{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":4,"startPagecode":1},"records":[{"abstractinfo":"探索了制备纳米<span style=\"color:red\">Skutterudite</span>材料的一种新工艺--微波辅助湿化学法,研究了溶剂体系、反应温度和时间对产物合成的影响.提出采用结构简单、低粘度的乙醇与高沸点的有机溶剂组成的混合溶剂体系可以控制和加快反应进程,反应温度是控制<span style=\"color:red\">Skutterudite</span>相形成的主要因素.采用微波加热对湿化学反应机理没有根本改变,但是显著加快了反应进程,制备了粒径约25 nm的CoSb3、RhSb3材料.","authors":[{"authorName":"彭江英","id":"dd681963-eafb-4688-bb0a-386b0e9accc0","originalAuthorName":"彭江英"},{"authorName":"杨君友","id":"54b30de9-3be8-4b0a-9ce8-45ede4f0be75","originalAuthorName":"杨君友"},{"authorName":"虞华翔","id":"4ee9050d-cf6b-4585-9a3c-62dd17569502","originalAuthorName":"虞华翔"},{"authorName":"刘小燕","id":"087fd906-9858-4334-8b9e-6aeb9375736c","originalAuthorName":"刘小燕"},{"authorName":"朱文","id":"20dd0894-fc69-4505-bbee-5538c3d016bc","originalAuthorName":"朱文"},{"authorName":"黄建新","id":"8aed651c-e97a-4856-a7e8-632793d3e703","originalAuthorName":"黄建新"}],"doi":"","fpage":"515","id":"6b4c0985-749b-48cf-9078-fb5cd1286fca","issue":"z1","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"64a2b524-dba3-4d04-bf19-6853d70bead4","keyword":"热电材料","originalKeyword":"热电材料"},{"id":"8a8546c1-ae59-4ade-ba2a-e7858094ab04","keyword":"<span style=\"color:red\">Skutterudite</span>","originalKeyword":"Skutterudite"},{"id":"8a59af98-acbb-4139-8a07-2ab988f1e1d1","keyword":"微波","originalKeyword":"微波"},{"id":"b1065ab7-f5f6-48ec-8345-3cfcb989e186","keyword":"湿化学","originalKeyword":"湿化学"}],"language":"zh","publisherId":"xyjsclygc2010z1123","title":"采用微波辅助湿化学法制备纳米<span style=\"color:red\">Skutterudite</span>材料的工艺研究","volume":"39","year":"2010"},{"abstractinfo":"研究了Fe置换CoSb3基<span style=\"color:red\">Skutterudite</span>化合物Co4-xFexSb12(x≤1)的机械合金化及其制备工艺.在研究的成分范围内,所有的成分显示出相似的机械合金化动力学过程,初期<span style=\"color:red\">Skutterudite</span>相比(Co/Fe)Sb2相更易于形成,但随球磨时间进一步延长,(Co/Fe)Sb2相逐渐成为最强相.通过机械合金化不能得到单相的<span style=\"color:red\">Skutterudite</span>结构.球磨10小时的粉末经过热压成形后,大部分已转变为<span style=\"color:red\">Skutterudite</span>相,但仍有少量残存的Sb杂质.热压后进一步在650℃退火48小时后,得到了基本为单相的<span style=\"color:red\">Skutterudite</span>结构化合物Co4-xFexSb12(x≤0.65),且x=0.65时基本达到了Fe的置换固溶度.","authors":[{"authorName":"彭江英","id":"c930d376-ff45-4962-8c3a-e5396c6c4a74","originalAuthorName":"彭江英"},{"authorName":"杨君友","id":"8f74be34-ecbd-48b8-9c64-299e84378c6a","originalAuthorName":"杨君友"},{"authorName":"宋新丽","id":"57bbaf67-2d6d-48fb-95fb-931a0822fb72","originalAuthorName":"宋新丽"},{"authorName":"陈跃华","id":"d571b780-8e1f-4420-ae1e-965d99d8206c","originalAuthorName":"陈跃华"},{"authorName":"鲍思前","id":"eab8a433-3130-4335-b780-6f0a9d5af8f8","originalAuthorName":"鲍思前"},{"authorName":"张同俊","id":"eed8f65c-b0a6-4c84-be77-daff07c338f8","originalAuthorName":"张同俊"}],"doi":"10.3969/j.issn.1673-2812.2006.06.001","fpage":"801","id":"d3af8b76-f7f8-423b-8b2c-2fd8b858657b","issue":"6","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"ae52cf5c-0267-4f9b-949a-1fc2b6128880","keyword":"热电材料","originalKeyword":"热电材料"},{"id":"b0dc922a-3440-4fc1-823e-34a218dd1536","keyword":"<span