层状的Li1+xV3O8电池正极材料具有比容量高、循环寿命长、价格便宜等优点,有望成为新一代锂离子二次电池的正极材料.综述了层状的Li1+xV3O8正极材料的结构、性质、制备技术、掺杂技术、电化学性能以及影响电极材料性能的各因素.其中重点总结了Li1+xV3O8正极材料的制备技术,包括高温固相合成技术、低温合成技术和掺杂技术.指出溶胶-凝胶法和经脱水处理的电极材料在综合性能上取得了一定突破,有望实现产业化生产.
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