欢迎登录材料期刊网

材料期刊网

高级检索

以凹凸棒石黏土(Attapulgite,ATP)为载体,通过酸性溶胶法制备纳米TiO2/SnO2/ATP前驱体,再经过不同温度煅烧得到其复合体.利用透射电镜(TEM)、X射线衍射(XRD)、热重分析(TG)等对其组成、尺寸、结构等进行分析和表征.结果表明,SnO2和TiO2纳米颗粒很好地复合在ATP表面而且分布均匀没有明显的团聚,同时SnO2的掺杂及ATP的负载使复合体中TiO2柱径比相同工艺获得的纯TiO2的粒径要小,SnO2的掺杂降低了复合体中TiO2晶型转变温度,在形成锐钛矿型TiO2的同时,复合体中ATP的吸附能力得以保持.

参考文献

[1] Zhou Zuoxing;Wang Jingbo;Zhou Sa.Processing TiO2 in gaseous sulfur and research on its photocatalysis under visible light[J].Solar Energy Materials and Solar Cells,2008(09):568.
[2] Satyen K Deb .Dye-sensitized TiO2 thin-film solar cell research at the national renewable energy laboratory(NREL)[J].Solar Energy Materials and Solar Cells,2005,88:1.
[3] 罗妮,沈俊,田从学,张昭.介孔SO42-/TiO2的一步法制备及其光催化性能[J].材料研究学报,2007(03):245-249.
[4] Dhawale DS;Salunkhe RR;Patil UM;Gurav KV;More AM;Lokhande CD .Room temperature liquefied petroleum gas (LPG) sensor based on p-polyaniline/n-TiO2 heterojunction[J].Sensors and Actuators, B. Chemical,2008(2):988-992.
[5] 王树峰,朱启安,陈万平,孙旭峰,张琪.掺Fe3+附银二氧化钛光催化剂的制备及其光催化活性研究[J].功能材料,2007(02):179-182.
[6] Wang J;Lin ZQ .Freestanding TiO2 nanotube arrays with ultrahigh aspect ratio via electrochemical anodization[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(4):1257-1261.
[7] 朱海青,周杰.凹凸棒石粘土的开发利用现状及发展趋势[J].矿产保护与利用,2004(04):14-17.
[8] 林岳宾,章跃.凹凸棒石黏土对TiO2纳米晶相变和晶粒生长的影响[C].第六届中国功能材料及其应用学术会议论文集,2007:2103-2105.
[9] Basa C;Tinani M;Irene E A .Atomic force microscopy and ellipsometry study of the nucleation and growth mechanism of polycrystalline silicon films on silicon dioxide[J].Journal of Vacuum Science and Technology A:Vacuum Surfaces and Films,1998,16(14):19.
[10] 龙明策,柴歆烨,周保学,蔡伟民,刘光增.不同掺杂二氧化钛的电子和晶体结构与光催化性能的关系[J].中国科技论文在线,2008(03):225-229.
[11] 许可,吕德义,郇昌永,郑遗凡,葛忠华.离子掺杂对纳米二氧化钛晶型转变的影响[J].材料科学与工程学报,2005(04):629-632.
[12] Sasikala R;Shirole A;Sudarsan V et al.Highly dispersed phase of SnO2 on TiO2 nanoparticles synthesized by polyolmediated route:Photocatalytic activity for hydrogen generation[J].International Journal of Hydrogen Energy,2009,34(04):3621.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%