{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以ZSM-5/丝光沸石(MOR)复合分子筛为催化剂,对<span style=\"color:red\">混合</span>C4<span style=\"color:red\">烃</span>的催化转化反应进行了评价,并采用程序升温脱附和原位红外光谱技术对ZSM-5/MOR的酸性进行了表征. 结果表明,与ZSM-5相比, MOR具有很低的催化活性,但ZSM-5/MOR复合分子筛具有较高的催化活性,随着ZSM-5/MOR复合分子筛中ZSM-5含量的增加, C4<span style=\"color:red\">烃</span>转化率稍有升高;在C4<span style=\"color:red\">烃</span>转化率大致相同的情况下,乙烯和丙烯的总选择性比较接近,但苯和甲苯的总收率却快速升高. 随着ZSM-5/MOR复合分子筛中ZSM-5含量的增加,弱酸和中强酸的酸量逐渐减少,强酸的酸量有所增加. 由于ZSM-5/MOR复合分子筛中MOR对ZSM-5起到分散作用而产生更多的L酸中心,且此L酸中心处于分子筛的外表面而具有较高的能量,导致苯和甲苯的总收率升高.","authors":[{"authorName":"刘百军","id":"cd989bd7-ca21-4bc4-be0f-16656b4cc575","originalAuthorName":"刘百军"},{"authorName":"曾贤君","id":"25818d6e-6079-4882-9307-15b588d592f8","originalAuthorName":"曾贤君"},{"authorName":"何琳琳","id":"f1ecd779-d9ca-4f2c-a567-f2cd9c6003c7","originalAuthorName":"何琳琳"},{"authorName":"赵震","id":"b4e8d8fa-d3cc-4fb5-8a38-956aeb1294f1","originalAuthorName":"赵震"}],"doi":"","fpage":"940","id":"56635710-055f-4014-92d0-013d3839c85d","issue":"9","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"e10146be-3402-4f63-ab73-c7fd1a9008e9","keyword":"ZSM-5分子筛","originalKeyword":"ZSM-5分子筛"},{"id":"a8eb2028-1c46-4568-977b-ae47b1a61c6a","keyword":"丝光沸石","originalKeyword":"丝光沸石"},{"id":"9e969d3a-1fa9-4863-b833-69982dd3ae53","keyword":"复合分子筛","originalKeyword":"复合分子筛"},{"id":"052cd937-f371-4ab4-8b9b-1061ece41825","keyword":"<span style=\"color:red\">混合</span><span style=\"color:red\">碳</span><span style=\"color:red\">四</span><span style=\"color:red\">烃</span>","originalKeyword":"混合碳四烃"},{"id":"b4644dda-9868-4fa9-8a4a-a2b3991beb73","keyword":"乙烯","originalKeyword":"乙烯"},{"id":"3ef30372-6c6d-49ff-b9c9-97dd9505c68b","keyword":"丙烯","originalKeyword":"丙烯"},{"id":"814af93b-6440-4e22-9d31-3605de6b71b3","keyword":"芳构化","originalKeyword":"芳构化"},{"id":"2e8bb5b5-8ae3-4945-b420-42b4049ecbe4","keyword":"苯","originalKeyword":"苯"},{"id":"f4984c60-9a31-494c-8151-b47f0f717434","keyword":"甲苯","originalKeyword":"甲苯"}],"language":"zh","publisherId":"cuihuaxb200809020","title":"ZSM-5/MOR复合分子筛催化剂对<span style=\"color:red\">混合</span>C4<span style=\"color:red\">烃</span>转化反应的催化性能","volume":"29","year":"2008"},{"abstractinfo":"用浸渍法制备了稀土改性HZSM-5分子筛催化剂(简称RE/HZSM-5),研究了RE/HZSM-5对<span style=\"color:red\">混合</span>C4<span style=\"color:red\">烃</span>(包括C4烷烃和C4烯烃)裂解活性及低<span style=\"color:red\">碳</span>烯烃收率的影响.结果表明,RE改性后HZSM-5分子筛催化剂的裂解活性明显增加,轻稀土改性HZSM-5分子筛比重稀土改性的表现出更好的增产低<span style=\"color:red\">碳</span>烯烃裂解性能.