{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以广西的优势资源<span style=\"color:red\">松香</span>为原料,<span style=\"color:red\">脱氢</span><span style=\"color:red\">松香</span>酸与亚硫酰氯在回流条件下反应6 h,所得产物与硫氰化钾回流反应1.5 h,得到<span style=\"color:red\">脱氢</span><span style=\"color:red\">松香</span>酰异硫氰酸酯,产率52%;然后与<span style=\"color:red\">芳</span>甲酰肼反应,得到一系列的1-<span style=\"color:red\">脱氢</span><span style=\"color:red\">松香</span>酰<span style=\"color:red\">基</span>-3-<span style=\"color:red\">芳</span><span style=\"color:red\">酰胺基</span>硫脲(4),产率39%～84%;最后用醋酸关环得到5-<span style=\"color:red\">芳</span><span style=\"color:red\">基</span>-2-<span style=\"color:red\">脱氢</span><span style=\"color:red\">松香</span><span style=\"color:red\">酰胺基</span>-1,3,4-<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>(5),产率49%～87%:化合物4和化合物5的结构经IR、NMR测试技术分析确认,并用X射线衍射法测定了化合物5b的晶体结构.经初步生物活性测试表明,化合物4c、4f、5f在质量浓度为100 mg/L时,对枯草杆菌和大肠杆菌有一定的抑制作用.","authors":[{"authorName":"苏桂发","id":"ab2ca0fa-2716-45eb-8db6-badc03811f3b","originalAuthorName":"苏桂发"},{"authorName":"霍丽妮","id":"8f5674c0-5a88-42ce-b958-39f984554f81","originalAuthorName":"霍丽妮"},{"authorName":"覃江克","id":"091b4965-eb74-459d-b7f8-7c94317eca7d","originalAuthorName":"覃江克"},{"authorName":"潘成学","id":"1979de56-816a-4074-8187-9b4f12a48552","originalAuthorName":"潘成学"},{"authorName":"关一富","id":"10cff985-bae0-4898-ad3a-06ca5e10ce16","originalAuthorName":"关一富"}],"doi":"10.3969/j.issn.1000-0518.2008.07.011","fpage":"803","id":"d18ccd34-bfce-41cd-ac57-3e1ca1a4ae6e","issue":"7","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"2afe53d9-5ee8-414a-b1a7-38ad868e907c","keyword":"<span style=\"color:red\">脱氢</span><span style=\"color:red\">松香</span>酸","originalKeyword":"脱氢松香酸"},{"id":"a611048f-570a-4248-90c1-e6998c3a9de0","keyword":"<span style=\"color:red\">脱氢</span><span style=\"color:red\">松香</span>酰<span style=\"color:red\">基</span><span style=\"color:red\">芳</span><span style=\"color:red\">酰胺基</span>硫脲","originalKeyword":"脱氢松香酰基芳酰胺基硫脲"},{"id":"76be1b84-a768-44d3-abca-3a71a859b43a","keyword":"<span style=\"color:red\">芳</span><span style=\"color:red\">基</span><span style=\"color:red\">脱氢</span><span style=\"color:red\">松香</span><span style=\"color:red\">酰胺基</span><span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>","originalKeyword":"芳基脱氢松香酰胺基噻二唑"},{"id":"68c2f702-bbd0-437d-aa3c-abd48067a8a8","keyword":"抑菌活性","originalKeyword":"抑菌活性"}],"language":"zh","publisherId":"yyhx200807011","title":"1-<span style=\"color:red\">脱氢</span><span style=\"color:red\">松香</span>酰<span style=\"color:red\">基</span>-3-<span style=\"color:red\">芳</span><span style=\"color:red\">酰胺基</span>硫脲及其1,3,4-<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>类衍生物的合成及抑菌活性","volume":"25","year":"2008"},{"abstractinfo":"2-氨基<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>与<span style=\"color:red\">芳</span>酰<span style=\"color:red\">基</span>异氰酸酯反应合成了13种N-(1,3,4-<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>-2<span style=\"color:red\">基</span>)-N'-的<span style=\"color:red\">芳</span>酰<span style=\"color:red\">基</span>脲,产率为54.5%～86.2%. 用核磁共振氢谱、红外光谱和元素分析确证了目标化合物的结构,室内的生物活性测定试验表明,目标化合物中的2b、2c、2e和2h具有优良的植物生长调节活性.","authors":[{"authorName":"张正文","id":"5f54a8ca-67c3-4ee2-81c7-9a4b342171d3","originalAuthorName":"张正文"},{"authorName":"王子云","id":"de245652-b3d7-4c0e-ba68-eae94ea52a32","originalAuthorName":"王子云"},{"authorName":"汪焱钢","id":"84320a04-cc12-4d8f-a2da-ee7632b078f5","originalAuthorName":"汪焱钢"},{"authorName":"陈传兵","id":"2d89b73f-73b7-4700-a977-96ce85e4bfd6","originalAuthorName":"陈传兵"},{"authorName":"宋新建","id":"50c4c5c3-8d75-4112-bce0-ff5dca3a1128","originalAuthorName":"宋新建"}],"doi":"10.3969/j.issn.1000-0518.2005.03.011","fpage":"278","id":"9dcb833d-c928-4a56-a9fe-775f9e1babe2","issue":"3","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"d3e3b664-a961-4593-bc63-825d6aa193f9","keyword":"<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>","originalKeyword":"噻二唑"},{"id":"aadd7729-57d5-49f9-b7c8-9edce6c6012b","keyword":"<span