{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"采用双模板法,向正硅酸甲酯的水解体系中同时引入聚乙二醇和三嵌段共聚物,成功制备出具有双连续<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>、同时<span style=\"color:red\">孔</span>壁中分布着有序<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>的复合<span style=\"color:red\">孔</span>结构硅胶独石<span style=\"color:red\">材料</span>. 产物的比表面积高达880 m2/g, <span style=\"color:red\">大</span><span style=\"color:red\">孔</span>孔径为0.2～5 μm, <span style=\"color:red\">介</span><span style=\"color:red\">孔</span>高度集中地分布在 5 nm. 结合物理吸附、扫描电镜、粉末X射线衍射和透射电镜等表征手段,发现合成条件如原料组成、反应温度和pH值等对反应体系中凝胶化转变和相分离发生的相对速度有重要影响,进而影响产物复合<span style=\"color:red\">孔</span>结构的生成. 此外,通过对合成条件的优化,一方面增强了无机骨架的强度,另一方面降低了湿凝胶干燥过程中的毛细管压力降,有效缓和了凝胶结构在干燥过程中的开裂和变形,使复合<span style=\"color:red\">孔</span>结构硅胶独石在厘米尺度内具有良好的整体性能.","authors":[{"authorName":"刘茜","id":"1d60a65d-9cd3-44d4-a242-308ce84cda94","originalAuthorName":"刘茜"},{"authorName":"李宏旭","id":"8e6d9fa5-1f6e-4e65-a835-04a9864991e5","originalAuthorName":"李宏旭"},{"authorName":"钱斌","id":"825dd257-aaec-45f9-8d66-7e7be551422d","originalAuthorName":"钱斌"},{"authorName":"高焕新","id":"e38ae3e2-7516-4270-ac5d-b849cf5a6b35","originalAuthorName":"高焕新"},{"authorName":"王仰东","id":"c85427eb-6298-470f-a589-83dc1c6376bb","originalAuthorName":"王仰东"},{"authorName":"唐颐","id":"54ca2722-5eb1-4928-8c97-155d27c7875d","originalAuthorName":"唐颐"},{"authorName":"谢在库","id":"8407d4b1-4636-4b4b-941c-aa72095c1cf9","originalAuthorName":"谢在库"}],"doi":"","fpage":"733","id":"1e4e77cb-498a-453c-8178-508987b588b4","issue":"8","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"2ebbe1fa-4537-4e51-a4c3-780f39191965","keyword":"<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>/<span style=\"color:red\">大</span><span style=\"color:red\">孔</span><span style=\"color:red\">材料</span>","originalKeyword":"介孔/大孔材料"},{"id":"e4e9d1ee-b450-4d80-ae2e-b6c388294949","keyword":"硅胶","originalKeyword":"硅胶"},{"id":"76e1d423-77fd-49e4-a107-b63121c52e64","keyword":"独石","originalKeyword":"独石"},{"id":"18bcd919-de7d-4b79-8a9a-2a43a8448dc8","keyword":"复合<span style=\"color:red\">孔</span>","originalKeyword":"复合孔"},{"id":"1a220398-67fa-4803-a574-d9ec9570b66e","keyword":"双模板法","originalKeyword":"双模板法"}],"language":"zh","publisherId":"cuihuaxb200808012","title":"双模板法制备<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>/<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>复合<span style=\"color:red\">孔</span>结构硅胶独石","volume":"29","year":"2008"},{"abstractinfo":"以聚苯乙烯微球以及F127嵌段共聚物自组装结构为模板, 酚醛树脂低聚物为碳前驱体, 双模板法合成了<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>-<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>分级<span style=\"color:red\">孔</span>结构的炭<span style=\"color:red\">材料</span>. 对样品进行了X射线衍射(XRD)、扫描电镜(SEM) 、透射电镜(TEM) 和氮吸附-脱附测试, 并研究了样品的电化学性能. 