style=\"color:red\">Skutterudite</span>","originalKeyword":"Skutterudite"},{"id":"e4b5347b-2d28-4466-bb63-284e7a903cde","keyword":"机械合金化","originalKeyword":"机械合金化"},{"id":"55b37d31-4f0a-48b6-8e7a-b37337d93297","keyword":"烧结","originalKeyword":"烧结"}],"language":"zh","publisherId":"clkxygc200606001","title":"Fe置换CoSb3基<span style=\"color:red\">Skutterudite</span>化合物Co4-xFexSb12的机械合金化-热压-退火制备工艺研究","volume":"24","year":"2006"},{"abstractinfo":"<span style=\"color:red\">Skutterudite</span>材料因具有特殊的晶体结构成为当前最有前途的热电材料之一,为深入研究填充<span style=\"color:red\">Skutterudite</span>化合物的热传导机制,对化合物的声子振动模式及置换、填充原子对声子模的影响进行了研究.通过对CoSb3,Co3.5Fe0.5Sb12的偏振拉曼谱研究,确认了一个Ag模,且与理论计算吻合较好.对CoSb3,Co3.5Fe0.5Sb12和La0.6Co3.5Fe0.5Sb12拉曼谱的对比研究表明,单纯Fe置换对拉曼谱影响很小,而La部分填充则使部分拉曼峰明显展宽,分析认为,这一现象主要源于填充原子在晶格空隙中的扰动.","authors":[{"authorName":"彭江英","id":"09756e6c-c8af-41dd-955a-76cc0c4101c0","originalAuthorName":"彭江英"},{"authorName":"杨君友","id":"c4818a98-9f77-44ec-af84-458f4682b2c7","originalAuthorName":"杨君友"},{"authorName":"鲍思前","id":"e43fc14b-6da4-4a3d-ab38-fd489537544b","originalAuthorName":"鲍思前"},{"authorName":"陈跃华","id":"dadc3aaa-5781-44f9-8652-a3b1654e9d96","originalAuthorName":"陈跃华"},{"authorName":"张同俊","id":"cc2f53e6-27c5-4ec0-98be-3054589ba308","originalAuthorName":"张同俊"}],"doi":"","fpage":"272","id":"34d1fc5b-2afe-494f-9ef7-639b4d94a1ed","issue":"z1","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"ff3495dd-db6a-4646-8173-8f9e0a61689f","keyword":"热电材料","originalKeyword":"热电材料"},{"id":"827cbdec-f767-4057-935d-c0051e16b429","keyword":"<span style=\"color:red\">Skutterudite</span>","originalKeyword":"Skutterudite"},{"id":"c35f39e2-69aa-4798-bf40-18522b7b000d","keyword":"拉曼散射","originalKeyword":"拉曼散射"}],"language":"zh","publisherId":"xyjsclygc2006z1067","title":"CoSb3基<span style=\"color:red\">Skutterudite</span>化合物拉曼光谱研究","volume":"35","year":"2006"},{"abstractinfo":"<span style=\"color:red\">Skutterudite</span>材料因具有特殊的晶体结构成为当前最有前途的热电材料之一,为深入研究填充<span style=\"color:red\">Skutterudite</span>化合物的热传导机制,对化合物的声子振动模式及置换、填充原子对声子模的影响进行了研究.通过对CoSb3,Co3.5Fe0.5Sb12的偏振拉曼谱研究,确认了一个Ag模,且与理论计算吻合较好.对CoSb3,Co3.5Fe0.5Sb12和La0.6Co3.5Fe0.5Sb12拉曼谱的对比研究表明,单纯Fe置换对拉曼谱影响很小,而La部分填充则使部分拉曼峰明显展宽,分析认为,这一现象主要源于填充原子在晶格空隙中的扰动.","authors":[{"authorName":"彭江英","id":"68821029-86b1-4936-b918-bde7c4897ade","originalAuthorName":"彭江英"},{"authorName":"杨君友","id":"5fab5565-4425-443b-bf42-d79bead6561d","originalAuthorName":"杨君友"},{"authorName":"鲍思前","id":"f50612e8-b39c-497c-853b-3f4078fd8cec","originalAuthorName":"鲍思前"},{"authorName":"陈跃华","id":"b30a8910-f203-476f-bd58-33f1eddb5c63","originalAuthorName":"陈跃华"},{"authorName":"张同俊","id":"4df18c0f-e25c-4d0b-bb46-1a818eb5db50","originalAuthorName":"张同俊"}],"doi":"","fpage":"272","id":"90d90693-433b-4f71-9f17-48d4401d491e","issue":"z2","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"3e343cfe-7255-42d8-9161-6ab2ed77631c","keyword":"热电材料","originalKeyword":"热电材料"},{"id":"72296e54-1bc7-496f-9730-1f302c614aaf","keyword":"<span