{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"通过合成一种新的含<span style=\"color:red\">二</span>酰胺键的单体,将其与硫化钠进行常压溶液缩聚,合成出了间位聚芳硫醚酰胺酰胺(m-PPSAA),通过红外、核磁证实了其化学结构,用DSC、TG等手段<span style=\"color:red\">对</span>m-PPSAA的热性能进行了表征,结果表明聚合物具有优良的热性能,通过X射线衍射表明m-PPSAA为结晶型聚合物,通过溶解性试验表明m-PPSAA能溶解于DMF、DMSO、NMP等溶剂,比PPS的溶解性好.","authors":[{"authorName":"张刚","id":"dd66a6a9-9c1b-46a9-8f95-e18ba2931269","originalAuthorName":"张刚"},{"authorName":"张美林","id":"c8b6da71-8f60-410c-8440-b8fefcc77a87","originalAuthorName":"张美林"},{"authorName":"龙盛如","id":"fc1f74ed-73e2-4e46-a0be-d30776dba4be","originalAuthorName":"龙盛如"},{"authorName":"杨杰","id":"d1e951cd-53dd-4294-9b6d-706139618d90","originalAuthorName":"杨杰"}],"doi":"","fpage":"1316","id":"00ddfec9-b8be-4157-9676-d21889c10095","issue":"8","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"260c9ee3-e5ea-45be-85c2-b3d7998483fe","keyword":"<span style=\"color:red\">3,3</span>'-<span style=\"color:red\">双</span>(<span style=\"color:red\">对</span><span style=\"color:red\">氟</span><span style=\"color:red\">苯甲酰基</span>)<span style=\"color:red\">二</span><span style=\"color:red\">氨基</span><span style=\"color:red\">苯</span>","originalKeyword":"3,3'-双(对氟苯甲酰基)二氨基苯"},{"id":"718610f5-c334-4f8f-b2b3-47b9a5b29109","keyword":"间位聚芳硫醚酰胺酰胺","originalKeyword":"间位聚芳硫醚酰胺酰胺"},{"id":"6527b7c3-a358-46bd-8896-bc93d54ed8f9","keyword":"溶解性","originalKeyword":"溶解性"}],"language":"zh","publisherId":"gncl200908022","title":"常压法间位聚芳硫醚酰胺酰胺的合成及表征","volume":"40","year":"2009"},{"abstractinfo":"本文在CuCl催化剂的作用下,利用<span style=\"color:red\">3</span>-羟基苯胺(<span style=\"color:red\">3</span>-HA)和<span style=\"color:red\">3</span>-<span style=\"color:red\">氨基</span>卤化物(<span style=\"color:red\">3</span>-AH)进行缩合醚化反应,一步法制得了高纯度的<span style=\"color:red\">3,3</span>'-<span style=\"color:red\">二</span><span style=\"color:red\">氨基</span><span style=\"color:red\">二</span><span style=\"color:red\">苯</span>醚(<span style=\"color:red\">3,3</span>'-DADPE).运用1H-NMR,13C-NMR,FTIR和熔点测试技术<span style=\"color:red\">对</span>其进行了表征.另外,在 N,N-<span style=\"color:red\">二</span>甲基乙酰胺(DMAC)溶剂中还与均<span style=\"color:red\">苯</span>四甲酸<span style=\"color:red\">二</span>酐(PMDA)进行了缩合反应,制得了新型聚酰胺酸<span style=\"color:red\">3,3</span>'-DADPE/PMDA-PAA,并在热的作用下,脱水环化成聚酰亚胺<span style=\"color:red\">3,3</span>'-DADPE/PMDA-PI.","authors":[{"authorName":"虞鑫海","id":"8744106a-0e9d-4849-bb71-0ac3e8ffaeb0","originalAuthorName":"虞鑫海"},{"authorName":"胡志强","id":"df027f83-16d6-46ed-812f-98534cede5d4","originalAuthorName":"胡志强"}],"doi":"10.3969/j.issn.1009-9239.2001.04.003","fpage":"13","id":"77e4ede3-8e61-4c48-9cbf-7423fc5caf4b","issue":"4","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"1137f76a-9d25-4ff4-8cd3-bb5608df92ba","keyword":"<span