以氯化铜和氢氧化钠为原料,采用室温固相法制备了碱式氯化铜Cu2(OH)3Cl,反应条件为n(NaOH): n(CuCl2) = 1.5: 1.0,研磨时间40 min,产率为94.1%.用XRD、IR和SEM对产物进行了表征.X射线粉末衍射数据的指标化结果表明,所得碱式氯化铜样品为单斜晶系,晶胞参数为:a= 0.5510 nm,b=1.0146 nm,c=1.3946 nm,β=96.39°.扫描电子显微镜分析表明制得的碱式氯化铜为60 nm,长度约600 nm纳米棒.
参考文献
[1] | Ye XR.;Yu JQ.;Xin XQ.;Xue ZL.;Jia DZ. .One-step solid-state reactions at ambient temperatures - A novel approach to nanocrystal synthesis[J].Advanced Materials,1999(11):941-942. |
[2] | Zhong G Q;Zhou H L;Jia Y Q .Preparation of Amorphous Ni-B Alloys Nanoparticles by Room Temperature Solid-solid Reaction[J].Journal of Alloys and Compounds,2008,465(1-2):L1-L3. |
[3] | 刘树信,王海滨,霍冀川.室温固相反应制备超细碳酸钡粒子的研究[J].人工晶体学报,2007(04):939-942. |
[4] | 彭秧锡,刘士军.微波固相反应前驱体热分解法制备纳米氧化铜粉体[J].人工晶体学报,2009(03):738-741. |
[5] | 李红雪,计成,马秋刚,罗绪刚,刘彬,余顺祥,陈昌铭,温炎燊,慎义勇.碱式氯化铜的分子结构、产品稳定性及理化特性研究[J].中国饲料,2004(06):28-29. |
[6] | 石荣铭,钟国清.新型饲料添加剂碱式氯化铜的制备研究[J].黑龙江畜牧兽医,2006(04):49-50. |
[7] | Ren, J;Li, Z;Liu, SS;Lu, XL;Xie, KC .Study on the formation and role of copper chloride hydroxide in the oxidative carbonylation of methanol to dimethyl carbonate[J].Kinetics and catalysis,2010(2):250-254. |
[8] | 王瑞玉,李忠,郑华艳,谢克昌.不同载体负载的Cu_2(OH)_3CI催化剂对甲醇氧化羰基化的催化性能[J].催化学报,2009(10):1068-1072. |
[9] | 邓凡政,祝爱侠,杨睿.CuO/Cu2(OH)3Cl的制备及其光催化降解染料光谱性能研究[J].光谱学与光谱分析,2006(02):299-301. |
[10] | 陈星铭,温炎燊,慎义勇,罗绪刚.碱式氯化铜的合成与理代特性研究[J].饲料工业,2004(05):38-40. |
[11] | Pollard A M;Thomas R G;Williams P A .Synthesis and Stabilities of the Basic Copper(II) Chlorides Atacamite,Paratacamite and Botallackite[J].Mineralogical Magazine,1989,53:557-563. |
[12] | S.C.Lee;S.-H.Park;S.M.Lee;J.B.Lee .Synthesis and H2 uptake of Cu2(OH)3Cl,Cu(OH)2 and CuO nanocrystal aggregate[J].Catalysis Today,2007(3/4):358-362. |
[13] | Zhitao Chen;Lian Gao .Hydrothermal Preparation of Biomineral Botallackite Cu2(OH)3Cl Hollow Nanoarchitectures[J].Chemistry Letters,2008(7):776-777. |
[14] | 李东升,王文亮,杨文选,李玉江,许刚健.Cu2(OH)3Cl-CuO纳米粉体的制备与表征[J].延安大学学报(自然科学版),2000(01):51-56. |
[15] | Stoilova D;Vassileva V .Infrared Spectroscopic Study of Solids in the Cu2(OH)3Cl (Paratacamite)-Zn5(OH)8Cl2@H2O (Simonkolleite) Series[J].Comptes-rendus de l'Académie Bulgare des Sciences,2002,55(07):51-54. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%