结果表明, 利用这种简便的合成方法可以得到具有三维连通<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>以及二维有序<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>结构的分级<span style=\"color:red\">孔</span>结构炭<span style=\"color:red\">材料</span>, <span style=\"color:red\">大</span><span style=\"color:red\">孔</span>尺寸在 1&mu;m左右 , <span style=\"color:red\">介</span><span style=\"color:red\">孔</span>孔径集中分布在5nm, 比表面积为 353.8m<sup>2</sup>/g , <span style=\"color:red\">孔</span>容0.36cm<sup>3</sup>/g. 利用三电极体系测试了产品作为电化学双电层电容器电极<span style=\"color:red\">材料</span>的性能, 在50mA/g的电流密度下, 放电质量比电容 为40F/g .","authors":[{"authorName":"周颖","id":"85d9ea1f-0553-4c50-b26c-b3f283cf39c2","originalAuthorName":"周颖"},{"authorName":"王志超","id":"6cc9600d-8521-4274-9a20-2e9b782f6cce","originalAuthorName":"王志超"},{"authorName":"王春雷","id":"b76a0e7a-10f5-4a51-a47e-a1611c4c85df","originalAuthorName":"王春雷"},{"authorName":"王六平","id":"a644a76a-71f3-405b-83e3-d4e4fd05d0b0","originalAuthorName":"王六平"},{"authorName":"许钦一","id":"cd218ec5-b14e-4b27-ad02-d125447ed8c6","originalAuthorName":"许钦一"},{"authorName":"邱<span style=\"color:red\">介</span>山","id":"ed5a6800-bfe0-446f-9fd8-81757348e569","originalAuthorName":"邱介山"}],"categoryName":"|","doi":"10.3724/SP.J.1077.2011.00145","fpage":"145","id":"b1fb63a5-9995-4099-ab93-57e0ae1a5790","issue":"2","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"80f08e9e-2185-4b60-a8b6-6c29b3c2d714","keyword":"分级<span style=\"color:red\">孔</span>结构","originalKeyword":"分级孔结构"},{"id":"65b453e5-6ed2-4cb4-ae9b-d78956ef5580","keyword":"dual-templating method","originalKeyword":"dual-templating method"},{"id":"f888b275-8a41-4b52-b6e7-df18bc6d06f1","keyword":"EDLCs","originalKeyword":"EDLCs"}],"language":"zh","publisherId":"1000-324X_2011_2_8","title":"<span style=\"color:red\">大</span><span style=\"color:red\">孔</span> - <span style=\"color:red\">介</span><span style=\"color:red\">孔</span>分级<span style=\"color:red\">孔</span>结构炭<span style=\"color:red\">材料</span>制备及性能 研究","volume":"26","year":"2011"},{"abstractinfo":"以聚苯乙烯微球以及F127嵌段共聚物自组装结构为模板,酚醛树脂低聚物为碳前驱体,双模板法合成了<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>-<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>分级<span style=\"color:red\">孔</span>结构的炭<span style=\"color:red\">材料</span>.对样品进行了X射线衍射(XRD)、扫描电镜(SEM)、透射电镜(TEM)和氮吸附-脱附测试,并研究了样品的电化学性能.结果表明,利用这种简便的合成方法可以得到具有三维连通<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>以及二维有序<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>结构的分级<span style=\"color:red\">孔</span>结构炭<span style=\"color:red\">材料</span>,<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>尺寸在1μm左右,<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>孔径集中分布在5nm,比表面积为353.8m2/g,<span style=\"color:red\">孔</span>容0.36cm3/g.