欢迎登录材料期刊网

材料期刊网

高级检索

利用溶液共混法成功制得聚酰胺46(PA46)/氧化石墨烯(GO)纳米复合材料.通过透射电镜观察得到氧化石墨烯在聚酰胺46中的纳米尺度的分散情况,差示扫描量热法的测试结果说明极少量的氧化石墨烯的加入可以对聚酰胺46的结晶起成核剂的作用,进一步通过Avrami方程分析得知受限制的环境使结晶生长的维度下降.聚酰胺46的熔点随着添加0.1%氧化石墨烯含量时升高了2.6℃,其热稳定性和动态力学性能也随之提高.

参考文献

[1] Fang-Chyou Chiu;Sun-Mou Lai;Yu-Lun Chen;Tsung-Han Lee .Investigation on the polyamide 6/organoclay nanocomposites with or without a maleated polyolefin elastomer as a toughener[J].Polymer: The International Journal for the Science and Technology of Polymers,2005(25):11600-11609.
[2] Fang-Chyou Chiu;Gow-Feng Kao .Polyamide 46/multi-walled carbon nanotube nanocomposites with enhanced thermal, electrical, and mechanical properties[J].Composites, Part A. Applied science and manufacturing,2012(1):208-218.
[3] Wang, H.;Qiu, Z..Crystallization kinetics and morphology of biodegradable poly(l-lactic acid)/graphene oxide nanocomposites: Influences of graphene oxide loading and crystallization temperature[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,2012:40-46.
[4] Fang-Chyou Chiu;Wen-I Su .Structure, thermal properties and mechanical properties of sPS-based nanocomposites with and without styrenic elastomer inclusions[J].Materials Chemistry and Physics,2012(1):145-153.
[5] Ramesh C. .New crystalline transitions in nylons 4,6, 6,10, and 6,12 using high temperature x-ray diffraction studies[J].Macromolecules,1999(11):3721-3726.
[6] Zhang QX.;Zhang ZH.;Zhang HF.;Mo ZS. .Isothermal and nonisothermal crystallization kinetics of nylon-46[J].Journal of Polymer Science, Part B. Polymer Physics,2002(16):1784-1793.
[7] Fan, P.;Wang, L.;Yang, J.;Chen, F.;Zhong, M. .Graphene/poly(vinylidene fluoride) composites with high dielectric constant and low percolation threshold[J].Nanotechnology,2012(36):365702-1-365702-8.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%