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测量并比较了掺有不同量(Ni0.8Zn0.2)O石盐相添加物(Ni0.4Zn0.6)Fe2O4尖晶石铁氧体的电磁特性.发现(1-)(Ni0.4Zn0.6)Fe2O4+x(Ni0.8Zn0.2)O铁氧体磁导率频谱在x=0.05时出现可以用Johnson和Visser磁路模型合理解释的异常突变.将这一现象结合X射线衍射、体积密度、直流电阻率、磁导率温谱的实验数据进行分析,我们得出以下结论:当x≤0.05时,铁氧体为单一尖晶石相,尖晶石晶格中少量氧缺位的存在促进了晶粒的生长,提高了瓷体的致密度;当x>0.05时,铁氧体为尖晶石和石盐石两相混合物,在晶界处非磁性石盐相y<0.8(NiyZn1-y)O的存在阻碍了尖晶石晶粒的生长,降低了瓷体的致密化程度.

The characteristics of (Ni0.4Zn0.6)Fe2O4 spinel ferrites doped with various amount of (Ni0.8Zn0.2)O halite additives were investigated.
The permeability frequency spectra of the doped ferrites (1-x)(Ni0.4Zn0.6)Fe2O4+x(Ni0.8Zn0.2)O exhibit an anomalous transition at x=0.05, which can
be well described by the magnetic circuit model developed by Johnson and Visser. From the experimental data of X-ray diffraction, bulk density, dc electrical
resistivity, and permeability temperature spectra, the crystallographic structure of the doped ferrite for x≤0.05 is a pure spinel phase,
the presence of a small amount of oxygen vacancies in spinel lattice favors the grain growth and promotes the densification. For x>0.05, the crystallographic
structure is a diphasic mixture. The segregation of nonmagnetic y<0.8 (NiyZn1-y)O halite second phase on grain boundary hinders the spinel grain growth and lowers the densification.

参考文献

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