射峰位于464nm,呈蓝光,随着焙烧温度的升高或KCl添加量的增大,荧光粉发光强度均呈现先增大后减小的变化规律;当焙烧温度为900℃、KCl添加量为10%(原子分数)时荧光粉的蓝光最强.

ZnS based phosphor with blue emission is fabricated via sintering the mixture of ZnS and KCl in Ar. The sintering temperature and additive level of KCl which will affect the blue emission of the powders are studied.The experimental results indicate that the intensity of blue emission which has a wavelength of 464nm under an excitation wavelength of 337nm increases firstly and then drops with the increase of the sintering temperature and additive level of KCl,and the optimum sintering temperature and additive level of KCl obtained from experiment are 900℃ and 10at%.

参考文献

[1] Arul Dhas N;Zaban A;Gedanken A .Surface synthesis of zinc sulfide nanoparticles on silica micropheres:sonochemical preparation,characterization and optical properties[J].CHEMISTRY OF MATERIALS,1999,11(03):806.
[2] 张海明,王之建,张力功,李玉琴,元金山.化学合成法制备ZnS基纳米荧光粉研究[J].无机材料学报,2002(06):1147-1151.
[3] 唐春玖,朱文清,赵伟明,刘祖刚,蒋雪茵,张志林,许少鸿.以陶瓷厚膜为绝缘层的红色ZnS:Sm,Cl电致发光器件[J].光学学报,1999(10):1430-1432.
[4] 谢相伟 .ZnS:Sm,F红色ACTFEL器件[J].光电子技术,1994,14(02):138.
[5] Hillie K T;Swart H C .Electron beam induced degradation of a pulsed laser deposited ZnS:Cu,Au,Al thin film on a Si(100) substrate[J].Applied Surface Sinence,2001,183(3-4):304.
[6] Hua RN;Niu JH;Li MT;Yu TZ;Li WL .Electroluminescent properties of device based on ZnS : Tb/CdS core-shell nanocrystals[J].Chemical Physics Letters,2006(1-3):269-272.
[7] Souriau JC.;Penczek J.;Paris HG.;Summers CJ.;Jiang YD. .Cathodoluminescent properties of coated SrGa2S4 : Eu2+ and ZnS : Ag,Cl phosphors for field emission display applications[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2000(2):165-168.
[8] 李岚,张东,熊光楠,姜春香,张飒飒.蓝色低压阴极射线荧光粉ZnS:Zn,Pb的研究[J].发光学报,1997(04):286-288.
[9] 张华.蓝色荧光硫化锌材料的制备及其发光特性[J].山东理工大学学报(自然科学版),2006(06):93-96.
[10] Craig M. Davis;Kelly A. Curran .Manipulation of a Schlenk Line: Preparation of Tetrahydrofuran Complexes of Transition-Metal Chlorides[J].Journal of Chemical Education,2007(11):1822-1823.
[11] Xue L A;Raj R .Superplastic deformation of zinc sulfide near its transformation temperature(1020℃)[J].Journal of the American Ceramic Society,1989,72(10):1792.
[12] Era K;Shionoya S;Washizawa Y .Mechanism of broad-band luminescences in ZnS phosphors-Ⅰ.Spectrum shift during decay and with excitation intensity[J].Journal of Physics and Chemistry of Solids,1968,29(10):1827.
[13] Georgobiani A N;Maev R G;Ozerov Yu V et al.Investigation of deep centers of chlorine doped zinc sulfide crystals[J].Phys Status Solidi(a),1976,38(01):77.
[14] Jong-Chan Lee;Dae-Hee Park .Self-defects properties of ZnS with sintering temperature[J].Materials Letters,2003(19):2872-2878.
[15] 里耳 N.硫化锌发光体的结构[M].北京:科学出版社,1965:21.
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