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为了提高聚醚砜酮(PPESK)微孔膜的亲水性和抗污性,采用紫外(UV)辐照引发聚乙二醇丙烯酸酯(PEGA)在膜上发生接枝和交联,在膜表面形成稳定的亲水层.利用场发射扫描电镜(SEM)研究了固定PEGA后PPESK膜表面形貌的变化.表面改性后PPESK膜的水接触角的降低表明PEGA的固定有利于提高其亲水性,蛋白质静态吸附实验显示膜的抗蛋白质污染能力增强,渗透实验表明膜表面较低数量的PEGA亲水链有利于提高PPESK微孔膜的水通量,膜的溶质截留率增大,截留分子量(MWCO)减小.

参考文献

[1] Dattatray S W;Ellen R F .[J].Langmuir,2003,19:79-85.
[2] Golander C G;Kiss E J .[J].Journal of Colloid and Interface Science,1988,121:240-246.
[3] Kaeselev B.;Belfort G.;Pieracci J. .Photoinduced grafting of ultrafiltration membranes: comparison of poly(ether sulfone) and poly(sulfone)[J].Journal of Membrane Science,2001(2):245-261.
[4] Pieracci J;Crivello J V;Belfort G .[J].Journal of Membrane Science,1999,156:223-240.
[5] Ulbricht M;Riedel M .Ultrafiltration membrane surfaces with grafted polymer 'tentacles': preparation, characterization and application for covalent protein binding.[J].Biomaterials,1998(14):1229-1237.
[6] 蹇锡高,陈平,廖功雄,朱秀玲,张守海,王锦艳.含二氮杂荼酮结构新型聚芳醚系列高性能聚合物的合成与性能[J].高分子学报,2003(04):469-475.
[7] Jian X G;Dai Y;He G H .[J].Journal of Membrane Science,1999,161:185-191.
[8] Zhang SH;Jian XG;Dai Y .Preparation of sulfonated poly(phthalazinone ether sulfone ketone) composite nanofiltration membrane[J].Journal of Membrane Science,2005(2):121-126.
[9] Su Y;Jian XG;Zhang SH;Wang GQ .Preparation and characterization of quaternized poly (phthalazinone ether sulfone ketone) NF membranes[J].Journal of Membrane Science,2004(2):225-233.
[10] Dai Y;Jian X G;Zhang S H et al.[J].Journal of Membrane Science,2001,188:195-203.
[11] Wang P.;Tan KL.;Kang ET.;Neoh KG. .Plasma-induced immobilization of poly(ethylene glycol) onto poly(vinylidene fluoride) microporous membrane[J].Journal of Membrane Science,2002(1):103-114.
[12] McPherson T.;Szleifer I.;Park K.;Kidane A. .Prevention of protein adsorption by tethered poly(ethylene oxide) layers: Experiments and single-chain mean-field analysis[J].Langmuir: The ACS Journal of Surfaces and Colloids,1998(1):176-186.
[13] Malucelli G.;Bongiovanni R.;Priola A.;Gozzelino G. .PHOTOPOLYMERIZATION OF POLY(TETRAMETHYLENE ETHER) GLYCOL DIACRYLATES AND PROPERTIES OF THE OBTAINED NETWORKS[J].Polymer: The International Journal for the Science and Technology of Polymers,1996(12):2565-2571.
[14] Shantha K L;Krishnamurti N .[J].Journal of Applied Polymer Science,1989,37:2987-3002.
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