style=\"color:red\">3,3</span>'-<span style=\"color:red\">二</span><span style=\"color:red\">氨基</span><span style=\"color:red\">二</span><span style=\"color:red\">苯</span>醚","originalKeyword":"3,3'-二氨基二苯醚"},{"id":"a6fcffaf-5042-4561-b87a-4cd4d5d96a02","keyword":"聚酰亚胺","originalKeyword":"聚酰亚胺"},{"id":"bfb1202b-135b-441c-bd11-0711735a9a3f","keyword":"合成","originalKeyword":"合成"},{"id":"374d1cf0-c24e-4fba-a458-226f43c8d856","keyword":"应用","originalKeyword":"应用"}],"language":"zh","publisherId":"jycltx200104003","title":"<span style=\"color:red\">3,3</span>'-<span style=\"color:red\">二</span><span style=\"color:red\">氨基</span><span style=\"color:red\">二</span><span style=\"color:red\">苯</span>醚的合成及其聚酰亚胺","volume":"34","year":"2001"},{"abstractinfo":"以4.4'-<span style=\"color:red\">二</span><span style=\"color:red\">氨基</span><span style=\"color:red\">二</span><span style=\"color:red\">苯</span>醚为原料,经乙酰化、硝化、碱解、还原、中和五步反应合成<span style=\"color:red\">3,3</span>',4,4'-四<span style=\"color:red\">氨基</span><span style=\"color:red\">二</span><span style=\"color:red\">苯</span>醚,总收率为52.8%,并用FT-IR及熔点测试技术<span style=\"color:red\">对</span>其进行了表征.结果表明,<span style=\"color:red\">3,3</span>',4,4'-四<span style=\"color:red\">氨基</span><span style=\"color:red\">二</span><span style=\"color:red\">苯</span>醚具有较高的纯度,在多聚磷酸与五氧化<span style=\"color:red\">二</span>磷的体系下,进一步与<span style=\"color:red\">二</span>酸聚合可获得高分子量的聚苯并咪唑.有望在未来兴起的燃料电池膜制作领域具有广阔的应用前景.","authors":[{"authorName":"徐俊","id":"2cd8de99-420f-426d-971c-61720076cb70","originalAuthorName":"徐俊"},{"authorName":"虞鑫海","id":"269e552c-f6f4-45dd-9c81-d8a86d67f507","originalAuthorName":"虞鑫海"},{"authorName":"张誉川","id":"ecf3a21d-9991-4146-92ff-504ccd3a969e","originalAuthorName":"张誉川"},{"authorName":"黄斌全","id":"e187f4da-86dd-4a55-91ce-eca8e0b5b843","originalAuthorName":"黄斌全"},{"authorName":"李波罗","id":"629e157d-23fe-4cc8-8b0b-df6ad8b4b169","originalAuthorName":"李波罗"}],"doi":"10.3969/j.issn.1009-9239.2009.03.008","fpage":"31","id":"14156b58-9dd5-4884-b2c8-a0681db6fc59","issue":"3","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"1e98fc65-985b-428a-9d5a-884e1a2aa48b","keyword":"4,4'-<span style=\"color:red\">二</span>乙酰<span style=\"color:red\">氨基</span><span style=\"color:red\">二</span><span style=\"color:red\">苯</span>醚:<span style=\"color:red\">3,3</span>'-<span style=\"color:red\">二</span>硝基-4,4'-<span style=\"color:red\">二</span>乙酰<span style=\"color:red\">氨基</span><span style=\"color:red\">二</span><span style=\"color:red\">苯</span>醚","originalKeyword":"4,4'-二乙酰氨基二苯醚:3,3'-二硝基-4,4'-二乙酰氨基二苯醚"},{"id":"06d63374-0aff-4030-b5d6-e79e1389478c","keyword":"<span style=\"color:red\">3,3</span>'-<span style=\"color:red\">二</span>硝基-4.4'-<span