采用一种改进的液相成膜技术--连续离子层吸附与反应(SILAR)法,用锌氨络离子[Zn(NH_3)_4]~(2+)溶液作为独立的前驱体溶液,以载玻片为衬底,在(125±5)℃的温度下沉积出致密、透明的ZnO薄膜.分别用冷场发射型扫描电镜(FESEM)和X射线衍射(XRD)分析了薄膜样品的表面形貌和结晶状态,用紫外-可见分光光度计(UV-Vis spectroscopy)研究了薄膜样品的发光性能.结果表明:获得样品为六角纤锌矿结构的多晶薄膜材料沿[002]方向择优生长;样品表面均匀、致密,厚度约为550 nm;在可见光波段具有高的透射率(>80%).
A modified solution method, successive ionic layer adsorption and reaction(SILAR), was applied to prepare transparent zinc oxide(ZnO) film on glass substrate at (125±5) ℃ in mixed ion precursor solution. The surface morphology and crystallizations of films were analyzed by field emission scanning microscopy (FESEM) and X-ray diffraction(XRD), respectively. The optical properties of the films were studied by ultraviolet visible(UV-Vis)spectroscopy. The results show that the obtained samples are poly-crystalline films of hexagonal wurtzite structure, with the preference of [002] orientation. The as-deposited films exhibit uniform and compact surface morphology, with the film thickness of 550 nm, and have high transmittance in the visible band(>80%).
参考文献
[1] | Chen Guanghua,Deng Jinxiang.Nanometer Thin Film Technology and Application,Beijing:Chemistry Industry Press,2004,88(in Chinese).(陈光华,邓金祥.纳米薄膜技术与应用.北京:化学工业出版社,2004,88.) |
[2] | Peng X P,Xu J Z,Zang H,et al.J Luminescence,2008,128:297. |
[3] | Liu Z F,Jin Z G,Li W,et al.Mater Lett,2005,59:3620. |
[4] | Kim D,Shimomura T,wakaiki S,et al.Phys,2006,B376/377:741. |
[5] | Ko H J,Chen Y,Hong S K,et al.J Crystal Grow,2000,209:816. |
[6] | Kim D C,Kong B H,Jun S O,et al.Thin Solid Films,2008,516:5562. |
[7] | Villanueva Y Y,Liu D R,Cheng P T.Thin Solid Films,2006,291:175. |
[8] | Nicolau Y F.Appl Surf Sci,1985,22/23:1061. |
[9] | Laukaitis G,Lindroos S,Tamulevi(c)ius S,et al.Mater Sci & Eng,2000,A288:223. |
[10] | Sankapal B R,Mane R S,Lokhande C D.Mater Res Bull,2000,35:177. |
[11] | Lindroos S,Arnold A,Leskel(a)M.Appl Surf Sci,2000,158:75. |
[12] | Pathan H M,Salunkhe P V,Sankapal B R,et al.Mater Chem and Phys,2001,72:105. |
[13] | Kale R B,Lokhande C D.Mater Res Bull,2004,39:1829. |
[14] | Laukaitis G,Lindroos S,Tamulevi(c)ius S,et al.Appl Surf Sci,2000,161:396. |
[15] | Sankapal B R,Ennaoui A,Guminskaya T,et al.Thin Solid Films,2005,480/481:142. |
[16] | Kundakci M,Ates A,Astam A,et al.Phys:Low-dimensional Systems and Nanostructures,2008,E40:600. |
[17] | Lokhande C D,Sankapal B R,Sartale S D,et al.Appl Surf Sci,2001,182:413. |
[18] | Gao X D,Li X M,Yu W D,et al.J Crystal Grow,2006,291:175. |
[19] | Jin Zhengguo,Liu Xiaoxin,Bu Shaojing,et al.Materials Review,2003,17(3):66(in Chinese).(靳正国,刘晓新,步绍静等.材料导报,2003,17(3):66.) |
[20] | Liu Xiaolin,Chen Xiaoqin,Qi Yajun,et al.Physics Progress,2006,6(3,4):495(in Chinese).(刘晓林,陈晓琴,祁亚军等.物理学进展,2006,6(3,4):495.) |
[21] | Liu J,Duan J L,Toimil-Molares M E,et al.Nanotechnology,2006,17:1922. |
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