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通过改变镀液还原剂的含量和加入定量的乙酸钠,研究对化学镀镍硼合金形貌和性能的变化。从晶体结构、镀层形貌、硬度和耐磨曲线等几方面来分析加入乙酸钠12g/L时,化学镀Ni—B合金镀层形貌和性能改善的原因。乙酸钠起到缓冲剂的作用,降低了化学镀Ni—B的镀速,提高了化学镀Ni-B的致密度,改善了镀层的质量从而提高镀层的各种性能。

In order to enhance the properties of electroless Ni-B, the changes in morphology and performance of electroless Ni-B alloy was studied by changing the contents of reducing agent and adding quantitative sodium acetate. The reasons of the morphology and performance of the electroless Ni-B were improved while adding sodium acetate 12 g/L are analyzed based on crystal structure, coating morphology, hardness, wear curves. It was found that sodium acetate as a buffer can reduce the deposition rate of the chemical plating Ni-B, increase the density of the chemical plating Ni-B, and improve the quality of coating in the process.

参考文献

[1] Lo YL.;Hwang BJ. .KINETICS OF ETHANOL OXIDATION ON ELECTROLESS NI-P/SNO2/TI ELECTRODES IN KOH SOLUTIONS[J].Journal of the Electrochemical Society,1995(2):445-450.
[2] Wang DQ.;Shi ZY.;Zou LJ. .A liquid aluminum corrosion resistance surface on steel substrate[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2003(1/4):304-311.
[3] Narayanan TSNS.;Krishnaveni K.;Seshadri SK. .Electroless Ni-P/Ni-B duplex coatings: preparation and evaluation of microhardness, wear and corrosion resistance[J].Materials Chemistry and Physics,2003(3):771-779.
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