利用三电极体系测试了产品作为电化学双电层电容器电极<span style=\"color:red\">材料</span>的性能,在50mA/g的电流密度下,放电质量比电容为40F/g.","authors":[{"authorName":"周颖","id":"00c0fddc-1742-46f7-b02b-35531161dc0b","originalAuthorName":"周颖"},{"authorName":"王志超","id":"85a0353d-3cdd-47f6-836d-5cfc4889d65b","originalAuthorName":"王志超"},{"authorName":"王春雷","id":"8fca0773-9585-4703-8471-dc777a8791ab","originalAuthorName":"王春雷"},{"authorName":"王六平","id":"fcd983ad-a628-4f92-84fd-ad19d8b2e1cd","originalAuthorName":"王六平"},{"authorName":"许钦一","id":"1befd096-61a8-4466-ad9f-f543d34db061","originalAuthorName":"许钦一"},{"authorName":"邱<span style=\"color:red\">介</span>山","id":"6874010e-6acb-4eee-9c06-451d3668877b","originalAuthorName":"邱介山"}],"doi":"10.3724/SP.J.1077.2011.00145","fpage":"145","id":"8a44bdf1-92b9-4b25-a6a9-ae0aa367f460","issue":"2","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"8f817c99-93d0-4a2d-88ac-782d6b3d910c","keyword":"分级<span style=\"color:red\">孔</span>结构","originalKeyword":"分级孔结构"},{"id":"d8388324-e35d-4df8-97c5-71ab7e681671","keyword":"双模板","originalKeyword":"双模板"},{"id":"3d918c94-3ce1-4f75-99c9-5fe4a2e39fe2","keyword":"电化学双电层电容器","originalKeyword":"电化学双电层电容器"}],"language":"zh","publisherId":"wjclxb201102007","title":"<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>-<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>分级<span style=\"color:red\">孔</span>结构炭<span style=\"color:red\">材料</span>制备及性能研究","volume":"26","year":"2011"},{"abstractinfo":"在正己烷-三嵌段共聚物(EO_(20)-PO_(70)-EO_(20),P123)体系中合成了小孔径<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>容<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>泡沫(MCF)氧化硅<span style=\"color:red\">材料</span>.采用高分辨扫描电镜、透射电镜、N_2吸附-脱附和小角XRD,对其孔道结构、型貌、比表面积、<span style=\"color:red\">孔</span>容等进行了表征.对合成条件的研究表明,在静置条件下水解TEOS合成的样品,其比表面积、孔径、<span style=\"color:red\">孔</span>容都比在搅拌下水解合成的样品明显增加,其中<span style=\"color:red\">孔</span>容可增加68%,达到2.32cm~3/g.","authors":[{"authorName":"张海东","id":"ed50a4e2-a66a-43c8-9aa4-7865e799f0ee","originalAuthorName":"张海东"}],"doi":"","fpage":"93","id":"b7bff25f-aad2-4dad-9407-3d436f0e7ea5","issue":"22","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"2c98df0d-9069-484c-9c39-cfc9bfd837c2","keyword":"<span style=\"color:red\">介</span><span style=\"color:red\">孔</span><span style=\"color:red\">材料</span>","originalKeyword":"介孔材料"},{"id":"531dd4e9-6c00-4576-b42d-f0452406992f","keyword":"泡沫","originalKeyword":"泡沫"},{"id":"dedee159-191a-4cd9-9311-fcb04c2d9735","keyword":"正己烷","originalKeyword":"正己烷"},{"id":"29e81f26-095c-4ea8-8fdc-72d04f6cb083","keyword":"氧化硅","originalKeyword":"氧化硅"}],"language":"zh","publisherId":"cldb200922027","title":"正己烷辅助合成小孔径<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>容<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>泡沫氧化硅<span style=\"color:red\">材料</span>","volume":"23","year":"2009"},{"abstractinfo":"<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>氧化铝<span style=\"color:red\">材料</span>自合成以来,因其在催化、吸附等领域的广泛应用受到了极大的关注.随着石油化工领域大分子反应不断增加,<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>氧化铝的使用逐渐受到限制,合成具有分级结构<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>-<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>氧化铝<span style=\"color:red\">材料</span>将具有重大意义.分级结构<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>-<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>氧化铝因其同时具有<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>和<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>孔道,不仅促进了客体分子在孔道内部的传送、减小扩散阻力,而且增大了孔道的比表面积,有助于改善吸附和分离效率、延长催化寿命,因此在吸附和催化方面具有广泛的应用前景.