style=\"color:red\">二</span><span style=\"color:red\">氨基</span><span style=\"color:red\">二</span><span style=\"color:red\">苯</span>醚","originalKeyword":"3,3'-二硝基-4.4'-二氨基二苯醚"},{"id":"47c6f1c3-2237-4a7b-bb6a-4f23c650abe8","keyword":"<span style=\"color:red\">3,3</span>',4.4'-四<span style=\"color:red\">氨基</span><span style=\"color:red\">二</span><span style=\"color:red\">苯</span>醚","originalKeyword":"3,3',4.4'-四氨基二苯醚"},{"id":"6e9770d5-b045-4c62-900b-9f2090f4d013","keyword":"聚苯并咪唑树脂","originalKeyword":"聚苯并咪唑树脂"},{"id":"47619561-bb27-4506-919a-498e578e5b2b","keyword":"合成","originalKeyword":"合成"},{"id":"4962e752-5e2d-43b7-9559-6e5258693a61","keyword":"表征","originalKeyword":"表征"}],"language":"zh","publisherId":"jycltx200903008","title":"<span style=\"color:red\">3,3</span>',4,4'-四<span style=\"color:red\">氨基</span><span style=\"color:red\">二</span><span style=\"color:red\">苯</span>醚的合成及其聚苯并咪唑树脂的制备","volume":"42","year":"2009"},{"abstractinfo":"由硝基<span style=\"color:red\">苯</span>甲醛和硝基苯乙酮经Claisen-Schmidt缩合制得<span style=\"color:red\">3,3</span>'-<span style=\"color:red\">二</span>硝基查尔酮,再用FeCl<span style=\"color:red\">3</span>-NH2NH2·H2O-C体系将其还原成<span style=\"color:red\">3,3</span>'-<span style=\"color:red\">二</span><span style=\"color:red\">氨基</span>查尔酮.所得产品经元素分析、熔点、IR和1H NMR测试确认,讨论了影响产品收率的因素.收率为78.6%.","authors":[{"authorName":"王维","id":"6f698702-7293-4b39-af79-b15e7fce02e6","originalAuthorName":"王维"},{"authorName":"吴群绒","id":"f7b957a8-ffa5-46b2-8f6a-f6083a9b66cd","originalAuthorName":"吴群绒"},{"authorName":"杨志兰","id":"490c0721-f53e-4b6c-8a6b-b74b0626e19a","originalAuthorName":"杨志兰"},{"authorName":"沈长虹","id":"f1705067-6831-4b24-818c-663b31f894c2","originalAuthorName":"沈长虹"},{"authorName":"张爱清","id":"748fe7a4-825c-4a61-9a66-cc15297ee4b1","originalAuthorName":"张爱清"},{"authorName":"韦海洋","id":"b093297f-2e79-4186-8c67-2f8ba05faa39","originalAuthorName":"韦海洋"}],"doi":"10.3969/j.issn.1000-0518.2006.04.025","fpage":"447","id":"e00c5238-096d-449b-b809-d7007cd856d5","issue":"4","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"0b52362b-991f-45ae-b1d4-2b7a95c0c893","keyword":"光敏性<span style=\"color:red\">二</span>胺","originalKeyword":"光敏性二胺"},{"id":"466d43da-bfbd-494e-9879-fde7144bb7cc","keyword":"查尔酮","originalKeyword":"查尔酮"},{"id":"84d4e754-1356-4298-87f0-b9960cef44c1","keyword":"聚酰亚胺","originalKeyword":"聚酰亚胺"},{"id":"80e70311-5b87-48d6-9fb2-7769871ccb08","keyword":"合成","originalKeyword":"合成"}],"language":"zh","publisherId":"yyhx200604025","title":"<span style=\"color:red\">3,3</span>'-<span style=\"color:red\">二</span><span style=\"color:red\">氨基</span>查尔酮的合成","volume":"23","year":"2006"},{"abstractinfo":"4,4'-<span style=\"color:red\">二</span>羟基-<span