在0.1MPa,重时空速(WHSV)=1.2×104 mL/h*g-1条件下,轻稀土La、Pr、Nd、Sm、Gd改性HZSM-5分子筛催化剂上<span style=\"color:red\">混合</span>C4<span style=\"color:red\">烃</span>催化裂解产物中乙烯和丙烯总收率在625℃时达到最高,分别为54.66%、54.32%、53.32%、54.15%和54.06%,比相同条件下未改性的HZSM-5高3%～4%.重稀土中只有Yb/HZSM-5表现出较好的裂解活性,裂解产物中乙烯和丙烯总收率在600℃时达到最高,为54.80%.用红外光谱(FT-IR),氨程序升温脱附(NH3-TPD)和吡啶吸附红外光谱法(Py-IR)法对RE/HZSM-5分子筛进行了表征,结果表明催化剂的总酸量、B酸与L酸的比值与催化活性之间存在密切关系.","authors":[{"authorName":"王晓宁","id":"41631d3b-9a0c-46fc-a91c-af3b4781658d","originalAuthorName":"王晓宁"},{"authorName":"周新宇","id":"55c77800-ce2a-4502-b5d4-8c9b18f0c3df","originalAuthorName":"周新宇"},{"authorName":"姜桂元","id":"e4b37dac-a8c2-49d4-a3c8-f15c1860d583","originalAuthorName":"姜桂元"},{"authorName":"赵震","id":"7bbb3f2b-4dfd-4d8b-af9a-cf6079da684e","originalAuthorName":"赵震"},{"authorName":"徐春明","id":"7d1d6638-b0d6-4819-927b-9f3418a7844a","originalAuthorName":"徐春明"},{"authorName":"段爱军","id":"ec0c1541-bc40-4858-baa1-ec8556b05b8d","originalAuthorName":"段爱军"}],"doi":"10.3969/j.issn.1004-0277.2008.05.008","fpage":"30","id":"f51a2fb0-cabe-4dd9-8d1a-561681f3d66a","issue":"5","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"4633ff78-75a8-483b-b93a-c5dbcefad969","keyword":"<span style=\"color:red\">混合</span>C4<span style=\"color:red\">烃</span>","originalKeyword":"混合C4烃"},{"id":"dfa8188b-948e-4129-80f9-089cb6ef4935","keyword":"催化裂解","originalKeyword":"催化裂解"},{"id":"fd73b222-c032-4085-ba93-3ba60f659bf8","keyword":"低<span style=\"color:red\">碳</span>烯烃","originalKeyword":"低碳烯烃"},{"id":"f9abe8ef-c357-419d-9f0f-eaf711609df6","keyword":"HZSM-5分子筛","originalKeyword":"HZSM-5分子筛"},{"id":"a0d3f004-844a-402e-8b6f-76296432de6c","keyword":"稀土","originalKeyword":"稀土"}],"language":"zh","publisherId":"xitu200805008","title":"稀土改性HZSM-5分子筛催化裂解<span style=\"color:red\">混合</span>C4<span style=\"color:red\">烃</span>制低<span style=\"color:red\">碳</span>烯烃性能的研究","volume":"29","year":"2008"},{"abstractinfo":"用XRD,XPS,SEM和H2-TPR等手段研究了铜基负载型催化剂的结构和物性及其对<span style=\"color:red\">混合</span><span style=\"color:red\">碳</span><span style=\"color:red\">四</span>加氢脱炔的催化性能. 