综述了添加型含磷阻燃改性和反应型含磷阻燃改性方法,重点介绍了反应型含磷阻燃改性方法包括DOPO类、 DOPO衍生物类、氧化磷或磷酸酯类环氧树脂改性及含磷胺类、含磷羟基类、亚磷酸酯固化剂改性.其中,添加型含磷阻燃改性方法的阻燃效果明显且操作简单易行;反应型含磷阻燃改性方法的阻燃效率高、稳定性好,可使环氧树脂体系获得优良的阻燃性能.
参考文献
[1] | 祝大同.含磷环氧树脂及其在无卤化覆铜板中的应用[J].绝缘材料,2004(05):61-64. |
[2] | 王淑波,王利生.磷系阻燃环氧树脂研究[J].化学进展,2007(01):159-164. |
[3] | 尹月,夏英,蹇锡高.无卤阻燃环氧树脂的研究进展[J].工程塑料应用,2007(09):76-79. |
[4] | 欧育湘.从欧盟对阻燃剂危害性的评估看我国阻燃剂产业的发展[J].阻燃材料与技术,2004(06):1-4. |
[5] | 徐伟箭,周晓,夏新年.新型含氮阻燃环氧树脂的合成与性能[J].湖南大学学报(自然科学版),2006(04):72-75. |
[6] | Mercado LA;Galia M;Reina JA .Silicon-containing flame retardant epoxy resins: Synthesis, characterization and properties[J].Polymer Degradation and Stability,2006(11):2588-2594. |
[7] | Ying Ling Liu .Flame-retardant epoxy resins from novel phosphorus-containgin novolac[J].Polymer: The International Journal for the Science and Technology of Polymers,2001(8):3445-3454. |
[8] | Wang XD.;Zhang Q. .Synthesis, characterization, and cure properties of phosphorus-containing epoxy resins for flame retardance[J].European Polymer Journal,2004(2):385-395. |
[9] | Hergenrother PM;Thompson CM;Smith JG;Connell JW;Hinkley JA;Lyon RE;Moulton R .Flame retardant aircraft epoxy resins containing phosphorus[J].Polymer: The International Journal for the Science and Technology of Polymers,2005(14):5012-5024. |
[10] | Schafer, A;Seibold, S;Walter, O;Doring, M .Novel high T-g flame retardancy approach for epoxy resins[J].Polymer Degradation and Stability,2008(2):557-560. |
[11] | 王小建,王汝敏,杨建华.新型含磷环氧树脂的合成及性能研究[J].热固性树脂,2009(01):27-30. |
[12] | Levchik, S;Piotrowski, A;Weil, E;Yao, Q .New developments in flame retardancy of epoxy resins[J].Polymer Degradation and Stability,2005(1):57-62. |
[13] | 叶坤,刘治猛,贾德民.含磷环氧树脂及其在无卤阻燃覆铜板中的应用研究进展[J].工程塑料应用,2007(07):81-84. |
[14] | 祝大同.含磷环氧树脂及其在无卤化覆铜板中的应用[J].绝缘材料,2004(05):61-64. |
[15] | Yu-Long Chang;Yu-Zhong Wang;Da-Ming Ban;Bing Yang;Guo-Ming Zhao .A Novel Phosphorus-Containing Polymer as a Highly Effective Flame Retardant[J].Macromolecular materials and engineering,2004(8):703-707. |
[16] | Hong-Jun Xu;Fan-Long Jin;Soo-Jin Park .Synthesis of a Novel Phosphorus-containing Flame Retardant for Epoxy Resins[J].Bulletin of the Korean Chemical Society,2009(11):2643-2646. |
[17] | Wang, X.;Hu, Y.;Song, L.;Yang, H.;Xing, W.;Lu, H. .Synthesis and characterization of a DOPO-substitued organophosphorus oligomer and its application in flame retardant epoxy resins[J].Progress in Organic Coatings: An International Review Journal,2011(1):72-82. |
[18] | 卢林刚,王会娅,王大为,于宝刚,王永明,唐凯.新型阻燃剂1,3,5-三(5,5-二甲基-1,3-二氧杂己内磷酸酯基)苯的合成及表征[J].化学研究,2007(04):16-19. |
[19] | 王会娅,黄晓东,张燕.膨胀型无卤阻燃环氧树脂的制备及性能[J].塑料,2009(04):73-75. |
[20] | Tsung-Han Ho;Hann-Jang Hwang;Jeng-Yueh Shieh .Thermal and Physical Properties of Flame Retardant Epoxy Resins Containing 2-(6-oxido-6H-dibenz(,)c,e(,).1,2,oxaphosphorin-6-yl)-1,4-naphthalenediol and Cured with Dicyanateester[J].Polymer Degradation and Stability,2008,93:2077-2083. |
[21] | 郝建薇,熊燕兵,张涛.含磷环氧树脂的合成及阻燃研究[J].北京理工大学学报,2006(03):279-282. |
