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  4. V系储氢合金及其合金化

材料导报, 2006, 20(10): 123-127.

V系储氢合金及其合金化

裴沛 1, , 张沛龙 2, , 张蓓 3, , 宋西平 4,

1.北京科技大学新金属材料国家重点实验室,北京,100083

2.北京科技大学新金属材料国家重点实验室,北京,100083

3.北京科技大学应用学院物理系,北京,100083

4.北京科技大学新金属材料国家重点实验室,北京,100083

基金项目:   北京市自然科学基金(2042015)  

关键词： 储氢材料储氢合金V合金VTi合金

V Based Hydrogen Storage Alloys and Alloying Research

概述了V系储氢合金的研究现状,涉及V系储氢合金的氢化物相结构、合金化元素及第二相对合金吸、放氢性能的影响:V系储氢合金随吸氢量的增加,氢化物结构发生bcc→bct→fcc转变,同时其稳定性呈降低趋势;合金元素通过改变V与H的亲和力以及氢化物的稳定性来影响合金的储氢性能;第二相的出现对合金电化学性能、吸放氢动力学有明显的影响作用.在上述分析的基础上,对V系bcc固溶体储氢合金今后的研究进行了展望.

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