结果表明,在负载铜催化剂中加入一定量的Co可提高催化剂的加氢脱炔活性,而Co含量较少时加入少量的Ce也能提高催化剂的活性和选择性. Cu和Co之间存在着相互协同作用,使得活性组分在催化剂表面偏析,CuO在催化剂表面呈非晶相分散状态,催化剂颗粒粒径变小,催化剂更容易被还原,从而改善了催化剂的催化性能.","authors":[{"authorName":"张全信","id":"6b41d77f-6dd3-404a-a2dc-3b77526ada04","originalAuthorName":"张全信"},{"authorName":"刘希尧","id":"a2392c01-9c8b-4e01-82ef-56b35826bc5b","originalAuthorName":"刘希尧"},{"authorName":"雷鸣","id":"de210d40-96e6-4130-a994-2915c626c9ef","originalAuthorName":"雷鸣"},{"authorName":"徐仑","id":"7cca592a-258a-486f-b322-e36a036cbf48","originalAuthorName":"徐仑"}],"doi":"","fpage":"250","id":"42262ee3-e557-4dc1-9d84-21527d1d1f9d","issue":"3","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"32c1d18a-28df-43be-81dd-e9cc45b73f8e","keyword":"铜基催化剂","originalKeyword":"铜基催化剂"},{"id":"516ea4ba-3294-4699-8ffd-376aa0db955b","keyword":"钴","originalKeyword":"钴"},{"id":"e89da8ea-4eb5-41c9-9f9a-9cc0227e4472","keyword":"铈","originalKeyword":"铈"},{"id":"a89337ab-8932-4db5-86fa-acdde4dd19c7","keyword":"协同作用","originalKeyword":"协同作用"},{"id":"430adf15-209c-40b2-80b1-8d2bb38af506","keyword":"<span style=\"color:red\">混合</span><span style=\"color:red\">碳</span><span style=\"color:red\">四</span>","originalKeyword":"混合碳四"},{"id":"d5f83a50-d5dc-442e-b29f-16dac71db57b","keyword":"加氢","originalKeyword":"加氢"},{"id":"c7bdd722-5d52-4245-9be7-cd3a5a1f96e4","keyword":"脱炔","originalKeyword":"脱炔"}],"language":"zh","publisherId":"cuihuaxb200203013","title":"铜基催化剂的结构、物性及其对<span style=\"color:red\">混合</span><span style=\"color:red\">碳</span><span style=\"color:red\">四</span>选择加氢反应的催化性能","volume":"23","year":"2002"},{"abstractinfo":"气相色谱法是最常用的<span style=\"color:red\">混合</span>工质组元浓度分析方法.针对氢氟<span style=\"color:red\">烃</span>二元<span style=\"color:red\">混合</span>物的特点,本文搭建了气相色谱法<span style=\"color:red\">混合</span>工质组分分析实验台,测定了9种氢氟<span style=\"color:red\">烃</span>二元<span style=\"color:red\">混合</span>物组元质量分数与峰面积百分比的对应关系.讨论了气相色谱法<span style=\"color:red\">混合</span>工质组分分析的理论方法,比较了2种标准曲线函数模型对实验数据的再现精度,本文提出的校正因子为变量的模型对实验数据的再现性较好,平均绝对偏差小于±0.25%,满足热物性研究对<span style=\"color:red\">混合</span>物组元成分分析的实验要求.","authors":[{"authorName":"王忠伟","id":"039e1d5e-75da-4b5c-9cd7-2fc634e600bd","originalAuthorName":"王忠伟"},{"authorName":"段远源","id":"aa5f3f06-9b08-4667-8710-79ffb3d16bcf","originalAuthorName":"段远源"}],"doi":"","fpage":"739","id":"d83d8a8f-1047-4c23-aecb-2f73191236e1","issue":"5","journal":{"abbrevTitle":"GCRWLXB","coverImgSrc":"journal/img/cover/GCRWLXB.jpg","id":"32","issnPpub":"0253-231X","publisherId":"GCRWLXB","title":"工程热物理学报   "},"keywords":[{"id":"e6ba1098-31d3-48b6-890e-8dd4993d84ef","keyword":"氢氟<span style=\"color:red\">烃</span><span