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概述了多种合成LiFePO4的方法,主要有高温固相法、机械化学法、微波加热法等固相合成方法和溶胶-凝胶法、共沉淀法、乳化干燥法、喷雾干燥法、水热法等液相合成方法.固相法具有操作简单、工艺流程短等特点,但其反应控制条件比较苛刻,批次稳定性差;液相法反应控制条件相对温和,批次稳定性较好,其中水热法具有原料来源广泛、能耗低等优点,工业化前景较好,值得进一步研究.

参考文献

[1] Dragana Jugovic;Dragan Uskokovic .A review of recent developments in the synthesis procedures of lithium iron phosphate powders[J].Journal of Power Sources,2009(2):538-544.
[2] 周公度;郭可信.晶体和准晶体的衍射[M].北京:北京大学出版社,1995:5.
[3] 戴曦,唐红辉,杨平,张传福.LiFePO4正极材料的研究进展[J].材料导报,2005(08):69-71.
[4] 郭孝东,刘恒,吴德桥,钟本和.磷酸盐系锂离子电池正极材料的研究进展[J].材料导报,2009(07):28-31.
[5] Padhi AK.;Goodenough JB.;Nanjundaswamy KS. .PHOSPHO-OLIVINES AS POSITIVE-ELECTRODE MATERIALS FOR RECHARGEABLE LITHIUM BATTERIES[J].Journal of the Electrochemical Society,1997(4):1188-1194.
[6] Gaberscek M;Dominko R;Jamnik J .Is small particle size more important than carbon coating? An example study on LiFePO4 cathodes[J].Electrochemistry communications,2007(12):2778-2783.
[7] Song M S;Kang Y M;Kim J K et al.Simple and fast synthesis of LiFePO4-C composite for lithium rechargeable batteries by ball-milling and microwave heating[J].Journal of Power Sources,2007,166(01):260.
[8] Kim C W;Park J S;Lee K S .Effect of Fe2P on the electron conductivity and electrochemical performance of LiFePO4synthesized by mechanical alloying using Fe3+raw material[J].Journal of Power Sources,2006,163(01):144.
[9] Whittingham MS;Song YN;Lutta S;Zavalij PY;Chernova NA .Some transition metal (oxy)phosphates and vanadium oxides for lithium batteries[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2005(33):3362-3379.
[10] Kim C W;Lee M H;Jeong W T et al.Synthesis of olivine LiFePO4 cathode materials by mechanical alloying using iron(Ⅲ)raw material[J].Journal of Power Sources,2005,146(1-2):534.
[11] Okada S;Sawa S;Egashira M et al.Cathode properties of phosphor-olivine LiMPO4 for lithium secondary batteries[J].Journal of Power Sources,2001,97-98:430.
[12] 赵新兵,谢健.新型锂离子电池正极材料LiFePO4的研究进展[J].机械工程学报,2007(01):69-76.
[13] Marca M. Doeff;Yaoqin HU;Frank McLarnon .Effect of Surface Carbon Structure on the Electrochemical Performance of LiFePO_4[J].Electrochemical and solid-state letters,2003(10):A207-A209.
[14] Lei M .Preparation and characterization of LiFePO4 cathode material for lithium ion batteries[D].Beijing:Institute of Technology,Tsinghua University,2005.
[15] Zaghib K;Ravet N;Gauthier M et al.Optimized electrochemical performance of LiFePO4 at 60℃ with purity controlled by SQUID magnetometer[J].Journal of Power Sources,2006,163(01):560.
[16] John B. Goodenough .Cathode materials: A personal perspective[J].Journal of Power Sources,2007(2):996-1000.
[17] A. Yamada;S.C. Chung;K. Hinokuma .Optimized LiFePO_4 for Lithium Battery Cathodes[J].Journal of the Electrochemical Society,2001(3):A224-A229.
[18] Takahashi M;Tobishima S;Takei K et al.Characterization of LiFePO4 as the cathode material for rechargeable lithium batteries[J].Journal of Power Sources,2001,97-98:508.
[19] Zhu BQ;Li XH;Wang ZX;Guo HJ .Novel synthesis of LiFePO4 by aqueous precipitation and carbothermal reduction[J].Materials Chemistry and Physics,2006(2/3):373-376.