style=\"color:red\">Skutterudite</span>","originalKeyword":"Skutterudite"},{"id":"42fe5e3a-dc2a-4bfb-960a-ed4174c3089d","keyword":"拉曼散射","originalKeyword":"拉曼散射"}],"language":"zh","publisherId":"xyjsclygc2006z2067","title":"CoSb3基<span style=\"color:red\">Skutterudite</span>化合物拉曼光谱研究","volume":"35","year":"2006"},{"abstractinfo":"首次采用乙醇sol-gel法制备二元<span style=\"color:red\">Skutterudite</span>化合物CoSb3纳米粉体.以CoCl2·6H2O和SbCl3为初始原料,乙醇为溶剂,柠檬酸为络合剂,经过溶胶-凝胶过程,将干燥凝胶研磨成粉,然后置于管式气氛炉中进行还原热处理.研究结果表明,当Sb/Co和C6H8O7/Co的摩尔配比适当,且还原气氛为H2,温度为300～600℃,最终可得到平均粒径尺寸在30nm左右的CoSb3纳米粉体.","authors":[{"authorName":"褚颖","id":"ada6e551-273a-4c16-982d-8d7d29410c00","originalAuthorName":"褚颖"},{"authorName":"唐新峰","id":"1bb5f569-3095-480b-b07c-bcca85ea7467","originalAuthorName":"唐新峰"},{"authorName":"赵文俞","id":"64663e1b-aefd-480a-b871-be22aa0f3432","originalAuthorName":"赵文俞"},{"authorName":"张清杰","id":"d6f2fa80-3103-400d-a870-03a6d0b62c66","originalAuthorName":"张清杰"}],"doi":"","fpage":"839","id":"377e7cf8-e048-422e-b7c8-db0d03400663","issue":"5","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"a126c6ca-30a7-4c04-bf7c-2bc9f5cbb55a","keyword":"乙醇sol-gel","originalKeyword":"乙醇sol-gel"},{"id":"b2ff6472-7e72-4aed-9bdf-bbfdb791edad","keyword":"<span style=\"color:red\">Skutterudite</span>","originalKeyword":"Skutterudite"},{"id":"1369ac14-3a04-4140-9b6f-28837fdbc6de","keyword":"纳米粉体","originalKeyword":"纳米粉体"}],"language":"zh","publisherId":"gncl200705044","title":"乙醇sol-gel法制备二元<span style=\"color:red\">Skutterudite</span>化合物纳米粉体","volume":"38","year":"2007"},{"abstractinfo":"研究了采用机械合金化加热压烧结工艺制备n型<span style=\"color:red\">Skutterudite</span>热电材料的工艺路线.采用了XRD、DTA等测试方法分析了试样的成分,研究了NixCo1-xSb3系材料采用机械合金化加热压烧结的基本工艺路线.研究表明Ni含量在0.2以下的NixCo1-xSb3系材料在球磨10h之后进行2h热压烧结后,试样基本上转化为CoSb3相,并且已经有大量的Ni被置换入CoSb3的晶格之中,形成(NixCo1-x)Sb3材料.","authors":[{"authorName":"陈跃华","id":"9387459a-798f-4155-a8c0-91f282dfc28b","originalAuthorName":"陈跃华"},{"authorName":"杨君友","id":"466b4353-c293-4c24-bea7-2ce26f872e87","originalAuthorName":"杨君友"},{"authorName":"彭江英","id":"4280a868-9fb1-412b-8c37-a958e1932e5a","originalAuthorName":"彭江英"},{"authorName":"宋新莉","id":"0f824ac4-1cac-434c-9ef9-1ab8bef7cf30","originalAuthorName":"宋新莉"},{"authorName":"胡安徽","id":"3420c222-292c-4b64-9c15-de4d2010ad46","originalAuthorName":"胡安徽"}],"doi":"","fpage":"1355","id":"edb4ff3a-bc42-4531-a57e-9fbfa7bb1554","issue":"z1","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"418fb748-526f-4bf0-8c25-2ec352e7b82c","keyword":"<span