style=\"color:red\">3,3</span>',5,5'-四甲基联苯(TMBP)、4-氯硝基<span style=\"color:red\">苯</span>(4CNB)和碳酸钾在N,N-<span style=\"color:red\">二</span>甲基甲酰胺(DMF)和甲苯的混合溶剂体系中回流反应,合成得到了4,4'-<span style=\"color:red\">双</span>(4-硝基<span style=\"color:red\">苯</span>氧基)-<span style=\"color:red\">3,3</span>',5,5'-四甲基联苯(BNTMBP);随后,在Pd/C-水合肼的还原体系中,被进一步还原,得到了4,4'-<span style=\"color:red\">双</span>(4-<span style=\"color:red\">氨基</span><span style=\"color:red\">苯</span>氧基)-<span style=\"color:red\">3,3</span>',5,5'-四甲基联苯(BATMBP).利用差示扫描量热计(DSC)、傅立叶转换红外光谱仪(FT-IR)等仪器,<span style=\"color:red\">对</span>其进行了表征.另外,将所得到的4,4'-<span style=\"color:red\">双</span>(4-<span style=\"color:red\">氨基</span><span style=\"color:red\">苯</span>氧基)-<span style=\"color:red\">3,3</span>',5,5'-四甲基联苯(BATMBP)与均<span style=\"color:red\">苯</span>四甲酸<span style=\"color:red\">二</span>酐(PMDA)在强极性非质子有机溶剂中进行聚合反应,得到了粘稠状的聚酰胺酸(BATMBP/PMDA-PAA)溶液,涂膜、热亚胺化,获得了相应的聚酰亚胺(BATMBP/PMDA-PI)薄膜,并<span style=\"color:red\">对</span>其性能进行了研究.","authors":[{"authorName":"虞鑫海","id":"fbf8e0bf-bdea-472b-ba46-da7ec4a180c1","originalAuthorName":"虞鑫海"},{"authorName":"刘万章","id":"dd5d9806-56c3-4a0d-9144-895fd5f27292","originalAuthorName":"刘万章"},{"authorName":"徐永芬","id":"c2f49e38-aa03-42e3-9e5f-494280e03a36","originalAuthorName":"徐永芬"},{"authorName":"傅菊荪","id":"65599ae7-cce3-4725-9f1e-1e354d025b2f","originalAuthorName":"傅菊荪"},{"authorName":"赵炯心","id":"ab3c7c15-6a42-4361-89eb-6e9d86cec019","originalAuthorName":"赵炯心"}],"doi":"10.3969/j.issn.1009-9239.2008.04.006","fpage":"16","id":"aab47a41-7386-4235-a458-cdf6d9388ac5","issue":"4","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"94b7aba8-f157-43e3-a3c1-f3f01e3f5563","keyword":"4,4'-<span style=\"color:red\">双</span>(4-硝基<span style=\"color:red\">苯</span>氧基)-<span style=\"color:red\">3,3</span>',5,5'-四甲基联苯","originalKeyword":"4,4'-双(4-硝基苯氧基)-3,3',5,5'-四甲基联苯"},{"id":"6d2f875c-f6ee-4477-8f63-c21ee4d2b74e","keyword":"4,4'-<span style=\"color:red\">双</span>(4-<span style=\"color:red\">氨基</span><span style=\"color:red\">苯</span>氧基)-<span style=\"color:red\">3,3</span>',5,5'-四甲基联苯","originalKeyword":"4,4'-双(4-氨基苯氧基)-3,3',5,5'-四甲基联苯"},{"id":"f7a3ea5f-d7fe-452a-afec-124755459dc5","keyword":"聚酰亚胺","originalKeyword":"聚酰亚胺"},{"id":"72747781-de3e-4dd1-a08b-4d1672651fc6","keyword":"合成","originalKeyword":"合成"},{"id":"d5fd06c9-9d44-4e17-a3ec-6c7f1a649470","keyword":"性能","originalKeyword":"性能"}],"language":"zh","publisherId":"jycltx200804006","title":"4,4'-<span style=\"color:red\">双</span>(4-<span style=\"color:red\">氨基</span><span style=\"color:red\">苯</span>氧基)- <span style=\"color:red\">3,3</span>',5,5'-四甲基联苯及其聚酰亚胺的合成与性能研究","volume":"41","year":"2008"},{"abstractinfo":"在酸催化条件下,利用2,6-<span style=\"color:red\">二</span>甲基苯胺和甲醛为原料,一步法制得了高纯度的<span style=\"color:red\">3,3</span>',5,5'-四甲基-4,4'-<span style=\"color:red\">二</span><span style=\"color:red\">氨基</span><span style=\"color:red\">二</span><span style=\"color:red\">苯</span>甲烷(AMD),运用H-NMR,FTIR,HPLC和熔点测试技术<span style=\"color:red\">对</span>其进行了表征.