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采用超声法一步合成了三聚氰胺-甲醛-乙二胺四草酰乙酸螯合树脂/纳米碳管复合物.采用红外光谱、场发射扫描电镜及电化学技术表征了材料的特性.该复合物修饰充蜡石墨电极被成功应用于水溶液中重金属离子Pb(Ⅱ)、Cd(Ⅱ)和Zn(Ⅱ)的同时测定,检测限分别为1×10-10、1×10-8和5×10-8 mol·L-1 (3σ).

参考文献

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[2] Joseph Wang;Jianmin Lu;Samo B. Hocevar .Bismuth-Coated Carbon Electrodes for Anodic Stripping Voltammetry[J].Analytical chemistry,2000(14):3218-3222.
[3] de Oliveira MF;Saczk AA;Okumura LL;Fernandes AP;de Moraes M;Stradiotto NR .Simultaneous determination of zinc, copper, lead, and cadmium in fuel ethanol by anodic stripping voltammetry using a glassy carbon-mercury-film electrode[J].Analytical and bioanalytical chemistry,2004(1):135-140.
[4] van Staden JF.;Matoetoe MC. .Simultaneous determination of copper, lead, cadmium and zinc using differential pulse anodic stripping voltammetry in a flow system[J].Analytica chimica acta,2000(1/2):201-207.
[5] A.I. Balabanovich .The effect of melamine on the combustion and thermal decomposition behaviour of poly(butylene terephthalate)[J].Polymer Degradation and Stability,2004(3):451-458.
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