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总结了自由基聚合教学中的几个值得关注的问题,包括自由基聚合时不同引发剂类型的选择和确定、聚合温度及其区间选择及确定、聚合时间的确定、溶剂选择等。同时阐述了这些相关因素在自由基聚合研究方案设计时的相互关系。旨在使学生对自由基聚合的认识更为深刻和系统,培养学生独立进行自由基聚合研究方案设计的能力。

Some issues related the free radical polymerization should be focused on during the course of being educated and have been discussed in detail in this paper.These issues included the selection of initiator,polymerization temperature,time of polymerization and used solvent when free radical polymerization mechanism was applied.Meanwhile,it also expressed the inreaction between these above factors when the free radical polymerization route and technologies were designed.It aims at to improve students understanding and application of free radical polymerization systemly and develop the ability of design.

参考文献

[1] 杨建国.浅谈自由基聚合动力学的教学与学习[J].高分子通报,2006(04):89-92.
[2] 陈学刚.自由基聚合的模块化教学及难点剖析[J].高分子通报,2009(10):64-69.
[3] 王峰,任琳,童彬.不同聚合机理的"聚合度"公式的讨论[J].高分子通报,2009(06):75-78.
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