结果表明:合成的AMD纯度较高;AMD和BTDA聚合制得较高分子量的聚酰胺酸,经化学亚胺化得到聚酰亚胺(PI),将其溶解后涂覆制得的聚酰亚胺薄膜有一定的溶解性、成膜性及较好的力学性能.","authors":[{"authorName":"石玉界","id":"94165d2b-484e-43a2-b378-6bfde725e2d4","originalAuthorName":"石玉界"},{"authorName":"范和平","id":"fdeedb63-794e-44ff-b58c-530ad11a818f","originalAuthorName":"范和平"}],"doi":"10.3969/j.issn.1009-9239.2008.06.009","fpage":"34","id":"cd6d4591-79c9-4301-915c-ec0e08db4587","issue":"6","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"5d5eebb6-f1f7-4f77-833d-0004146be2a7","keyword":"<span style=\"color:red\">3,3</span>',5,5'-四甲基-4,4'-<span style=\"color:red\">二</span><span style=\"color:red\">氨基</span><span style=\"color:red\">二</span><span style=\"color:red\">苯</span>甲烷","originalKeyword":"3,3',5,5'-四甲基-4,4'-二氨基二苯甲烷"},{"id":"f0663258-d482-40f0-8455-1953596d69e0","keyword":"聚酰亚胺","originalKeyword":"聚酰亚胺"},{"id":"64efcd7d-2ff4-476e-8d4e-7a85ab7911bf","keyword":"2L-FCCL","originalKeyword":"2L-FCCL"}],"language":"zh","publisherId":"jycltx200806009","title":"<span style=\"color:red\">3,3</span>',5,5'-四甲基-4,4'-<span style=\"color:red\">二</span><span style=\"color:red\">氨基</span><span style=\"color:red\">二</span><span style=\"color:red\">苯</span>甲烷及其聚酰亚胺的合成与应用","volume":"41","year":"2008"},{"abstractinfo":"4,4'-<span style=\"color:red\">二</span>羟基联苯(DHBP)和浓硝酸在有机溶剂中反应,合成得到了<span style=\"color:red\">3,3</span>'-<span style=\"color:red\">二</span>硝基-4,4'-<span style=\"color:red\">二</span>羟基联苯(DNDHBP).随后,在Pd/C-水合肼的还原体系中,被进一步还原,得到了<span style=\"color:red\">3,3</span>'-<span style=\"color:red\">二</span><span style=\"color:red\">氨基</span>-4,4'-<span style=\"color:red\">二</span>羟基联苯(DADHBP).将得到的<span style=\"color:red\">3,3</span>'-<span style=\"color:red\">二</span><span style=\"color:red\">氨基</span>-4,4'-<span style=\"color:red\">二</span>羟基联苯(DADHBP)与<span style=\"color:red\">3,3</span>',4,4'-四羧基<span style=\"color:red\">二</span><span style=\"color:red\">苯</span>醚<span style=\"color:red\">二</span>酐(ODPA)在强极性非质子有机溶剂中进行聚合反应,得到了粘稠状的聚酰胺酸(DADHBP/ODPA-PAA)溶液,涂膜,热亚胺化,获得了相应的聚酰亚胺(DADHBP/ODPA-PI)薄膜.利用差示扫描量热计(DSC)、傅立叶转换红外光谱仪(FT-IR)、紫外一可见分光光度计等仪器,<span style=\"color:red\">对</span>它们的性能进行了研究.