[22] | Hao Ai;Kai Xu;Huan Liu .Synthesis,Characterization,and Curing Properties of Novel Phosphorus-Conlaining Naphthyl Epoxy Systems[J].Journal of Applied Polymer Science,2009,113:541-546. |
[23] | Lin, HT;Lin, CH;Hu, YM;Su, WC .An approach to develop high-Tg epoxy resins for halogen-free copper clad laminates[J].Polymer: The International Journal for the Science and Technology of Polymers,2009(24):5685-5692. |
[24] | Ho TH;Leu TS;Sun YM;Shieh JY .Thermal degradation kinetics and flame retardancy of phosphorus-containing dicyclopentadiene epoxy resins[J].Polymer Degradation and Stability,2006(10):2347-2356. |
[25] | Hua Ren;Jianzhong Sun;Binjie Wu;Qiyun Zhou .Synthesis and properties of a phosphorus-containing flame retardant epoxy resin based on bis-phenoxy (3-hydroxy) phenyl phosphine oxide[J].Polymer Degradation and Stability,2007(6):956-961. |
[26] | Wanshuang Liu;Zhonggang Wang;Li Xiong .Phosphorus-containing Liquid Cycloaliphatic Epoxy Resins for Reworkable Environment-firiendly Electronic Packaging Materials[J].Polymer,2010,51:4776-4783. |
[27] | Li-Ping Gao;De-Yi Wang;Yu-Zhong Wang .A Flame-retardant Epoxy Resin Based on a Reactive phosphorus-containing Monomer of DODPP and Its Thhermal and Flame-retardant Properties[J].Polymer Degradation and Stability,2008,93:1308-1315. |
[28] | Mauerer, O .New reactive, halogen-free flame retardant system for epoxy resins[J].Polymer Degradation and Stability,2005(1):70-73. |
[29] | 王红娟,王新龙,王清华.环氧树脂含磷固化剂的合成和应用[J].绝缘材料,2005(02):4-7,12. |
[30] | Huan Liu;Kai Xu;Hao Ai;Liangliang Zhang;Mingcai Chen .Preparation and characterization of phosphorus-containing Mannich-type bases as curing agents for epoxy resin[J].Polymers for advanced technologies,2009(9):753-758. |
[31] | Schartel B;Braun U;Balabanovich AI;Artner J;Ciesielski M;Doring M;Perez RM;Sandler JKW;Altstadt V .Pyrolysis and fire behaviour of epoxy systems containing a novel 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide-(DOPO)-based diamino hardener[J].European Polymer Journal,2008(3):704-715. |
[32] | Toldy, A;Anna, P;Csontos, I;Szabo, A;Marosi, G .Intrinsically flame retardant epoxy resin - Fire performance and background - Part I[J].Polymer Degradation and Stability,2007(12):2223-2230. |
[33] | Toldy A;Szabo A;Novak C;Madarasz J;Toth A;Marosi G .Intrinsically flame retardant epoxy resin - Fire performance and background - Part II[J].Polymer Degradation and Stability,2008(11):2007-2013. |
[34] | Toldy, A.;Szolnoki, B.;Marosi, G. .Flame retardancy of fibre-reinforced epoxy resin composites for aerospace applications[J].Polymer Degradation and Stability,2011(3):371-376. |
[35] | Thermal, physical and flame-retardant properties of phosphorus-containing epoxy cured with cyanate ester[J].Reactive & functional polymers,2009(3):176. |
[36] | Yie Shun Chiu;Ying Ling Liu;Wen Lung Wei .Using Diethylphosphites as Thermaily Latent Cuting Agents for Epoxy Compunnds[J].Journal of Polymer Science Part A:Polymer Chemistry,2003,41:432-440. |
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