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以碳化温度为900℃的竹炭为导电骨料、酚醛树脂为黏结剂、炭黑为添加剂,采用模压成型法制备竹炭/酚醛树脂复合导电材料.考察了竹炭的粒度、酚醛树脂用量、炭黑用量、成型压力及固化温度等工艺因素对竹炭/酚醛树脂复合导电材料导电性和抗弯强度的影响.结果表明:随着酚醛树脂用量的增加,复合材料的抗弯强度增大,电导率先增大后减小;增加成型压力可同时提高复合材料的电导率和抗弯强度;增大竹炭粉粒的粒径、增加炭黑用量、提高同化温度有利于改善复合材料的导电性,但会不同程度地改变复合材料的力学性能.制备竹炭/酚醛树脂复合导电材料的最佳工艺条件为:竹炭粒度≤75/μm,树脂用量30%,炭黑用量7.5%,成型压力280 MPa,固化温度180℃.

参考文献

[1] 雀部博之,白川英树.导电高分子材料[M].曹镛,叶成,朱道本,译.北京:科学出版社,1989:238-245.
[2] 刘明军.传统块状炭材料的发展概况[J].炭素技术,2005,24(4):38-42.Liu Mingjun.Development status of traditional bulk carbon materials[J].Carbon Techniques,2005,24(4):38-42.
[3] 刘志坤,邵千钧,余养伦,等.竹材加工剩余物综合利用研究(Ⅱ)[J].竹子研究汇刊,2003,22(3):44-48.Liu Zhikun,Shao Qianjun,Yu Yanglun,et al.Study on comprehensive utilization of bamboo surplus material of processing(Ⅱ)[J].Journal of Bamboo Research,2003,22(3):44-48.
[4] 白翔,陈晓红,张东升,等.竹炭基超级电容器电极材料的制备和电化学性质[J].炭素技术,2009,28(1):9-13.Bai Xiang,Chen Xiaohong,Zhang Dongsheng,et al.Preparation and electrochemical properties of bamboo based electrode materials for supercapacitor[J].Carbon Techniques,2009,28(1):9-13.
[5] Byrbe C E,Nagle D C.Carbonization of wood for advance materials applications[J].Carbon,1997,35(2):259-266.
[6] Zhao R S,Wang X,Lin J M,Yuan J P.Using bamboo charcoal as solid-phase extraction adsorbent for the ultratracelevel determination of perfluorooctanoic acid in water samples by high-performance liquid chromatography-mass spectrometry[J].Analytical and Bioanalytical Chemistry,2008,390(6):1671-1676.
[7] 戴嘉璐,郭兴忠,杨辉,等.竹炭微结构的研究[J].材料科学与工程学报,2007,25(5):743-745.Dai Jialu,Guo Xingzhong,Yang Hui,et al.Study on the microstructure of bamboo charcoal[J].Journal of Materials Science & Engineering,2007,25(5):743-745.
[8] 李霞镇,徐明,任海青.中国竹炭产业研究新进展及发展建议[J].木材加工机械,2007(6):45-49.Li Xiazhen,Xu Ming,Ren Haiqing.New advance and suggestions of the bamboo charcoal industry in China[J].Woodworking Machinery,2007(6):45-49.
[9] Nitayaphat W,Jiratumnukul N,Charuchinda S,Kittinaovara S.Mechanical properties of chitosan/bamboo charcoal composite films made with normal and surface oxidized charcoal[J].Carbohydrate Polymers,2009,78(3):444-448.
[10] Zhao R S,Wang X,Yuan J P,Lin J M Investigation of feasibility of bamboo charcoal as solid-phase extraction adsorbem for the enrichment and determination of four phthalate esters in environmental water samples[J].Journal of Chromatography A,2008,1183(1):15-20.
[11] 钱欣,濮阳楠,金扬福.酚醛树脂/石墨导热塑料性能研究[J].工程塑料应用,1997,25(3):10-12.Qian Xin,Pu Yangnan,Jin Yangfu.Study on the properties of phenolic resin/graphite thermoplastics[J].Engineering Plastics Application.1997,25(3):10-12.
[12] Nelson J R,Wissing W K.Formulation of electrically conductive plastics:USP-4465166[P].1986-08-14.
[13] 季小勇,李惠,欧进萍.炭黑分散状态对炭黑/环氧树脂导电复合材料电阻率和力电性能的影响[J].复合材料学报,2009,26(5):39-46.Ji Xiaoyong,Li Hui,Ou Jinping.Influence of the dispersion of carbon black on the resistivity and electromechanical properties of carbon black filled epoxy matrix conductive composites[J].Acta Materiae Compositae Sinica,2009,26(5):39-46.
[14] Ganglani M,Carr S H,Torkelson J M.Influence of cure via network structure on mechanical properties of a free-radical polymerizing thermoset[J].Polymer,2002,43(9):2747-2760.
[15] Hsiao K T,Little R,Restrepo O,Minaie B.A study of direct cure kinetics characterization during liquid composite molding[J].Composites Part A,2006,37(6):925-933.
[16] Li M,Tucker Ⅲ C L.Optimal curing for thermoset matrix composites:Thermochemical and consolidations[J].Polymer Composites,2001,21(1):118-131.
[17] Xia J T,Hu Z L,Chen Z H.Preparation carbon brushes with thermosetting resin binder[J].Trans Nonferrous Met Soc,2007,17(6):1379-1384.
[18] 唐路林,李乃宁,吴培熙.高性能酚醛树脂及其应用技术[M].北京:化学工业出版社,2008:45-50.
[19] Wilson M S,Busick D N.Composite bipolar plate for electrochemical cells:US Patent,US 6248467 B1[P].2001-06-19.
[20] Chen H,Liu H B,Yang L,Li J X.Study on the preparation and properties of novolac epoxy/graphite composite bipolar plate for PEMFC[J].International Journal of Hydrogen Energy,2010,35(7):3105-3109.
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