style=\"color:red\">混合</span>物","originalKeyword":"氢氟烃混合物"},{"id":"7c7e16ed-e953-4917-945c-c2978618a9c2","keyword":"气相色谱法","originalKeyword":"气相色谱法"},{"id":"b8df9032-ea84-4805-b412-67e1344aef41","keyword":"组分分析","originalKeyword":"组分分析"},{"id":"7fc54d89-697f-4504-8df3-1205365db4c5","keyword":"实验测量","originalKeyword":"实验测量"}],"language":"zh","publisherId":"gcrwlxb200505006","title":"氢氟<span style=\"color:red\">烃</span>二元<span style=\"color:red\">混合</span>工质的组分分析","volume":"26","year":"2005"},{"abstractinfo":"氢氟<span style=\"color:red\">烃</span>+润滑油体系的气液相平衡性质近年来受到了广泛关注,国际上已有一批相关实验数据发表.本文研究了状态方程法模型描述氢氟<span style=\"color:red\">烃</span>+润滑油体系气液相平衡性质的适用性,分析了<span style=\"color:red\">混合</span>规则和溶液模型的影响,针对不同类型的体系建立了相应的相平衡预测模型,较好地再现了多种氢氟<span style=\"color:red\">烃</span>+POE、BAB润滑油体系的气液相平衡性质.","authors":[{"authorName":"侯树鑫","id":"1647728a-0cb7-43ae-b811-104b250a1994","originalAuthorName":"侯树鑫"},{"authorName":"段远源","id":"81a58a91-5dc6-4236-a9f3-761596d7435c","originalAuthorName":"段远源"},{"authorName":"王晓东","id":"c5c41132-f6b3-442e-9eda-7fb6671bedbf","originalAuthorName":"王晓东"}],"doi":"","fpage":"927","id":"512460eb-f06c-4a83-a816-a64f228717c2","issue":"6","journal":{"abbrevTitle":"GCRWLXB","coverImgSrc":"journal/img/cover/GCRWLXB.jpg","id":"32","issnPpub":"0253-231X","publisherId":"GCRWLXB","title":"工程热物理学报   "},"keywords":[{"id":"e97ebb5b-df45-40cd-8fcd-5a89247e99da","keyword":"气液相平衡","originalKeyword":"气液相平衡"},{"id":"c3a1a67d-09e3-4973-819d-351b784ac961","keyword":"状态方程","originalKeyword":"状态方程"},{"id":"e22f756d-719f-44b4-8b69-5a51959779a0","keyword":"<span style=\"color:red\">混合</span>规则","originalKeyword":"混合规则"},{"id":"59374b54-b862-440b-81a2-20ac25b3ad0e","keyword":"氢氟<span style=\"color:red\">烃</span>","originalKeyword":"氢氟烃"},{"id":"2ab3758e-176f-4851-8866-6cf82b6df69d","keyword":"润滑油","originalKeyword":"润滑油"}],"language":"zh","publisherId":"gcrwlxb200806007","title":"氢氟<span style=\"color:red\">烃</span>+润滑油<span style=\"color:red\">混合</span>物气液相平衡模型","volume":"29","year":"2008"},{"abstractinfo":"着重介绍了近年来低<span style=\"color:red\">碳</span><span style=\"color:red\">烃</span>芳构化制芳烃研究进展和无机膜催化低<span style=\"color:red\">碳</span><span style=\"color:red\">烃</span>脱氢芳构化制芳烃研究现状,阐述了膜性能与芳构化反应性能的关系及其应用开发前景.","authors":[{"authorName":"张雄福","id":"53c28032-864c-4984-ac74-256516b1e3c3","originalAuthorName":"张雄福"},{"authorName":"王金渠","id":"fa4f820f-98ac-493f-b87f-6e38eba02cb7","originalAuthorName":"王金渠"}],"doi":"10.3969/j.issn.1007-8924.1998.02.002","fpage":"3","id":"cf735d15-970f-4e96-932f-7cb7bb321448","issue":"2","journal":{"abbrevTitle":"MKXYJS","coverImgSrc":"journal/img/cover/MKXYJS.jpg","id":"54","issnPpub":"1007-8924","publisherId":"MKXYJS","title":"膜科学与技术   "},"keywords":[{"id":"43b07a3f-1171-4794-98e8-a1f405b6a0b7","keyword":"无机膜","originalKeyword":"无机膜"},{"id":"f5181aff-7233-40ba-90ea-6706271a852d","keyword":"低<span style=\"color:red\">碳</span><span style=\"color:red\">烃</span>","originalKeyword":"低碳烃"},{"id":"599b94f3-f5cc-4206-bb23-8ba8de985c96","keyword":"芳构化","originalKeyword":"芳构化"}],"language":"zh","publisherId":"mkxyjs199802002","title":"无机膜催化低<span style=\"color:red\">碳</span><span style=\"color:red\">烃</span>脱氢芳构化制芳烃研究进展","volume":"18","year":"1998"},{"abstractinfo":"合成了3个含硅<span style=\"color:red\">四</span><span style=\"color:red\">烃</span>基二锡氧烷化合物,并通过乙酸与异戊醇的反应和丁醛与乙二醇的反应,考察了它们在酯化反应和缩醛化反应中的催化活性,讨论了催化剂用量、反应时间和溶剂等因素对催化反应的影响.结果表明,与二氯代<span style=\"color:red\">四</span>丁基二锡氧烷相比,3种含硅<span style=\"color:red\">四</span><span style=\"color:red\">烃</span>基二锡氧烷在酯化反应和缩醛化反应中均表现出类似的高催化活性;催化剂[ClBu2SnOSn(CH2SiMe3)2Cl]2用量为反应物料质量的1.5%时,乙酸异戊酯的产率为91.8%,丁醛缩乙二醇的产率为94.2%.在<span style=\"color:red\">四</span><span style=\"color:red\">烃</span>基二锡氧烷结构中,锡原子上的<span style=\"color:red\">烃</span>基或桥联基团的不同,对其催化活性均有一定程度的影响.","authors":[{"authorName":"何小立","id":"3d428ee3-95e5-45d1-bb18-8d128128557e","originalAuthorName":"何小立"},{"authorName":"林森","id":"087cac7e-99a0-4930-af7e-3b30053d8d44","originalAuthorName":"林森"},{"authorName":"郭璇","id":"fe47fbf3-4c1a-4e44-a107-313e890b25cd","originalAuthorName":"郭璇"},{"authorName":"陆路德","id":"9cec6b86-10a1-425e-ab65-79abc84c418f","originalAuthorName":"陆路德"},{"authorName":"汪信","id":"bd8905a3-55bb-4397-95ad-bcd87df28394","originalAuthorName":"汪信"},{"authorName":"杨绪杰","id":"cfda73b7-676f-455a-8a9a-9e24e9ce1470","originalAuthorName":"杨绪杰"}],"doi":"10.3969/j.issn.1000-0518.2007.11.010","fpage":"1268","id":"ec8720aa-85a2-4b58-820a-8fae5ba70001","issue":"11","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"f02d2d5f-09f0-4b2d-ba78-e94e92cf02a9","keyword":"含硅<span style=\"color:red\">四</span><span style=\"color:red\">烃</span>基二锡氧烷","originalKeyword":"含硅四烃基二锡氧烷"},{"id":"0644d0d9-16db-4c24-95e0-bada7f460794","keyword":"合成","originalKeyword":"合成"},{"id":"8bb83849-6fd3-494c-b124-1ef40c4a5197","keyword":"催化","originalKeyword":"催化"},{"id":"4f6ea8a3-6afe-4a38-a3c5-c96860e98fce","keyword":"酯化反应","originalKeyword":"酯化反应"},{"id":"ab9962c0-3d3e-4e74-849f-1d7bff92d2be","keyword":"缩醛化反应","originalKeyword":"缩醛化反应"}],"language":"zh","publisherId":"yyhx200711010","title":"含硅<span style=\"color:red\">四</span><span style=\"color:red\">烃</span>基二锡氧烷的合成及其催化性能","volume":"24","year":"2007"},{"abstractinfo":"整理了已公开发表的氢氟<span style=\"color:red\">烃</span>(HFC)/烷烃(HC)二元<span style=\"color:red\">混合</span>物气液相平衡实验数据,对实验数据进行了热力学一致性检验.