[20] Kwon S J;Kim C W;Jeong W T et al.Synthesis and electrochemical properties of olivine LiFePO4 as a cathode material prepared by mechanical alloying[J].Journal of Power Sources,2004,137(01):93.
[21] Kosova N;Devyatkina E .On mechanochemical preparation of materials with enhanced characteristics for lithium batteries[J].Solid state ionics,2004(1/4):181-184.
[22] Franger S;Cras F L;Bourbon C et al.Comparison between different LiFePO4 synthesis routes and their influence on its physical-chemical properties[J].Journal of Power Sources,2003,119-121:252.
[23] K. S. Park;J. T. Son;H. T. Chung;S. J. Kim;C. H. Lee;H. G. Kim .Synthesis of LiFePO_4 by co-precipitation and microwave heating[J].Electrochemistry communications,2003(10):839-842.
[24] Wang L;Huang Y D;Jiang R R et al.Preparation and characterization of nano-sized LiFePO4 by low heating solidstate coordination method and microwave heating[J].Electrochimica Acta,2007,24(01):6778.
[25] Vadivel Murugan A;Muraliganth T;Manthiram A .Rapid microwave-solvothermal synthesis of phospho-olivine nanorods and their coating with a mixed couducting polymer for lithium iron battery[J].Electrochemistry Communications,2008,10(06):903.
[26] Higuchi M;Katayama K;Azuma Y et al.Synthesis of LiFePO4 cathode material by microwave processing[J].Journal of Power Sources,2003,119-121(01):258.
[27] Franger S;Benoit C;Bourbon C;Le Cras F .Chemistry and electrochemistry of composite LiFePO4 materials for secondary lithium batteries[J].The journal of physics and chemistry of solids,2006(5/6):1338-1342.
[28] Hench L L;West J K .The sol-gel process[J].Chemical Reviews,1990,90(01):33.
[29] D. Morgan;A. Van der Ven;G. Ceder .Li Conductivity in Li_xMPO_4 (M = Mn, Fe, Co, Ni) Olivine Materials[J].Electrochemical and solid-state letters,2004(2):A30-A32.
[30] J. Yang;J.J. Xu .Nonaqueous Sol-Gel Synthesis of High-Performance LiFePO_4[J].Electrochemical and solid-state letters,2004(12):A515-A518.
[31] Y. Sundarayya;K.C. Kumara Swamy;C.S. Sunandana .Oxalate based non-aqueous sol-gel synthesis of phase pure sub-micron LiFePO_4[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2007(11):1942-1948.
[32] Choi D;Kumta P N .Surfactant based sol-gel approach to nanostructured LiFePO4 for high rate Li-ion battery[J].Journal of Power Sources,2007,163(02):1064.
[33] Dominko R;Bele M;Goupil JM;Gaberseek M;Hanzel D;Arcon L;Jamnik J .Wired porous cathode materials: A novel concept for synthesis of LiFePO4[J].Chemistry of Materials: A Publication of the American Chemistry Society,2007(12):2960-2969.
[34] Jae-Kwang Kim;Jae-Won Choi;Ghanshyam S. Chauhan;Jou-Hyeon Ahn;Gil-Chan Hwang;Jin-Beom Choi;Hyo-Jun Ahn .Enhancement of electrochemical performance of lithium iron phosphate by controlled sol-gel synthesis[J].Electrochimica Acta,2008(28):8258-8264.
[35] Y. Lin;M.X. Gao;D. Zhu;Y.F. Liu;H.G. Pan .Effects Of Carbon Coating And Iron Phosphides On The Electrochemical Properties Of Lifepo_4/c[J].Journal of Power Sources,2008(2):444-448.
[36] Silvera Scaccia;Maria Carewska;Pawel Wisniewski;Pier Paolo Prosini .Morphological investigation of sub-micron FePO_4 and LiFePO_4 particles for rechargeable lithium batteries[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2003(7):1155-1163.
[37] Arold G;Garche J;Hemmer R.Fine-particle lithium iron phosphate LiFePO4 synthesized by a new low-cost aqueous precipitation technique[J].Journal of Power Sources,2003(119-121):247.