介绍了采用单模板法、双模板法和无模板法合成分级结构<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>-<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>氧化铝<span style=\"color:red\">材料</span>,并对<span style=\"color:red\">材料</span>在吸附和催化领域的应用进行探讨,最后对分级结构<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>-<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>氧化铝<span style=\"color:red\">材料</span>的发展趋势进行了展望.","authors":[{"authorName":"张瑞琪","id":"afb8701d-6c07-41a9-974a-a62d7d07537f","originalAuthorName":"张瑞琪"},{"authorName":"王晓钟","id":"8e57980d-94ef-4092-ad33-bfeb487f93a8","originalAuthorName":"王晓钟"},{"authorName":"崔莹莹","id":"5d6a7a0a-f18e-4238-a167-54e9d80575d4","originalAuthorName":"崔莹莹"},{"authorName":"连海霞","id":"be4fc03c-fd96-491a-a309-e4940bb22ad0","originalAuthorName":"连海霞"},{"authorName":"董家鑫","id":"ede20468-4c1c-45af-9aa8-219d1142b60d","originalAuthorName":"董家鑫"},{"authorName":"白亚东","id":"575c1069-0d3a-4480-a468-97e8ccec7364","originalAuthorName":"白亚东"},{"authorName":"王政","id":"5d052d9e-d8a8-454d-b183-5bb5f548e537","originalAuthorName":"王政"}],"doi":"10.7502/j.issn.1674-3962.2017.05.09","fpage":"384","id":"dc27225a-6944-4764-937a-694444acdafe","issue":"5","journal":{"abbrevTitle":"ZGCLJZ","coverImgSrc":"journal/img/cover/中国材料进展.jpg","id":"80","issnPpub":"1674-3962","publisherId":"ZGCLJZ","title":"中国材料进展"},"keywords":[{"id":"bee9660f-ea8c-4b09-a911-8e2f38569b40","keyword":"<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>-<span style=\"color:red\">大</span><span style=\"color:red\">孔</span><span style=\"color:red\">材料</span>","originalKeyword":"介孔-大孔材料"},{"id":"1896f784-5ae7-4394-8a1c-e85e5660aae9","keyword":"氧化铝","originalKeyword":"氧化铝"},{"id":"42c5b79b-826a-4529-a33b-278b76e1f49f","keyword":"模板","originalKeyword":"模板"},{"id":"686d88a0-b41e-4065-8785-caa1db8526e1","keyword":"吸附","originalKeyword":"吸附"},{"id":"5fb5a180-4d73-4ca5-bdc4-94f7c4f511e3","keyword":"催化","originalKeyword":"催化"}],"language":"zh","publisherId":"zgcljz201705009","title":"分级结构<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>-<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>氧化铝的研究进展","volume":"36","year":"2017"},{"abstractinfo":"<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>泡沫<span style=\"color:red\">材料</span>具有超大<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>、开放式<span style=\"color:red\">孔</span>结构、孔径可调等特点,在催化剂载体、酶固定等领域具有明显的优势.手性<span style=\"color:red\">介</span><span style=\"color:red\">孔</span><span style=\"color:red\">材料</span>除了具有常规<span style=\"color:red\">介</span><span style=\"color:red\">孔</span><span style=\"color:red\">材料</span>的特点外还具有手性,因此在立体化学领域具有潜在的研究与应用价值.