采用PR方程加van der Waals<span style=\"color:red\">混合</span>规则描述该类<span style=\"color:red\">混合</span>物的气液相平衡性质,优化得到了11种<span style=\"color:red\">混合</span>物的二元交互作用系数,经比较表明采用优化结果能够高精度再现气液相平衡实验数据,比kij取0的计算结果有很大改善.","authors":[{"authorName":"张秋芳","id":"c4cdcbb4-e4f9-4659-b145-4feff5ec7c99","originalAuthorName":"张秋芳"},{"authorName":"侯树鑫","id":"7aa313a7-1a15-4879-85c9-fa5fa955730d","originalAuthorName":"侯树鑫"},{"authorName":"段远源","id":"1355bacd-29fc-496a-a4a8-1a7eefa96809","originalAuthorName":"段远源"},{"authorName":"宋艺新","id":"d42ba07a-548c-4380-a722-224daa543153","originalAuthorName":"宋艺新"}],"doi":"","fpage":"49","id":"2ae17e6d-7aff-453b-9c7d-cd97fd1b1bfc","issue":"z1","journal":{"abbrevTitle":"GCRWLXB","coverImgSrc":"journal/img/cover/GCRWLXB.jpg","id":"32","issnPpub":"0253-231X","publisherId":"GCRWLXB","title":"工程热物理学报   "},"keywords":[{"id":"88b3a271-f927-45fb-9c35-b28226709c1e","keyword":"气液相平衡","originalKeyword":"气液相平衡"},{"id":"79cc67d3-f250-4165-bdf4-cf946e566cac","keyword":"氢氟<span style=\"color:red\">烃</span>","originalKeyword":"氢氟烃"},{"id":"e9921e7e-edf8-493a-bbd2-1303065c23a1","keyword":"烷烃","originalKeyword":"烷烃"},{"id":"a4d7436f-8c77-4d7d-b788-f780917960a7","keyword":"PR方程","originalKeyword":"PR方程"},{"id":"f792a51f-1f93-4ded-8db0-291df5580b74","keyword":"交互作用系数","originalKeyword":"交互作用系数"}],"language":"zh","publisherId":"gcrwlxb2006z1013","title":"氢氟<span style=\"color:red\">烃</span>/烷烃二元<span style=\"color:red\">混合</span>物的气液相平衡","volume":"27","year":"2006"},{"abstractinfo":"通过计算甲烷、乙烷、乙烯、乙炔、丙烷和丙烯等低<span style=\"color:red\">碳</span><span style=\"color:red\">烃</span>与NO反应的热力学函数和低<span style=\"color:red\">碳</span><span style=\"color:red\">烃</span>在电场作用下产生活性粒子的反应焓变,找出合适的低<span style=\"color:red\">碳</span><span style=\"color:red\">烃</span>作为脱除NO的添加剂.根据计算结果.以丙烷和丙烯为例,利用脉冲电晕加氨分别与丙烷和丙烯协同进行了脱除NO的实验研究,得出了最佳工艺参数.