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通过浮选试验、吸附量试验和红外光谱测试,考察捕收剂戊黄药(PAX)和抑制剂羧甲基纤维素(CMC)的添加顺序对绿泥石与黄铁矿浮选分离的影响,并研究其作用机理。结果表明:先加抑制剂羧甲基纤维素时,羧甲基纤维素是绿泥石的有效抑制剂,但也会抑制黄铁矿的浮选,影响绿泥石与黄铁矿的浮选分离;先加入捕收剂戊黄药时,羧甲基纤维素对黄铁矿的抑制作用减弱,而绿泥石的浮选回收不受影响,黄铁矿与绿泥石的分离选择性提高。抑制剂羧甲基纤维素能同时吸附在黄铁矿与绿泥石表面,而捕收剂戊黄药只能吸附在黄铁矿表面。戊黄药与羧甲基纤维素在黄铁矿表面存在竞争吸附,先加捕收剂时,戊黄药的预先吸附降低了羧甲基纤维素在黄铁矿表面的吸附量,减弱了羧甲基纤维素对黄铁矿的抑制作用,提高了黄铁矿与绿泥石的分离选择性。

The effects of collector potassium amyl xanthale (PAX) and depressant carboxy methyl cellulose (CMC) addition order on the separation of chlorite from pyrite were investigated by flotation tests, adsorption tests and FTIR study. The results show that CMC is an effective depressant in the flotation of chlorite, while it also depresses the flotation of pyrite. With the addition of PAX first, the depression effect of CMC on the pyrite is weakened while the chlorite flotation recovery is not influenced. CMC is adsorbed on the surfaces of both pyrite and serpentine while PAX is only adsorbed on the pyrite surface. CMC and PAX compete in adsorbing on pyrite surface and the adsorption density of CMC decreases in the presence of a pre-adsorbed layer of PAX. However, there is no competitive adsorption on the chlorite surface between PAX and CMC, while PAX can not be adsorbed on the chlorite surface.

参考文献

[1] 许荣华.硫化镍及硫化铜镍矿石选矿概述[J].昆明理工大学学报(理工版),2000(02):16-19.
[2] 卢毅屏,龙涛,冯其明,欧乐明,张国范.微细粒蛇纹石的可浮性及其机理[J].中国有色金属学报,2009(08):1493-1497.
[3] 卢毅屏,张明强,冯其明,龙涛,欧乐明,张国范.六偏磷酸钠在蛇纹石与黄铁矿分离中的作用[J].中国有色金属学报(英文版),2011(01):208-213.
[4] 张秀品,戴惠新.某镍矿选矿降镁研究探讨[J].云南冶金,2006(03):12-17.
[5] Witney J.Y.;Yan D.S. .REDUCTION OF MAGNESIA IN NICKEL CONCENTRATES BY MODIFICATION OF THE FROTH ZONE IN COLUMN FLOTATION[J].Minerals Engineering,1997(2):139-154.
[6] D. Fornasiero;J. Ralston .Cu(II) and Ni(II) activation in the flotation of quartz, lizardite and chlorite[J].International Journal of Mineral Processing,2005(1/2):75-81.
[7] 刘谷山,冯其明,欧乐明,卢毅屏,张国范.铜离子和镍离子对滑石浮选的影响及作用机理[J].硅酸盐学报,2005(08):1018-1022.
[8] P. G. Shortridge;P. J. Harris .The effect of chemical composition and molecular weight of polysaccharide depressants on the flotation of talc[J].International Journal of Mineral Processing,2000(3):215-224.
[9] David A. Beattie;Le Huynh;Gillian B. Kaggwa .Influence of adsorbed polysaccharides and polyacrylamides on talc flotation[J].International Journal of Mineral Processing,2006(4):238-249.
[10] WELLHAM E J;ELBER L;YAN D S .The role of carboxy methyl cellulose in the flotation of a nickel sulphide transition ore[J].Minerals Engineering,1992,5(3/5):381-395.
[11] Gayle E. Morris;Daniel Fornasiero;John Ralston .Polymer depressants at the talc-water interface: adsorption isotherm, microflotation and electrokinetic studies[J].International Journal of Mineral Processing,2002(1/4):211-227.
[12] O. Bicak;Z. Ekmekci;D.J. Bradshaw .Adsorption of guar gum and CMC on pyrite[J].Minerals Engineering,2007(10):996-1002.
[13] J. Wiese;P. Harris;D. Bradshaw .The response of sulphide and gangue minerals in selected Merensky ores to increased depressant dosages[J].Minerals Engineering,2007(10):986-995.
[14] 王淀佐;胡岳华.资源加工学[M].长沙:科学出版社,2005
[15] A. Lopez Valdivieso;T. Celedon Cervantes;S. Song .Dextrin as a non-toxic depressant for pyrite in flotation with xanthates as collector[J].Minerals Engineering,2004(9/10):1001-1006.
[16] Qin Wenqing,Wei Qian,Jiao Fen,Yang Congren,Liu Ruizeng,Wang Peipei,Ke Lifang.Utilization of polysaccharides as depressants for the flotation separation of copper/lead concentrate[J].矿业科学技术(英文版),2013(02):179-186.
[17] Zhang, Y.;Cao, Z.;Cao, Y.;Sun, C..FTIR studies of xanthate adsorption on chalcopyrite, pentlandite and pyrite surfaces[J].Journal of Molecular Structure,2013:434-440.
[18] E. J. Silvester;W. J. Bruckard;J. T. Woodcock .Surface and chemical properties of chlorite in relation to its flotation and depression[J].Transactions of the Institutions of Mining and Metallurgy, Section C. Mineral Processing and Extractive Metallurgy,2011(2):65-70.
[19] M.B.M. Monte;A.J.B. Dutra;C.R.F. Albuquerque Jr. .The influence of the oxidation state of pyrite and arsenopyrite on the flotation of an auriferous sulphide ore[J].Minerals Engineering,2002(12):1113-1120.
[20] P. K. Sharma;K. Hanumantha Rao .Adhesion of Paenibacillus polymyxa on chalcopyrite and pyrite: surface thermodynamics and extended DLVO theory[J].Colloids and Surfaces, B. Biointerfaces,2003(1):21-38.
[21] 张芹,胡岳华,顾帼华,徐竟.磁黄铁矿与乙黄药相互作用电化学浮选红外光谱的研究[J].矿冶工程,2004(05):42-44.
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