介绍了3种组成的Ti-V合金(Ti0.76V0.24、Ti0.51V0.49和Ti0.25V0.75)吸氢动力学研究方法,获得了动力学曲线、动力学方程及表观动力学参数.分析了Ti-V合金吸氢动力学的影响因素,金属氢化物动力学过程的特点及其与气-固反应动力学的区别.对反应程度进行归纳,得出Ti-V合金吸氢动力学方程的适用范围.
参考文献
| [1] | 万竟平,彭述明,郝万立,张涛,黄海禹,龙兴贵,杨本福.Ti-V合金吸氢性能研究[J].核化学与放射化学,2004(03):141-146. |
| [2] | 万竟平,彭述明,龙兴贵,杨本福.Ti-V合金及其氢化物结构的研究[J].材料导报,2006(z2):451-454. |
| [3] | Ono S;Imanari K;Akiba E.Reaction kinetics of the magnesium nickel alloys and hydrogen systems[A].Oxfod:Pergamon Press,1982:467. |
| [4] | Zarynow A;Goudy A J;Schweibenz R G et al.The effect of the partial replacement of nickel in LaNi5 hydride with iron,cobailt,and copper on absorption and desorption kinetics[J].Journal of the Less-Common Metals,1991,172-174:1009. |
| [5] | Uchida H;Ohtani Y;Ozawa M .Surface processes of H2 in the initial activation of LaNi5[J].Journal of the Less-Common Metals,1991,172-174:983. |
| [6] | Bershadsky E;Josephy Y;Ron M .Investigation of kinetics and strucral changes in TiFe0.8Ni0.2 after prolonged cycling[J].Journal of the Less-Common Metals,1991,172-174:1036. |
| [7] | Wang X L;Suda S .Study of the hydriding kinetics of LaNi4.7 Al0.3-H system by a step-wise method[J].Journal of the Less-Common Metals,1990,159:109. |
| [8] | Boulghallat M;Gerard N .Hydrding kinetics of TiFe0.5-Co0.5 compounds[J].Journal of the Less-Common Metals,1991,172-174:1052. |
| [9] | Josephy Y;Bershadsky E;Ron M .Investigation of LaNi5after prolonged cycling[J].Journal of the Less-Common Metals,1991,172-174:997. |
| [10] | Gavra Z;Johnson J R;Reilly J J .Decomposition kinetics of palladium nickel hydride[J].Journal of the Less-Common Metals,1991,172-174:107. |
| [11] | Hayao Imamura .Improved hydrogen storage by Mg and Mg-Ni modified by organic compounds[J].Journal of the Less-Common Metals,1991,172-174:1064. |
| [12] | Suda S;Komazaki Y;Miyamoto M.Hydriding properties of Al-substituted mischmetal nickels[A].Oxfod:Pergamon Press,1982:407. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%