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采用硬度测试、拉伸性能测试、DSC分析和透射电镜(TEM)等方法研究不同时效制度对2A97铝锂合金组织和性能的影响。结果表明:采用165℃人工时效时,峰值强度最高,但其塑性也最差,且达到峰值的时间长达60 h;200℃人工时效时,达到峰值的时间缩短为6 h,而其峰值强度和塑性均很差;(200℃,6 h)+(165℃,6 h)双级时效优化后,可获得比200℃峰时效更高的强度,其抗拉强度为545 MPa,只比165℃峰时效强度低11 MPa,伸长率却提高至7.1%,且时效时间比165℃峰时效时缩短了48 h。2A97铝锂合金峰时效状态下的析出相有T1(Al2CuLi)相、θ′相和一定量的σ(Al5Cu6Mg2)相。根据不同升温速率下的DSC曲线,采用Kissinger法求得T1相的析出激活能为75.9 kJ/mol。综合分析可知,采用(200℃,6 h)+(165℃,6 h)双级时效可以得到比单级时效更加优异的综合性能。

The effect of aging treatment on the microstructure and mechanical properties of 2A97 Al-Li alloy during artificial aging was studied by hardness measurement, tensile test, differential scanning calorimetry (DSC) and transmission electron microscopy (TEM). The results indicate that 2A97 alloy obtains the highest strength, but its elongation is relatively low when aged at 165℃for 60 h;when it is aged at 200℃, only 6 h is needed to achieve peak aging, whereas the peak strength and elongation are both poor;when the alloy is aged at (200℃, 6 h)+(165℃, 6 h), the aging time of which is 48 h less than that of single aging treatment when peak values are obtained, while the tensile strength is 545 MPa, only 11 MPa less than that of single aging treatment, and the elongation increases to 7.1%. The T1(Al2CuLi) phase, θ' phase and σ(Al5Cu6Mg2) phase are the major precipitates in 2A97 alloy. According to the DSC curves at various heating rates, the activation energies of T1 phases by Kissinger method is 75.9 kJ/mol. To sum up, the (200℃, 6 h)+(165℃, 6 h) double aging treatment can endow the alloy with more excellent comprehensive performance than single aging system.

参考文献

[1] SANDERS T H Jr;BALMUTH E S .Aluminum-lithium alloys:Low density and high stiffness[J].METAL PROGRESS,1978,113(01):32-35.
[2] RIOJA R J .Fabrication methods to manufacture isotropic Al-Li alloys and products for space and aerospace applications[J].Materials Science and Engineering A,1998,257(01):100-107.
[3] FRIDLYANDER I N .Russian aluminum alloys for aerospace and transport applications[J].Materials Science Forum,2000,331/337:921-926.
[4] R.K. Gupta;Niraj Nayan;G. Nagasireesha;S.C. Sharma .Development and characterization of Al-Li alloys[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2006(1/2):228-234.
[5] MENG L;ZHENG X L .Overview of the effects of impurities and rare earth elements in Al-Li alloys[J].Materials Science and Engineering A,1997,237(01):109-118.
[6] 李红英,王晓峰,赵延阔,曾翠婷,张建飞.固溶温度对2A97合金组织与性能的影响[J].材料热处理学报,2010(04):114-119.
[7] K. S. KUMAR;S. A. BROWN;J. R. PICKENS .MICROSTRUCTURAL EVOLUTION DURING AGING OF AN Al-Cu-Li-Ag-Mg-Zr ALLOY[J].Acta materialia,1996(5):1899-1915.
[8] GAYLE F W;HEUBAUM F H;PICKENS J R .Structure and properties during aging of an ultra-high strength Al-Cu-Li-Ag-Mg alloy[J].Scripta Metallurgica et Materialia,1990,24(05):79-84.
[9] WILLIAMS D B;EDINGTON J W .The precipitation of δ′(Al3Li)in dilute aluminium-lithium alloys[J].Metal Science Journal,1975,9(12):529-532.
[10] Li, HY;Tang, Y;Zeng, ZD;Zheng, ZQ;Zheng, F .Effect of ageing time on strength and microstructures of an Al-Cu-Li-Zn-Mg-Mn-Zr alloy[J].Materials Science and Engineering. A, Structural Materials: Properties, Microstructure and Processing,2008(1/2):314-320.
[11] NOBLE B;THONGSON G E .T1(Al2CuLi)precipitation in aluminium-copper-lithium alloys[J].Metal Science Journal,1972,6(01):167-174.
[12] 卫英慧,贾连锁,胡兰青,许并社.Al-Li-Cu-Zr合金中T1相结构、形核和长大机制研究[J].稀有金属材料与工程,2003(06):428-431.
[13] S. Ahmadi;H. Arabi;A. Shokuhfar .Formation mechanisms of precipitates in an Al-Cu-Li-Zr alloy and their effects on strength and electrical resistance of the alloy[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2009(1/2):90-94.
[14] 李红英,张孝军,张建飞,郑子樵.分级时效对新型Al-Cu-Li合金组织与性能的影响[J].中国有色金属学报,2008(03):426-432.
[15] Li Q.;Wawner FE. .CHARACTERIZATION OF A CUBIC PHASE IN AN AL-CU-MG-AG ALLOY[J].Journal of Materials Science,1997(20):5363-5370.
[16] SCHUELLER R D;SACHDEV A K;WAWNER F E .Identification of a cubic precipitate observed in an Al-4.3Cu-2Mg/SiC cast composite[J].Scripta Metallurgica et Materialia,1992,27(01):1289-1294.
[17] FRIDLYANDER J N;ANTIPOV V V;FEDORENKO T P .Product properties of high workability 1441 Al-Li alloy[J].Materials Forum,2004,28(01):1051-1052.
[18] J. Mizera;K.J. Kurzydlowski .On the anisotropy of the Portevin-Le Chatelier plastic instabilities in Al-Li-Cu-Zr alloy[J].Scripta materialia,2001(7):801-806.
[19] S.Ahmadi,H.Arabi,A.Shokuhfar.Effects of Multiple Strengthening Treatments on Mechanical Properties and Stability of Nanoscale Precipitated Phases in an Aluminum-Copper-Lithium Alloy[J].材料科学技术学报(英文版),2010(12):1078-1082.
[20] 林毅,郑子樵,韩烨,张海锋.热处理工艺对2A97铝锂合金拉伸性能和腐蚀性能的影响[J].中国有色金属学报,2012(08):2181-2186.
[21] DAVYDOV V G;FRIDLYANDER I N;SAMARINA M V .The heat treatment of Al-Cu-Li alloys ensured the stability of structure and properties at long low temperature exposure[J].Materials Science Forum,2000,331:1049-1054.
[22] MUKHOPADHYAY A K .Coprecipitation ofΩandσphases in Al-Cu-Mg-Mn alloys containing Ag and Si[J].Metallurgical and Materials Transactions A:Physical Metallurgy and Materials Science,2002,33(12):3635-3648.
[23] TOSTEN M H;VASUDEVAN A K;HOWELL P R .Structure and deformation behavior of T1 precipitate plates in an Al-2Li-1Cu alloy[J].Metallurgical and Materials Transactions A:Physical Metallurgy and Materials Science,1988,19(12):2911-2920.
[24] 袁志山,陆政,谢优华,吴秀亮,戴圣龙,刘常升.2A97铝锂合金双级时效研究[J].稀有金属材料与工程,2011(03):443-447.
[25] 钟申,郑子樵,廖忠全,蔡彪.时效制度对2A97铝锂合金强韧性的影响[J].中国有色金属学报,2011(03):546-553.
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