采用激光加工在Ti6Al4V试样表面加工不同间距的点阵结构,采用自组装技术制备4种自组装分子膜.通过表面形貌和接触角的测量表征试样的表面特性.结果表明:通过激光点阵加工和沉积自组装分子膜,可显著增加Ti6Al4V试样的水接触角.长链分子FDTS、FOTS和OTS制备的自组装分子膜,使Ti6Al4V试样的接触角均大于150°,形成超疏水表面,其中沉积FDTS自组装分子膜时,试样的接触角最大,可达164.5°.沉积短链分子MPS自组装分子膜时,只有当激光加工间距为50μm时,试样方可形成超疏水表面；间距增大后,试样表面变成疏水表面.沉积4种自组装分子膜时,试样的接触角均随激光点阵加工间距的增大而减小.
参考文献
| [1] | Lineberger L .[J].Current Advances in Materials and Processes,1998,5:45. |
| [2] | 孟祥军,时锦.漫谈钛合金在舰船上的应用[J].钛工业进展,2003(04):23-26. |
| [3] | Gloance A L;Henaff G;Bertheau D et al.[J].Scripta Materialia,2003,49(09):825. |
| [4] | Nakajma K;Terao K;Miyata T.[J].Materials Science and Engineering,1998(A243):176. |
| [5] | Cottin-Bizonne C;Barrat J L;Bocquet L et al.[J].Nature Materials,2003,2:237. |
| [6] | Jiang L. .Binary cooperative complementary nanoscale interfacial materials[J].Pure and Applied Chemistry,2000(1/2):73-81. |
| [7] | Song X;Zhai J;Wang Y et al.[J].Journal of Physical Chemistry B,2005,109(09):4048. |
| [8] | 李艳峰,于志家,于跃飞,霍素斌,宋善鹏.铝合金基体上超疏水表面的制备[J].高校化学工程学报,2008(01):6-10. |
| [9] | 屈孟男 .[D].兰州:兰州大学,2008. |
| [10] | Spori D M;Venkataraman N V;Tosatti S G P et al.[J].Langmuir,2007,23(15):8053. |
| [11] | Wenzel R N .[J].In dEng Chem,1936,28:988. |
| [12] | Cassie A B;Baxter S .[J].Transactions of the Faraday Society,1944,40:546. |
| [13] | Marmur A .From hygrophilic to superhygrophobic: Theoretical conditions for making high-contact-angle surfaces from low-contact-angle materials[J].Langmuir: The ACS Journal of Surfaces and Colloids,2008(14):7573-7579. |
| [14] | 柯清平,李广录,郝天歌,何涛,李雪梅.超疏水模型及其机理[J].化学进展,2010(02):284-290. |
| [15] | Herminghaus S. .Roughness-induced non-wetting[J].EPL,2000(2):165-170. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%