[38] Jugovic, D;Mitric, M;Cvjeticanin, N;Jancar, B;Mentus, S;Uskokovic, D .Synthesis and characterization of LiFePO4/C composite obtained by sonochemical method[J].Solid state ionics,2008(11/12):415-419.
[39] 李运姣,洪良仕,习小明.锂离子电池正极材料LiFePO4的湿化学合成研究进展[J].矿冶工程,2005(04):58-61.
[40] Chung HT;Jang SK;Ryu HW;Shim KB .Effects of nano-carbon webs on the electrochemical properties in LiFePO4/C composite[J].Solid State Communications,2004(8):549-554.
[41] Seung-Taek Myung;Shinichi Komaba;Norimitsu Hirosaki;Hitoshi Yashiro;Naoaki Kumagai .Emulsion drying synthesis of olivine LiFePO{sub}4/C composite and its electrochemical properties as lithium intercalation material[J].Electrochimica Acta,2004(24):4213-4222.
[42] Xu ZH;Xu L;Lai QY;Ji XY .Microemulsion synthesis of LiFePO4/C and its electrochemical properties as cathode materials for lithium-ion cells[J].Materials Chemistry and Physics,2007(1):80-85.
[43] Cho T H;Chung H T et al.Synthesis of olivine-type LiFePO4 by emulsion-drying method[J].Journal of Power Sources,2004,133(02):272.
[44] Yang M R;Teng T H;Wu S H .LiFePO4/carbon cathode materials prepared by ultrasonic spay pyrolysis[J].Journal of Power Sources,2006,159(01):307.
[45] Jugovic D;Cvjeticanin N;Mitric M et al.Comparison between different LiFePO4 synthesis routes[J].Mater Sei Forum,2007,555:225.
[46] S. L. Bewlay;K. Konstantinov;G. X. Wang .Conductivity improvements to spray-produced LiFePO_4 by addition of a carbon source[J].Materials Letters,2004(11):1788-1791.
[47] Konarova M;Taniguchi I .Preparation of carbon coated LiFePO4 by a combination of spray pyrolysis with planetary ballmilling followed by heat treatment and their electrochemical properties[J].Power Technology,2009,191(1-2):111.
[48] Tsung-Hsien Teng;Mu-Rong Yang;She-hung Wu;Yi-Ping Chiang .Electrochemical properties of LiFe0.9Mg0.1PO4 / carbon cathode materials prepared by ultrasonic spray pyrolysis[J].Solid State Communications,2007(7):389-392.
[49] Muxina Konarova;Izumi Taniguchi .Preparation Of Lifepo_4/c Composite Powders By Ultrasonic Spray Pyrolysis Followed By Heat Treatment And Their Electrochemical Properties[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2008(12):3305-3317.
[50] Shoufeng Yang;Peter Y. Zavalij;M. Stanley Whittingham .Hydrothermal synthesis of lithium iron phosphate cathodes[J].Electrochemistry communications,2001(9):505-508.
[51] Tajimi S;Ikeda Y;Uematsu K et al.Enhanced electrochemical performance of LiFePO4 Preparaed by hydrothermal reaction[J].Solid State Ionics,2004,175(1-4):287.
[52] Meligrana G;Gerbaldi C;Tuel A et al.Hydrothermal synthesis of high surface LiFePO4 powers as cathode for Li-ion cells[J].Journal of Power Sources,2006,160(01):516.
[53] Xiao-dong Guo;Ben-he Zhong;Heng Liu .The Preparation of LiFePO_4/C Cathode by a Modified Carbon-Coated Method[J].Journal of the Electrochemical Society,2009(10):787-790.
[54] Kang B;Ceder G .Battery materials for ultra-fast charging and discharging[J].Nature,2009,458:190.
[55] Sondi I;Matijevic F .Homogeneous precipitation of calcium carbonates by enzyme catalyzed reaction[J].Journal of Colloid and Interface Science,2001,208(01):208.
[56] Recham, N;Armand, M;Laffont, L;Tarascon, JM .Eco-Efficient Synthesis of LiFePO4 with Different Morphologies for Li-Ion Batteries[J].Electrochemical and solid-state letters,2009(2):A39-A44.
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