综述了<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>泡沫<span style=\"color:red\">材料</span>以及手性<span style=\"color:red\">介</span><span style=\"color:red\">孔</span><span style=\"color:red\">材料</span>的合成与应用.","authors":[{"authorName":"白光伟","id":"4a42d353-ffb9-4e3c-ae7b-8880d520dede","originalAuthorName":"白光伟"},{"authorName":"周国伟","id":"695140ab-7fb6-4e65-a6a5-6fc96cd92605","originalAuthorName":"周国伟"},{"authorName":"章晓彤","id":"363c8ad4-40c9-457f-be48-51c49de43410","originalAuthorName":"章晓彤"},{"authorName":"李长军","id":"e9b43e7c-6894-42e1-8608-df130c565666","originalAuthorName":"李长军"},{"authorName":"邢凡勤","id":"684d8f7e-c9ca-4f6f-9e64-54e944fb2079","originalAuthorName":"邢凡勤"}],"doi":"","fpage":"55","id":"6548c29a-1fc5-40ef-9ddd-2a4ddb1cea04","issue":"11","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"0c12c58e-4caa-49fe-b8e0-2e49cafb1e6f","keyword":"<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>泡沫","originalKeyword":"介孔泡沫"},{"id":"5e2be47f-94ac-429f-934c-ad4537354ace","keyword":"手性<span style=\"color:red\">介</span><span style=\"color:red\">孔</span><span style=\"color:red\">材料</span>","originalKeyword":"手性介孔材料"},{"id":"56c1071b-209d-4340-ab6e-64f184fde782","keyword":"酶固定","originalKeyword":"酶固定"}],"language":"zh","publisherId":"cldb200911012","title":"<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>泡沫及手性<span style=\"color:red\">介</span><span style=\"color:red\">孔</span><span style=\"color:red\">材料</span>的制备与应用","volume":"23","year":"2009"},{"abstractinfo":"<span style=\"color:red\">介</span><span style=\"color:red\">孔</span><span style=\"color:red\">材料</span>孔径调节可通过改变表面活性剂及添加辅助剂来实现,其作用机理是在<span style=\"color:red\">介</span><span style=\"color:red\">孔</span><span style=\"color:red\">材料</span>形成过程中改变胶束的大小;改变组成配比和温度等反应条件也能实现调<span style=\"color:red\">孔</span>,这可能涉及合成机理的变化.相比而言,前2种方法运用得较多,也更有效.","authors":[{"authorName":"曹渊","id":"128559ed-d51e-4ed4-998b-aa6eddc73850","originalAuthorName":"曹渊"},{"authorName":"魏红娟","id":"af5096fa-d1d7-45a6-822e-187abc4af2bb","originalAuthorName":"魏红娟"},{"authorName":"王晓","id":"e623ca81-71c0-4e7c-a16c-784476b765a9","originalAuthorName":"王晓"}],"doi":"","fpage":"27","id":"91f2aada-ff9b-44e0-9ea3-cfb852ef7d68","issue":"11","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"7d5d1d9b-a879-491f-b5d2-94c604b61ceb","keyword":"<span style=\"color:red\">介</span><span style=\"color:red\">孔</span><span style=\"color:red\">材料</span>","originalKeyword":"介孔材料"},{"id":"50683efa-b165-4b58-b25e-f0d1a61998d5","keyword":"孔径","originalKeyword":"孔径"},{"id":"385b84c2-0ee8-4b2f-b1fd-d2e7b741bff2","keyword":"表面活性剂","originalKeyword":"表面活性剂"},{"id":"29beb0c6-714c-4c1a-8eb3-96b63a066354","keyword":"辅助剂","originalKeyword":"辅助剂"}],"language":"zh","publisherId":"cldb201011006","title":"<span style=\"color:red\">介</span><span style=\"color:red\">孔</span><span style=\"color:red\">材料</span>的调<span style=\"color:red\">孔</span>方法及机理","volume":"24","year":"2010"},{"abstractinfo":"自从1992年首次报道<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>氧化硅分子筛M41S系列以来,人们采用各种商业化表面活性剂为模板,合成了多种骨架组成、丰富的有序<span style=\"color:red\">介</span>观结构、不同孔径尺寸的<span style=\"color:red\">介</span><span style=\"color:red\">孔</span><span style=\"color:red\">材料</span>,并将其应用在能源、环境、催化等诸多领域.