style=\"color:red\">Skutterudite</span>","originalKeyword":"Skutterudite"},{"id":"41020f31-64d9-4390-be05-963d0095f5e2","keyword":"机械合金化","originalKeyword":"机械合金化"},{"id":"94f0d003-249a-4d0f-8f12-b6d0536ee697","keyword":"热压烧结","originalKeyword":"热压烧结"}],"language":"zh","publisherId":"gncl2004z1380","title":"机械合金化法制备N型<span style=\"color:red\">Skutterudite</span>热电材料研究","volume":"35","year":"2004"},{"abstractinfo":"探索了交叉共沉淀法制备纳米方钴矿化合物CoSb3.以钴和锑的氯化物为原料,NaOH和氨水为沉淀剂,室温下调节pH=5～10,经过滤、洗涤、超声分散和真空干燥后得到了Co(OH)2和Sb2O3前驱体.研究了还原热处理过程中还原气氛、温度、时间、原料配比对还原产物的相组成和粉体粒径的影响.结果表明,采用纯H2为还原气氛,500℃下还原3h,当Sb/Co摩尔比为3.15时,可得到粒径均匀、平均粒径约为100nm的单相CoSb3粉体.","authors":[{"authorName":"褚颖","id":"c0e023c8-2527-4e43-b8ff-a2dfbcf8b79b","originalAuthorName":"褚颖"},{"authorName":"唐新峰","id":"d5970253-05b7-4260-abdf-9bb3a3735494","originalAuthorName":"唐新峰"},{"authorName":"万玲","id":"7741cd93-f187-4cc0-8bf3-d20d2726fcd9","originalAuthorName":"万玲"},{"authorName":"赵文俞","id":"9f1e12d2-b9e2-40a2-bb80-b6df36e459e6","originalAuthorName":"赵文俞"},{"authorName":"张清杰","id":"2612bb36-66f8-4fd3-9a07-2d49019be722","originalAuthorName":"张清杰"}],"doi":"10.3321/j.issn:1000-324X.2006.02.006","fpage":"298","id":"f92f054b-8163-4007-baf7-8a5f2d90ad9d","issue":"2","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"a16f56ed-b2bb-47d2-b885-d1545b7b11af","keyword":"交叉共沉淀","originalKeyword":"交叉共沉淀"},{"id":"58b836b5-48b4-43fe-9f57-4d5f08ba57a7","keyword":"<span style=\"color:red\">Skutterudite</span>","originalKeyword":"Skutterudite"},{"id":"f1501c67-c2db-48c3-a6dc-524d76df6d5a","keyword":"纳米粉体","originalKeyword":"纳米粉体"}],"language":"zh","publisherId":"wjclxb200602006","title":"交叉共沉淀法制备<span style=\"color:red\">Skutterudite</span>纳米粉体的研究","volume":"21","year":"2006"},{"abstractinfo":"采用熔融法合成了<span style=\"color:red\">Skutterudite</span>化合物Co4-xNixSb12,并研究了Ni掺杂对该化合物的高温热电性能的影响.实验结果表明:由于Ni向<span style=\"color:red\">Skutterudite</span>结构中提供电子,导致化合物的载流子浓度和电导率随Ni置换量的增加而增加,Seebeck系数为负值,Seebeck系数的峰值温度随Ni置换量的增加向高温方向移动;Ni置换引入了电子-声子散射,导致晶格热导率降低.对于<span style=\"color:red\">Skutterudite</span>化合物Co4-xNixSb12,得到的最大热电性能指数ZT约为0.55.","authors":[{"authorName":"赵雪盈","id":"7ac53f77-1e63-440b-ae5c-c1de5f7e1cb1","originalAuthorName":"赵雪盈"},{"authorName":"史迅","id":"5b7a2506-3d2c-44c6-9a25-c9c113758247","originalAuthorName":"史迅"},{"authorName":"陈立东","id":"51b0dd5d-4a32-4521-bd61-e92e38b8570e","originalAuthorName":"陈立东"},{"authorName":"唐新峰","id":"a155bfe4-5d25-4a22-9bfc-72680d36f9d1","originalAuthorName":"唐新峰"}],"doi":"10.3321/j.issn:1000-324X.2006.02.022","fpage":"392","id":"da0ec75b-1b79-4c40-bccd-ddba0667db98","issue":"2","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"ecaf89a1-e27f-46b0-bd36-5245c5ac2764","keyword":"Ni掺杂","originalKeyword":"Ni掺杂"},{"id":"e6f35ae1-ae00-4438-882a-9c8620d750d2","keyword":"<span