结果表明,制成的聚酰亚胺薄膜具有良好的疏水性、光学性能和力学性能.","authors":[{"authorName":"费斐","id":"9214d603-bdec-4166-855b-85ef54b908f5","originalAuthorName":"费斐"},{"authorName":"徐永芬","id":"9899e213-f1da-479b-b4de-99f37e25f7c4","originalAuthorName":"徐永芬"},{"authorName":"傅菊荪","id":"c44f33f5-c8a9-4bf6-b2ef-018ff6909e22","originalAuthorName":"傅菊荪"},{"authorName":"虞鑫海","id":"cfc52400-31bd-4b38-8ecc-1eca07a8b194","originalAuthorName":"虞鑫海"}],"doi":"10.3969/j.issn.1009-9239.2009.06.004","fpage":"12","id":"94117272-cbba-4f5a-9631-7b01d4b93cd6","issue":"6","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"017fff79-1a5d-48e6-8992-7349a30c90b9","keyword":"<span style=\"color:red\">3,3</span>'-<span style=\"color:red\">二</span>硝基-4,4'-<span style=\"color:red\">二</span>羟基联苯","originalKeyword":"3,3'-二硝基-4,4'-二羟基联苯"},{"id":"2eba9dcd-06fe-467f-8df9-1126027b53bf","keyword":"<span style=\"color:red\">3,3</span>'-<span style=\"color:red\">二</span><span style=\"color:red\">氨基</span>-4,4'-<span style=\"color:red\">二</span>羟基联苯","originalKeyword":"3,3'-二氨基-4,4'-二羟基联苯"},{"id":"d54364aa-29c7-41fe-b84b-23f33a381fb7","keyword":"<span style=\"color:red\">3,3</span>',4,4'-四羧基<span style=\"color:red\">二</span><span style=\"color:red\">苯</span>醚<span style=\"color:red\">二</span>酐","originalKeyword":"3,3',4,4'-四羧基二苯醚二酐"},{"id":"0155f72b-42b9-417b-8d7b-2ad2f85842aa","keyword":"聚酰亚胺","originalKeyword":"聚酰亚胺"},{"id":"a207bf45-7607-4d7f-a6ba-b4708ed8bd41","keyword":"合成","originalKeyword":"合成"},{"id":"756966e9-bad1-4da9-b98e-6af54aebf981","keyword":"性能","originalKeyword":"性能"}],"language":"zh","publisherId":"jycltx200906004","title":"<span style=\"color:red\">3,3</span>'-<span style=\"color:red\">二</span><span style=\"color:red\">氨基</span>-4,4'-<span style=\"color:red\">二</span>羟基联苯及其聚酰亚胺的合成与性能研究","volume":"42","year":"2009"},{"abstractinfo":"研究了N,N,N',N'-四缩水甘油基-4,4'-<span style=\"color:red\">二</span><span style=\"color:red\">氨基</span><span style=\"color:red\">二</span><span style=\"color:red\">苯</span>甲烷(TGDDM)与含活性基团羟基的固化剂<span style=\"color:red\">3,3</span>'-<span style=\"color:red\">二</span><span style=\"color:red\">氨基</span>-4,4'-<span style=\"color:red\">二</span>羟基联苯(DADHBP)的固化反应动力学.通过<span style=\"color:red\">对</span>固化体系的差示扫描量热法(DSC)的测试数据进行分析,利用OzaWa、Kissinger、Crane和Arrhenius方程对此进行了固化反应动力学研究.计算得到了固化体系的动力学参数:反应活化能Ea、反应级数n、频率因子A及峰温时的反应速率常数kpo结果表明,在TGDDM/DADHBP体系的固化反应过程中,DSC曲线出现了两个明显的放热峰,低温放热峰所对应的平均反应活化能(Ea1)为110.19 kJ/mol,反应级数(n1)为0.94;高温放热峰所对应的平均反应活化能(Ea2)为143.89 kJ/mol,反应级数(n2)为0.95.","authors":[{"authorName":"徐永芬","id":"ccca9421-0dbd-4e62-87e7-105c2ea8e586","originalAuthorName":"徐永芬"},{"authorName":"虞鑫海","id":"5cbdeaa8-d6bd-4075-8501-bdda7474aa70","originalAuthorName":"虞鑫海"},{"authorName":"赵炯心","id":"023bc6be-9295-4e94-b0b6-aecc2754ee0c","originalAuthorName":"赵炯心"},{"authorName":"傅菊荪","id":"c6fcaf92-34f5-4f25-a646-0292cc1f9580","originalAuthorName":"傅菊荪"}],"doi":"10.3969/j.issn.1009-9239.2010.05.015","fpage":"57","id":"362ef622-02fa-4c36-b383-e360464c59ad","issue":"5","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"23951539-c8ff-4aa6-ad4f-82cc126aa48d","keyword":"N,N,N',N'-四缩水甘油基-4,4'-<span