在进口风速为1.2 m/s、出口风速为1.0 m/s、进口温度为80℃、出口温度为40℃、脉冲电压为50 kV时,加入丙烯的脱氮率可以达到60%,加入丙烷的脱氮率可接近30%.","authors":[{"authorName":"李秋荣","id":"4dcbe091-ca22-4a2f-bfad-2220ae06f164","originalAuthorName":"李秋荣"},{"authorName":"白明华","id":"da562b7d-dadc-4c56-803a-0a6187e47c84","originalAuthorName":"白明华"},{"authorName":"贺君","id":"9496b03a-bc16-48c7-8253-996afb2a4843","originalAuthorName":"贺君"},{"authorName":"武金宝","id":"9ac07bb7-6564-4e88-91d4-4c2d7ec77e22","originalAuthorName":"武金宝"}],"doi":"","fpage":"86","id":"792f09d0-5026-4a1b-b9f6-d41b5f67d662","issue":"3","journal":{"abbrevTitle":"GT","coverImgSrc":"journal/img/cover/GT.jpg","id":"27","issnPpub":"0449-749X","publisherId":"GT","title":"钢铁"},"keywords":[{"id":"5541d8f2-5f7a-4e4b-a12d-56fd4121a8d8","keyword":"NO","originalKeyword":"NO"},{"id":"aa3e0da7-cf56-4f67-bc2b-d02680905b25","keyword":"低<span style=\"color:red\">碳</span><span style=\"color:red\">烃</span>","originalKeyword":"低碳烃"},{"id":"bc534a0d-a073-4b58-baac-72b499cb415e","keyword":"热力学分析","originalKeyword":"热力学分析"},{"id":"c8acb4d6-d710-4314-b6f5-3ac0dd3bc44f","keyword":"脉冲电晕","originalKeyword":"脉冲电晕"}],"language":"zh","publisherId":"gt200803020","title":"低<span style=\"color:red\">碳</span><span style=\"color:red\">烃</span>脱除NO气体的热力学分析及实验研究","volume":"43","year":"2008"},{"abstractinfo":"通过计算甲烷、乙烷、乙烯、乙炔、丙烷和丙烯等低<span style=\"color:red\">碳</span><span style=\"color:red\">烃</span>与NO反应的热力学函数和低<span style=\"color:red\">碳</span><span style=\"color:red\">烃</span>在电场作用下产生活性粒子的反应焓变，找出合适的低<span style=\"color:red\">碳</span><span style=\"color:red\">烃</span>作为脱除NO的添加剂。根据计算结果，以丙烷和丙烯为例，利用脉冲电晕加氨分别与丙烷和丙烯协同进行了脱除NO的实验研究，得出了最佳工艺参数。在进口风速为1.2 m/s、出口风速为1.0 m/s、进口温度为80 ℃、出口温度为40 ℃、脉冲电压为50 kV时，加入丙烯的脱氮率可以达到60%，加入丙烷的脱氮率可接近30%。","authors":[{"authorName":"李秋荣","id":"571809a6-ad6c-4f8b-958f-19b78b644e72","originalAuthorName":"李秋荣"},{"authorName":"白明华","id":"6e40f294-ea7c-4ca2-8adf-a44017f72d45","originalAuthorName":"白明华"},{"authorName":"贺君","id":"506cce66-e9bf-448e-aade-844f1e4db9d2","originalAuthorName":"贺君"},{"authorName":"武金宝","id":"47201b14-3ea4-4c41-8591-4fa6c763bb25","originalAuthorName":"武金宝"}],"categoryName":"|","doi":"","fpage":"86","id":"87969b9e-0ec6-4840-975f-7f76b3173177","issue":"3","journal":{"abbrevTitle":"GT","coverImgSrc":"journal/img/cover/GT.jpg","id":"27","issnPpub":"0449-749X","publisherId":"GT","title":"钢铁"},"keywords":[{"id":"80cecb5b-c372-415e-bef9-c219b85698bb","keyword":"NO;低<span style=\"color:red\">碳</span><span style=\"color:red\">烃</span>;热力学分析;脉冲电晕","originalKeyword":"NO;低碳烃;热力学分析;脉冲电晕"}],"language":"zh","publisherId":"0449-749X_2008_3_2","title":"低<span style=\"color:red\">碳</span><span style=\"color:red\">烃</span>脱除NO气体的热力学分析及实验研究","volume":"43","year":"2008"}],"totalpage":2722,"totalrecord":27220}