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采用端羟基丁二烯液体橡胶(HTPB)对环氧树脂进行改性,研究了改性环氧树脂的热稳定性、力学及电性能.结果表明:HTPB的羟基与环氧基团发生了化学反应;HTPB改性环氧树脂的热稳定性下降;低橡胶用量下环氧树脂的弯曲、拉伸强度和冲击强度显著提高.HTPB橡胶颗粒均匀分布于环氧基体中并在固化时形成相分离.此外,改性环氧树脂的电绝缘性及介电性能均得到明显改善.

参考文献

[1] 王德忠.环氧树脂生产与应用[M].北京:化学工业出版社,2002:4-5.
[2] 石敏先,黄志雄,郦亚铭,杨国瑞.端羧基丁腈橡胶改性环氧树脂的结构与性能[J].高分子材料科学与工程,2008(02):47-50.
[3] Wise C.W. .CTBN rubber phase precipitation in model epoxy resins[J].Polymer: The International Journal for the Science and Technology of Polymers,2000(12):4625-4633.
[4] D.Ratna .Phase separation in liquid rubber modified epoxy mixture. Relationship between curing conditions, morphology and ultimate behavior[J].Polymer: The International Journal for the Science and Technology of Polymers,2001(9):4209-4218.
[5] Chikhi N.;Fellahi S.;Bakar M. .Modification of epoxy resin using reactive liquid (ATBN) rubber[J].European Polymer Journal,2002(2):251-264.
[6] Harani H.;Bakar M.;Fellahi S. .Toughening of epoxy resin using synthesized polyurethane prepolymer based on hydroxyl-terminated polyesters[J].Journal of Applied Polymer Science,1998(13):2603-2618.
[7] Fabio L.Barcia;Thiago P.Amaral;Bluma G.Soares .Synthesis and properties of epoxy resin modified with epoxy-terminated liquid polybutadiene[J].Polymer: The International Journal for the Science and Technology of Polymers,2003(19):5811-5819.
[8] Raju Thomas;Ding Yumei;He Yuelong .Miscibility,morphology,thermal,and mechanical properties of a DGEBA based epoxy resin toughened with a liquid rubber[J].Polymer: The International Journal for the Science and Technology of Polymers,2008(1):278-294.
[9] 孔德忠.环氧树脂增韧改性研究的新进展[J].绝缘材料,2010(06):25-27.
[10] 陈青,宫大军,魏伯荣,柳丛辉.端羧基丁腈橡胶改性环氧树脂的研究[J].绝缘材料,2011(02):30-33,38.
[11] 霍蛟龙,虞鑫海,李四新.环境友好型阻燃环氧树脂的研究现状[J].绝缘材料,2010(05):35-39.
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