style=\"color:red\">二</span><span style=\"color:red\">氨基</span><span style=\"color:red\">二</span><span style=\"color:red\">苯</span>甲烷","originalKeyword":"N,N,N',N'-四缩水甘油基-4,4'-二氨基二苯甲烷"},{"id":"c93f4b27-1294-42bd-8004-4021292d597d","keyword":"<span style=\"color:red\">3,3</span>'-<span style=\"color:red\">二</span><span style=\"color:red\">氨基</span>-4,4'-<span style=\"color:red\">二</span>羟基联苯","originalKeyword":"3,3'-二氨基-4,4'-二羟基联苯"},{"id":"a6ca0e60-585c-4ec6-8ab3-2beca2d696be","keyword":"固化反应动力学","originalKeyword":"固化反应动力学"},{"id":"1c4434ba-8943-4551-a654-66cc394fe3be","keyword":"差示扫描量热法","originalKeyword":"差示扫描量热法"}],"language":"zh","publisherId":"jycltx201005015","title":"TGDDM/<span style=\"color:red\">3,3</span>'-<span style=\"color:red\">二</span><span style=\"color:red\">氨基</span>-4,4'-<span style=\"color:red\">二</span>羟基联苯固化反应动力学研究","volume":"43","year":"2010"},{"abstractinfo":"测试了<span style=\"color:red\">3,3</span>-<span style=\"color:red\">双</span>(N-辛基-2-甲基吲哚)邻<span style=\"color:red\">苯</span><span style=\"color:red\">二</span>甲内酯荧烷(ck-16)在显色前后的13C NMR谱图,揭示了其显色前后的结构变化及其显色机理.利用紫外可见吸收光谱法研究了ck-16在乙醇溶液中与不同显色剂作用后的光谱性质,测定了其与常用显色剂间的络合比和不稳定常数,并进一步研究了外界条件的改变<span style=\"color:red\">对</span>ck-16在乙醇溶液中与特定显色剂作用后显色性能的影响.研究发现,亲电阳离子进攻ck-16荧烷分子的<span style=\"color:red\">苯</span>酞环,使<span style=\"color:red\">苯</span>酞环断裂,推电子的N原子和吸电子的羰基O原子之间建立π电子迁移通道使分子显色.在乙醇介质中,ck-16与不同显色剂作用后具有不同的显色效果;对路易斯酸和有机弱酸这两类显色剂而言,ck-16与所测的四种显色剂(FeCl<span style=\"color:red\">3</span>、草酸、CuCl2、水杨酸)均以1:1的形式络合,ck-16与Fe<span style=\"color:red\">3</span>+的不稳定常数最小,结合最稳定,草酸其次,与Cu2+的相近,ck-16与水杨酸的结合最弱;在乙醇中,放置时间<span style=\"color:red\">对</span>ck-16/FeCl<span style=\"color:red\">3</span>和ck-16/H2C2O4两个体系的吸光度影响不大,但两体系表现出随水含量变化不同的敏感性,ck-16/FeCl<span style=\"color:red\">3</span>体系具有比ck-16/H2C2O4体系更为灵敏和快速的水致褪色性能.","authors":[{"authorName":"刘付永","id":"b9f323bd-3678-4423-8220-5a997972243e","originalAuthorName":"刘付永"},{"authorName":"冯丹","id":"38094542-ec0b-4b55-aad6-a843c7502e07","originalAuthorName":"冯丹"},{"authorName":"武永平","id":"05fd1341-4d8f-4b3f-90bb-5cc3e841a3c8","originalAuthorName":"武永平"},{"authorName":"吴佳娜","id":"63808ecc-ef55-4a03-bdd4-2140bf0a8077","originalAuthorName":"吴佳娜"},{"authorName":"董川","id":"fa55b6eb-3437-4fc5-b9dc-d63a5592cc23","originalAuthorName":"董川"}],"doi":"10.11944/j.issn.1000-0518.2015.12.150170","fpage":"1437","id":"da7fa89d-7727-4260-ad4f-615b1010b7c3","issue":"12","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"4f3dfd71-9307-4dc0-a1b9-7c4d52b05e9a","keyword":"荧烷染料","originalKeyword":"荧烷染料"},{"id":"f8c7d8fd-dce2-480e-ad7e-158b083e0ae0","keyword":"显色剂","originalKeyword":"显色剂"},{"id":"57150f68-b7da-44ad-8f95-3adb992ec09b","keyword":"显色性能","originalKeyword":"显色性能"},{"id":"4ceecd85-7442-4e6e-8466-18bd6b114456","keyword":"紫外可见光谱","originalKeyword":"紫外可见光谱"}],"language":"zh","publisherId":"yyhx201512014","title":"<span