然而,由于常规商业化模板剂的分子量大小有限,合成的<span style=\"color:red\">介</span><span style=\"color:red\">孔</span><span style=\"color:red\">材料</span>具有较小的孔径(＜8.0 nm),从而极大地限制了其面对<span style=\"color:red\">大</span>尺寸客体分子的相关应用.此外,利用常规模板剂难以合成出具有晶化墙壁的<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>金属氧化物<span style=\"color:red\">材料</span>.近年来,大分子量两亲性嵌段共聚物相继被报道用来合成新型<span style=\"color:red\">介</span><span style=\"color:red\">孔</span><span style=\"color:red\">材料</span>,本文将综述基于这种嵌段共聚物为模板剂合成各种具有<span style=\"color:red\">大</span>孔径和晶化墙壁<span style=\"color:red\">介</span><span style=\"color:red\">孔</span><span style=\"color:red\">材料</span>的研究进展.","authors":[{"authorName":"罗维","id":"bdc5c3f3-8263-4a05-bd23-36ae2eae5bb3","originalAuthorName":"罗维"},{"authorName":"魏晶","id":"94023c62-e990-4b4e-b30e-cfad4a10fe29","originalAuthorName":"魏晶"},{"authorName":"邓勇辉","id":"3a777802-0fd7-436c-8f3f-6df49c0f99a8","originalAuthorName":"邓勇辉"},{"authorName":"李宇慧","id":"46302ab0-1d1e-49e7-a02e-edb7d1afd985","originalAuthorName":"李宇慧"},{"authorName":"王连军","id":"7f93853d-58f4-46c9-979a-26ca58f8257e","originalAuthorName":"王连军"},{"authorName":"赵涛","id":"a5cd74bc-8486-4e59-8951-1187b152b732","originalAuthorName":"赵涛"},{"authorName":"江莞","id":"dc4aa287-abb8-4edd-a7cd-e3f000bdcae9","originalAuthorName":"江莞"}],"doi":"10.15541/jim20160297","fpage":"1","id":"a085ed7e-272e-4a49-82fd-795420ab5a51","issue":"1","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"cc91947c-a66d-4eb4-b70d-043bb86ec10b","keyword":"<span style=\"color:red\">介</span><span style=\"color:red\">孔</span><span style=\"color:red\">材料</span>","originalKeyword":"介孔材料"},{"id":"be83891a-81cb-4510-8d31-19fcaa70441e","keyword":"嵌段共聚物","originalKeyword":"嵌段共聚物"},{"id":"41295c0d-008f-4830-8ce4-3e4e2698dbd5","keyword":"软模板","originalKeyword":"软模板"},{"id":"6732aa88-19fd-4b69-b8d6-e11d2bbbda3b","keyword":"自组装","originalKeyword":"自组装"},{"id":"5693cca0-52a2-41f7-ae3e-1a567f270391","keyword":"综述","originalKeyword":"综述"}],"language":"zh","publisherId":"wjclxb201701001","title":"新型两亲性嵌段共聚物导向合成有序<span style=\"color:red\">大</span>孔径<span style=\"color:red\">介</span><span style=\"color:red\">孔</span><span style=\"color:red\">材料</span>的研究进展","volume":"32","year":"2017"},{"abstractinfo":"综述了近年来<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>分子筛催化<span style=\"color:red\">材料</span>制备的研究成果及其在催化领域特别是精细化学品合成中的应用. 文章分为两部分,分别讨论了<span style=\"color:red\">介</span><span style=\"color:red\">孔</span><span style=\"color:red\">材料</span>本身作为催化剂以及<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>主客体催化<span style=\"color:red\">材料</span>的应用. ","authors":[{"authorName":"李亮","id":"a0537bfd-c13e-45c0-bbd4-6dec35059150","originalAuthorName":"李亮"},{"authorName":"施剑林","id":"81ef9895-a281-484a-aefb-39ac408c0c5b","originalAuthorName":"施剑林"}],"doi":"","fpage":"159","id":"8fa96ba1-b556-4636-b65b-5a005234ed15","issue":"2","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"0f0c28e6-ac7e-4d4b-be4c-5824c959fa7b","keyword":"<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>分子筛","originalKeyword":"介孔分子筛"},{"id":"8b3a91fd-1b08-4752-8960-f7f8da083b1a","keyword":"<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>主客体<span