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表面金属化的聚合物因其卓越的综合性能广泛应用于多个领域,但聚合物表面金属化过程中通常会出现金属薄膜与基底材料附着力较差的问题,限制了其实际应用.为解决这一问题,多种表面改性技术被用来对聚合物的表面性质进行修饰.文中探讨了聚合物上金属薄膜附着力较差的原因并介绍了目前用以改善薄膜附着力的聚合物表面改性技术的研究进展,比较了离子注入、等离子体处理、离子束辐照、化学法、光化学法及准分子激光刻蚀等不同技术的改性效果和改性机理,对工业化应用需要克服的问题和研究方向也作了展望.

参考文献

[1] W. Xu;J.S. Yang;T. J. Lu .Ductility of thin copper films on rough polymer substrates[J].Materials & design,2011(1):154-161.
[2] Won-Seock Kim;Il-Han Yun;Jung-Ju Lee .Evaluation of mechanical interlock effect on adhesion strength of polymer-metal interfaces using micro-patterned surface topography[J].International Journal of Adhesion & Adhesives,2010(6):408-417.
[3] S. Kisin;F. Scaltro;P. Malanowski;P. G. Th. van der Varst;G. de With .Chemical and structural changes at the ABS polymer—copper metal interface[J].Polymer Degradation and Stability,2007(4):605-610.
[4] 高原,邢安,殷军港,秦晓刚,刘惠涛.高分子基材料表面改性研究进展[J].高分子材料科学与工程,2012(06):172-175.
[5] S.W. Lee;J.W. Hong;M.Y. Wye;J.H. Kim;H.J. Kang;Y.S. Lee .Surface modification and adhesion improvement of PTFE film by ion beam irradiation[J].Nuclear Instruments and Methods in Physics Research, Section B. Beam Interactions with Materials and Atoms,2004(0):963-967.
[6] Kim SH;Na SW;Lee NE;Nam YW;Kim YH .Effect of surface roughness on the adhesion properties of Cu/Cr films on polyimide substrate treated by inductively coupled oxygen plasma[J].Surface & Coatings Technology,2005(7):2072-2079.
[7] Sanchis MR;Blanes V;Blanes M;Garcia D;Balart R .Surface modification of low density polyethylene (LDPE) film by low pressure O-2 plasma treatment[J].European Polymer Journal,2006(7):1558-1568.
[8] Chan-Hee Jung;Hwang-Woo Cho;In-Tae Hwang .The effects of energetic ion irradiation on metal-to-polymer adhesion[J].Radiation Physics and Chemistry,2012(8):919-922.
[9] Chaiwong C;McKenzie DR;Bilek MMM .Study of adhesion of TiN grown on a polymer substrate[J].Surface & Coatings Technology,2007(15):6742-6744.
[10] A. Pundt;E. Nikitin;P. Pekarski;R. Kirchheim .Adhesion energy between metal films and polymers obtained by studying buckling induced by hydrogen[J].Acta materialia,2004(6):1579-1587.
[11] Guzman L.;Voltolini E.;Adami M.;Miotello A. .Hard coating adhesion on ion implanted polymer surfaces[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2000(0):760-765.
[12] 周固,吴瑜光,张通和,赵新荣.Ti离子注入聚合物纳米结构分析[J].北京师范大学学报(自然科学版),2001(02):183-186.
[13] 吴瑜光,张通和,刘安东,张旭,周固.硅离子注入聚合物表面改性的研究[J].中国科学E辑,2003(01):42-46.
[14] 吴瑜光,张通和,张荟星,张孝吉,王广甫.磁过滤阴极真空弧沉积薄膜研究[J].微细加工技术,2001(01):45-49.
[15] Junkar, I;Vesel, A;Cvelbar, U;Mozetic, M;Strnad, S .Influence of oxygen and nitrogen plasma treatment on polyethylene terephthalate (PET) polymers[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,2009(1):83-85.
[16] Lin YS;Liu HM;Chen CL .Plasma surface modification of polyimide films by air glow discharge for copper metallization on microelectronic flex substrates[J].Surface & Coatings Technology,2006(12/13):3775-3785.
[17] Zaporojtchenko V;Zekonyte J;Faupel F .Effects of ion beam treatment on atomic and macroscopic adhesion of copper to different polymer materials[J].Nuclear Instruments and Methods in Physics Research, Section B. Beam Interactions with Materials and Atoms,2007(1):139-145.
[18] Peng Yang;Jian Yuan Deng;Wan Tai Yang .Confined photo-catalytic oxidation:a fast surface hydrophilic modification method for polymeric materials[J].Polymer: The International Journal for the Science and Technology of Polymers,2003(23):7157-7164.
[19] Kim GG;Kang JA;Kim JH;Kim SJ;Lee NH;Kim SJ .Metallization of polymer through a novel surface modification applying a photocatalytic reaction[J].Surface & Coatings Technology,2006(6):3761-3766.
[20] Wei Chen;Junying Zhang;Qi Fang;Keliang Hu;Ian W. Boyd .Surface modification of polyimide with excimer UV radiation at wavelength of 126 nm[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2004(4):3-6.
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