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基于品位匹配和多能源综合梯级利用的原则,本文提出了低CO_2排放的太阳能与化石能源互补发电系统LESOLCC,并对其进行了热力经济性能分析。所提系统以甲醇为燃料,中低温太阳能首先提供甲醇重整反应的反应热,从而转化为富氢合成气的化学能,实现品位提升;其次通过燃烧前对CO_2的捕集,实现燃料的清洁燃烧,最终在高效联合循环中实现其热功转换。结果表明:基本工况下,系统当量效率达到55.1%,比投资为833$/kW,发电成本为0.124$/kWh,回收期17年;与相同化石燃料输入及CO_2捕集水平的尾气捕集CO_2的常规燃气-蒸汽联合循环(CC-Post)相比,发电成本下降了10.1%,充分显示其优越性。

A novel gas-steam combined cycle power systems integrated with low/mid temperature solar heat thermo-chemical conversion and CO_2 capture,with methanol as the input fuel,have been proposed and analysed.Solar heat collected at 200~300℃is used to heat the endothermic methanol reforming reaction and is thereby converted into syngas chemical energy;the produced syngas is enriched with H_2 and CO_2(24.4%CO_2 and 74.7%H_2 by volume),thus is ready for pre-combustion decarbonization.The processed CO_2-lean syngas is used to fuel a gas/steam combined cycle.The results show that exergy efficiency of 55.1%can be achieved;the specific total plant cost is 833$/kW, the cost of electricity is 0.124$/kWh and the payback period is 17 years.As compared with the reference system with the same methanol input and CO_2 capture rate,the hybrid system exhibits the advantage of reduced cost of electricity by up to 10.1%.

参考文献

[1] Hui Hong;Hongguang Jin;Jun Ji;Zhifeng Wang;Ruixian Cai .Solar thermal power cycle with integration of methanol decomposition and middle-temperature solar thermal energy[J].Solar Energy,2005(1):49-58.
[2] T. Nakagaki;T. Ogawa;K. Murata .Development of Methanol Steam Reformer for Chemical Recuperation[J].Journal of engineering for gas turbines and power: Transactions of the ASME,2001(4):727-733.
[3] 刘启斌 .中低温太阳能热化学制氢与工程热物理某些问题的代数显式解析解[D].中国科学院工程热物理研究所,2008.
[4] Thomas Kreutz;Robert Williams;Stefano Consonni;Paolo Chiesa .Co-production of hydrogen, electricity and CO_2 from coal with commercially ready technology. Part B: Economic analysis[J].International journal of hydrogen energy,2005(7):769-784.
[5] Meng Liu;Noam Lior;Na Zhang;Wei Han .Thermoeconomic analysis of a novel zero-CO_2-emission high-efficiency power cycle using LNG coldness[J].Energy conversion & management,2009(11):2768-2781.
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