style=\"color:red\">Skutterudite</span>","originalKeyword":"Skutterudite"},{"id":"0c8eb3b4-32a4-470e-ba76-b1b898715e6b","keyword":"热电性能","originalKeyword":"热电性能"}],"language":"zh","publisherId":"wjclxb200602022","title":"Ni掺杂对Co4-xNixSb12热电转换性能的影响","volume":"21","year":"2006"},{"abstractinfo":"结合声子散射机制介绍了近来报道的几种降低<span style=\"color:red\">skutterudite</span>类热电材料热导率的途径,为研究和发展<span style=\"color:red\">skutterudite</span>类热电材料提供一些思路和方法.","authors":[{"authorName":"杨磊","id":"2bd0ecd5-f37f-4492-b95e-7ad23a49a71d","originalAuthorName":"杨磊"},{"authorName":"吴建生","id":"aa3d51bd-798f-409d-99aa-914300498ec5","originalAuthorName":"吴建生"},{"authorName":"张澜庭","id":"aac72ddc-4a78-4d00-bdc3-66277fecf771","originalAuthorName":"张澜庭"}],"doi":"","fpage":"14","id":"4134d14b-3f71-4413-819b-481c637298d7","issue":"4","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"c90b424b-c5c3-43d7-8ba3-71c3f0d2a928","keyword":"<span style=\"color:red\">skutterudite</span>","originalKeyword":"skutterudite"},{"id":"1709ed18-ab8d-4955-82e8-a43e1c609230","keyword":"热电材料","originalKeyword":"热电材料"},{"id":"aac70e72-0645-453d-b1ee-8870ffe0d0eb","keyword":"热导率","originalKeyword":"热导率"},{"id":"2708d6be-aed6-4ef7-90c8-9e8a999460b3","keyword":"热电性能","originalKeyword":"热电性能"}],"language":"zh","publisherId":"cldb200304005","title":"具有低热导率的<span style=\"color:red\">Skutterudite</span>类新型热电材料","volume":"17","year":"2003"},{"abstractinfo":"首先介绍了填充式<span style=\"color:red\">Skutterudite</span>热电材料在成分优化方面的研究进展,再从组织结构优化以及合成低维<span style=\"color:red\">Skutterudite</span>材料等几个方面探讨了近年来<span style=\"color:red\">Skutterudite</span>类热电材料的研究状况和最新进展.","authors":[{"authorName":"胡安徽","id":"6d8b10e9-83fb-4e7f-94ca-48f358687abd","originalAuthorName":"胡安徽"},{"authorName":"杨君友","id":"f0a5003c-d88b-4274-bdb1-04e66fb2fa48","originalAuthorName":"杨君友"},{"authorName":"鲍思前","id":"5d6a6409-3b8e-49c4-a8b1-82225bede08f","originalAuthorName":"鲍思前"},{"authorName":"樊希安","id":"771d44eb-84a7-411d-9687-6adf58a45523","originalAuthorName":"樊希安"},{"authorName":"段兴凯","id":"43b09be1-7830-4694-a010-80b07d6d87f7","originalAuthorName":"段兴凯"}],"doi":"","fpage":"37","id":"3343f267-1be2-420c-973e-274e352d43ff","issue":"1","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"2a22abd1-2fdd-4aa0-8b1d-c14c7a06e5e0","keyword":"方钴矿","originalKeyword":"方钴矿"},{"id":"f937a368-ee33-446e-a3af-cd89d621218c","keyword":"热电材料","originalKeyword":"热电材料"},{"id":"d658de93-77de-46f2-9562-a1c355ed925d","keyword":"填充限度","originalKeyword":"填充限度"},{"id":"c93fd9ef-e9ad-40ea-af9b-d94e691f69dd","keyword":"低维","originalKeyword":"低维"}],"language":"zh","publisherId":"cldb200701010","title":"<span style=\"color:red\">Skutterudite</span>热电材料的最新研究进展","volume":"21","year":"2007"}],"totalpage":4,"totalrecord":40}