style=\"color:red\">3,3</span>-<span style=\"color:red\">双</span>(N-辛基-2-甲基吲哚)邻<span style=\"color:red\">苯</span><span style=\"color:red\">二</span>甲内酯荧烷在乙醇溶液中的显色性能","volume":"32","year":"2015"},{"abstractinfo":"在N,N-<span style=\"color:red\">二</span>甲基甲酰胺和甲苯的混合溶剂体系中,4,4'-<span style=\"color:red\">二</span><span style=\"color:red\">氟</span><span style=\"color:red\">二</span><span style=\"color:red\">苯</span>甲酮(DFBP)与<span style=\"color:red\">3</span>-<span style=\"color:red\">氨基</span>苯酚(<span style=\"color:red\">3</span>AP)在无水碳酸钾的作用下发生化学反应,合成得到了4,4'-<span style=\"color:red\">双</span>(<span style=\"color:red\">3</span>-<span style=\"color:red\">氨基</span><span style=\"color:red\">苯</span>氧基)<span style=\"color:red\">二</span><span style=\"color:red\">苯</span>甲酮(443BAPOBP)单体.通过熔点测试、高效注注液相色谱(HPLC)、傅立叶红外(FT-IR)以及元素分析<span style=\"color:red\">对</span>443BAPOBP进行了表征,并且在N,N-<span style=\"color:red\">二</span>甲基乙酰胺溶剂中,443BAPOBP与均<span style=\"color:red\">苯</span>四甲酸<span style=\"color:red\">二</span>酐(PMDA)聚合成得到了新型的聚醚醚酮酰亚胺(PEEKI)树脂及其薄膜.","authors":[{"authorName":"虞鑫海","id":"a1a52986-9186-4b31-bea5-f44588d4a19c","originalAuthorName":"虞鑫海"},{"authorName":"杨名波","id":"bbe6af67-4723-4c0f-9d55-a7f13a6743cc","originalAuthorName":"杨名波"},{"authorName":"徐永芬","id":"81cbb837-4a5f-4c5b-b415-15cc8b4144a3","originalAuthorName":"徐永芬"},{"authorName":"赵炯心","id":"8ced1b82-2d93-4a0b-be80-bafc1ca47e3e","originalAuthorName":"赵炯心"}],"doi":"10.3969/j.issn.1009-9239.2006.05.001","fpage":"1","id":"c547fbe9-f4be-4ddb-b3dc-9532fb91daa9","issue":"5","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"e23e4619-30a7-4dde-ae11-d431f4192163","keyword":"4,4'-<span style=\"color:red\">双</span>(<span style=\"color:red\">3</span>-<span style=\"color:red\">氨基</span><span style=\"color:red\">苯</span>氧基)<span style=\"color:red\">二</span><span style=\"color:red\">苯</span>甲酮","originalKeyword":"4,4'-双(3-氨基苯氧基)二苯甲酮"},{"id":"984d98b7-5627-4352-a4ed-300ad3a1b956","keyword":"聚醚醚酮酰亚胺","originalKeyword":"聚醚醚酮酰亚胺"},{"id":"610a73ff-d793-4dce-8efc-857976abb931","keyword":"合成","originalKeyword":"合成"}],"language":"zh","publisherId":"jycltx200605001","title":"4,4'-<span style=\"color:red\">双</span>(<span style=\"color:red\">3</span>-<span style=\"color:red\">氨基</span><span style=\"color:red\">苯</span>氧基)<span style=\"color:red\">二</span><span style=\"color:red\">苯</span>甲酮及其聚醚醚酮酰亚胺的合成","volume":"39","year":"2006"}],"totalpage":17246,"totalrecord":172452}