style=\"color:red\">材料</span>","originalKeyword":"介孔主客体材料"},{"id":"24f131ee-d503-4f20-a5ee-c1d3997f2dea","keyword":"催化","originalKeyword":"催化"},{"id":"bc588473-1fd8-40ef-be15-2e92ac37cf28","keyword":"应用","originalKeyword":"应用"}],"language":"zh","publisherId":"cuihuaxb200502015","title":"<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>与<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>主客体<span style=\"color:red\">材料</span>在催化领域的应用","volume":"26","year":"2005"},{"abstractinfo":"以嵌段共聚物为模板剂,甲酰胺为氮源,结合溶胶凝胶法制备了具有可见光活性的<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>-<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>氮掺杂二氧化钛(N-TiO2)<span style=\"color:red\">材料</span>.通过X射线衍射、低温N2吸附-脱附、扫描电镜、紫外-可见吸收光谱等手段,考察了嵌段共聚物对样品微结构和可见光活性的影响.结果表明,样品主要以锐钛矿相和板钛矿相混合形式存在;改变嵌段共聚物的浓度,可以制得晶粒粒径9～12 nm,孔径10～14 nm,禁带宽度2.98～2.76 eV的<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>-<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>N-TiO2,且随着模板剂加入量的增加,<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>孔径增大,<span style=\"color:red\">孔</span>壁增厚.对甲基橙溶液的室内自然光降解实验表明,<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>-<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>N-TiO2具有良好的光催化活性,随着嵌段共聚物加入量的增加,样品对甲基橙的降解时间缩短,降解率提高.","authors":[{"authorName":"景文珩","id":"0e99a4e6-9814-4898-ae00-93cb2101467f","originalAuthorName":"景文珩"},{"authorName":"王韦岗","id":"6ce3d92b-0732-4ac1-af28-503916014407","originalAuthorName":"王韦岗"},{"authorName":"邢卫红","id":"af912372-9764-421c-9b74-1b87c757df03","originalAuthorName":"邢卫红"}],"doi":"","fpage":"426","id":"67293066-9684-4e48-9104-6b5c60859ad4","issue":"5","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"923628b3-bc87-4e37-9419-3109ccfab4bb","keyword":"嵌段共聚物","originalKeyword":"嵌段共聚物"},{"id":"f0cfdfbb-3b1a-4921-b019-d91ab5876ae1","keyword":"甲酰胺","originalKeyword":"甲酰胺"},{"id":"7352b7b5-469c-4f9a-a2c6-46bcd8148185","keyword":"二氧化钛","originalKeyword":"二氧化钛"},{"id":"a1f38f04-def6-4572-b472-1b8fbc183f65","keyword":"氮掺杂","originalKeyword":"氮掺杂"},{"id":"7acb9160-03bf-4cc3-832c-b17a06fabea7","keyword":"<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>-<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>","originalKeyword":"大孔-介孔"},{"id":"e7cbf5f6-befb-450c-9a30-e10533a4c36d","keyword":"甲基橙","originalKeyword":"甲基橙"},{"id":"efe44af9-03f3-40b5-8918-dab952608c30","keyword":"光催化降解","originalKeyword":"光催化降解"}],"language":"zh","publisherId":"cuihuaxb200905011","title":"<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>-<span style=\"color:red\">介</span><span style=\"color:red\">孔</span>氮掺杂二氧化钛的制备及其光催化性能测试","volume":"30","year":"2009"}],"totalpage":6550,"totalrecord":65492}