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采用小麦秸秆、玉米秸秆、锯末、中药渣作为吸油材料,重点研究了吸附材料粒径、吸附时间以及不同油品对这4种天然生物质材料的吸油性能的影响。同时,研究对比了这4种材料的吸水性能和保油能力。在对原油进行吸附实验时,发现锯末和小麦秸秆在0.25~0.83mm粒径范围内具有较好的吸油性能,吸油量分别为5.79和6.02g/g,其次为玉米秸秆,0.15~0.18mm之间的材料吸油量最大能达到5.02g/g,而中药渣在0.18~0.20mm之间的吸油量仅为2.37g/g。比较4种材料对有机物甲苯及植物油的吸附性能发现,其对原油的吸附效果优于植物油和甲苯。材料均有一定的保油能力,而锯末的保油能力最高,其油水比〉11。由于天然生物质材料属固体废物,其吸油后可直接作为燃料使用,可达到以废治废的目的,因此在含油污水处理领域具有较好的开发和应用前景。

This research investigates the use of four kinds of natural biomass materials,namely wheat straw,corn stalks,sawdust and the dregs.The influence factors on oil-adsorbing properties were studied,such as particle size,adsorption time and oil types.The paper also studied the water absorption of the four kinds of materials in order to investigate the selectivity of water and oil.In addition,oil retain capacity was evaluated too.On the crude oil adsorption test,sawdust and wheat straw have good oil absorption performance within the size range of 0.25-0.83mm and oil sorption capacities are approximately 5.79 and 6.02g/g m(oil)/m(sorbent),followed by corn stalks,oil absorption of the absorbing material between 0.15-0.18mm was 5.02g/g,the dregs of oil absorption between 0.18-0.20mm was only 2.37g/g.Comparison of four kinds of materials on the adsorption properties of organic compounds toluene and vegetable oil,the adsorption effect of the crude oil is better than vegetable oil and toluene.The four kinds of materials all have a certain amount of oil retention capacity,the oil retention capacity of sawdust is highest and oil-water ratio is greater than 11.Besides,natural biomass materials are solid wastes,they can be directly used as fuel after oil absorption,to achieve the purpose of waste by waste.The results show that natural biomass materials show a high performance as a low cost and environmental friendly sorbents for the removal oil from water.Natural biomass materials will have better development and application prospects in the area of oily wastewater treatment.

参考文献

[1] 柳婷婷,田珊珊.海上溢油事故处理及未来发展趋势[J].中国水运(理论版),2006(11):27-29.
[2] Khan E;Virojnagud W;Ratpukdi T .Use of biomass sorbents for oil removal from gas station runo[J].Chemosphere,2004,5 :682-689.
[3] 石艳锦,封严.吸油材料[C].第七届中国功能材料及其应用学术会议论文集,2010:84-86.
[4] Lim TT;Huang XF .Evaluation of kapok (Ceiba pentandra (L.) Gaertn.) as a natural hollow hydrophobic-oleophilic fibrous sorbent for oil spill cleanup[J].Chemosphere: Environmental toxicology and risk assessment,2007(2):955-963.
[5] Adeba]o M O;Frost R L .Acetylation of raw cotton for oil spill cleanup application:an FT-IR and 13C MAS NMR spectroscopic investigation[J].Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy,2004,60:2315-2321.
[6] S. Suni;A.-L. Kosunen;M. Hautala;A. Pasila;M. Romantschuk .Use of a by-product of peat excavation, cotton grass fibre, as a sorbent for oil-spills[J].Marine pollution bulletin,2004(11/12):916-921.
[7] Moriwaki H;Kitajima S;Kurashima M et al.Utiliza- tion of silkworm cocoon waste as a sorbent for the remov- al of oil from water[J].Journal of Hazardous Materials,2009,165:266-270.
[8] Abdullah M A;Rahmah A U;Man Z .Physicochemical and sorption characteristics of malaysian ceiba pentandra(L.) Gaertn as a natural oil sorbent[J].Journal of Haz- ardous Materials,2010,177:683-691.
[9] S.A.Sayed;A.M.Zayed .Investigation of the effectiveness of some adsorbent materials in oil spill clean-ups[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2006(1/3):90-100.
[10] Radetic, M;Ilic, V;Radojevic, D;Miladinovic, R;Jocic, D;Jovancic, P .Efficiency of recycled wool-based nonwoven material for the removal of oils from water[J].Chemosphere,2008(3):525-530.
[11] T.R. Annunciado;T.H.D. Sydenstricker;S.C. Amico .Experimental investigation of various vegetable fibers as sorbent materials for oil spills[J].Marine pollution bulletin,2005(11):1340-1346.
[12] Chen L L .Adsorption of petroleum in seawater on bio- degradable materials and Ca-bentonite[D].青岛:青岛科技大学,2010.
[13] Xie Y;Huang T L;Wang Z Y et al.An experimental study of petroleum pollutant's adsorption on and pelease from river sediments[J].Environmental Engineering,2000,18(03):58-60.
[14] 韩立宏 .甲基丙烯酸丁酯类高吸油树脂的合成及性能研究[D].沈阳农业大学,2006.
[15] 刘幸福 .利用蔗渣纤维制备高吸油材料的研究和应用[D].广西大学,2010.
[16] Niu J T;Tao M;Jin B D .Study on the preparation of one new type oil-adsorbent fiber and absorptive proper- ties[J].Journal of Functional Materials,2011,42(III):416-422.
[17] Banerjee SS;Joshi MV;Jayaram RV .Treatment of oil spill by sorption technique using fatty acid grafted sawdust[J].Chemosphere: Environmental toxicology and risk assessment,2006(6):1026-1031.
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