style=\"color:red\">芳</span>酰<span style=\"color:red\">基</span>脲","originalKeyword":"芳酰基脲"},{"id":"d9bd73ef-0acc-4b4e-9a8d-c6590b7a1bb2","keyword":"合成","originalKeyword":"合成"},{"id":"169ee1c3-7190-4920-acd2-85c74682c16b","keyword":"生物活性","originalKeyword":"生物活性"},{"id":"078e1005-119f-42cf-8b66-9580a627e3f3","keyword":"植物生长调节剂","originalKeyword":"植物生长调节剂"}],"language":"zh","publisherId":"yyhx200503011","title":"N-(1,3,4-<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>-2-<span style=\"color:red\">基</span>)-N'-<span style=\"color:red\">芳</span>酰<span style=\"color:red\">基</span>脲的合成及其生物活性","volume":"22","year":"2005"},{"abstractinfo":"通过2-氨基<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>与<span style=\"color:red\">芳</span>氧乙酰<span style=\"color:red\">基</span>异氰酸酯反应合成了11种新的N-(1,3,4-<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>-2-<span style=\"color:red\">基</span>)-N'-<span style=\"color:red\">芳</span>氧乙酰<span style=\"color:red\">基</span>脲化合物.产率为50.2%-68.7%.用红外光谱、核磁共振氢谱和元素分析测试技术确证了它们的结构,初步的生物活性测试实验表明,部分目标化合物具有优良的植物生长调节活性,其中2d、2e和2k生长素活性的促进率分别达到40.1%、35.5%和28.8%.","authors":[{"authorName":"陈传兵","id":"530f6d87-e088-4c11-966d-8d2d10711721","originalAuthorName":"陈传兵"},{"authorName":"张正文","id":"6958ec43-f4dd-4582-ba08-a7f3d1184304","originalAuthorName":"张正文"},{"authorName":"汪焱钢","id":"7d79da3b-d77c-4ed4-88e3-12b3b524ec13","originalAuthorName":"汪焱钢"}],"doi":"10.3969/j.issn.1000-0518.2008.07.023","fpage":"862","id":"bcd9393b-2b10-4188-96ba-64b65df6bcdb","issue":"7","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"bf22eec1-a293-4794-8052-e21fd85cba40","keyword":"氨基<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>","originalKeyword":"氨基噻二唑"},{"id":"a9251dfc-7a56-41ed-8e07-9c82c5d639e4","keyword":"<span style=\"color:red\">芳</span>氧乙酰<span style=\"color:red\">基</span>脲","originalKeyword":"芳氧乙酰基脲"},{"id":"227c8190-9b61-4371-92ec-7d29ecff9b48","keyword":"合成","originalKeyword":"合成"},{"id":"fcf8a61a-dc0e-4a7a-858a-5c469c57e10f","keyword":"生物活性","originalKeyword":"生物活性"},{"id":"28e9991f-615e-4ed9-9f5a-336cd1b2db6c","keyword":"生长紊","originalKeyword":"生长紊"}],"language":"zh","publisherId":"yyhx200807023","title":"N-(1,3,4-<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>-2-<span style=\"color:red\">基</span>)-N'-<span style=\"color:red\">芳</span>氧乙酰<span style=\"color:red\">基</span>脲的合成及其生物活性","volume":"25","year":"2008"},{"abstractinfo":"由化合物3-(4'-吡啶<span style=\"color:red\">基</span>)/苯基-4氨基5-巯基-1,2,4-三<span style=\"color:red\">唑</span>与芳香酸在三氯氧磷作用下脱水、闭环得到3-(4'-吡啶<span style=\"color:red\">基</span>)/苯基-3-<span style=\"color:red\">芳</span><span style=\"color:red\">基</span>-1,2,4-三<span style=\"color:red\">唑</span>并[3,4-b]-1,3,4-<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>类新型化合物,产率为42%～72%.该化合物具有较大的共轭平面,其结构经红外光谱、核磁共振氢谱、元素分析测试技术确证.电化学测试的工作窗口为-1.4～1.0 V,负向扫描,循环伏安图中显示标题化合物均有还原峰,还原起始电位为-0.35～-0.95 V.借鉴有机材料能带表征的方法,结合其紫外-可见光谱计算出了被测化合物的电子亲和势、电离势、带隙等电化学参数.结果表明,与常用的有机电子传输材料PBD相比,标题化合物具有较高的电子亲和势(3.79～4.39 eV)和电离势(6.95～7.84eV),较高的电子亲和势有利于电子的传输.","authors":[{"authorName":"谈春霞","id":"73fad801-07a1-4532-aa2b-8b912c26f8dc","originalAuthorName":"谈春霞"},{"authorName":"冯若飞","id":"11ebdcae-2e59-4ddc-99b6-9f26d8fddcb0","originalAuthorName":"冯若飞"}],"doi":"10.3969/j.issn.1000-0518.2007.11.023","fpage":"1332","id":"b85ca631-6ff6-4a0e-ace7-c6191a722a43","issue":"11","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"7ea5aa8e-ae86-41f7-837c-40726afe9eeb","keyword":"均三<span style=\"color:red\">唑</span>并<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>","originalKeyword":"均三唑并噻二唑"},{"id":"45f389a8-68f9-4f1f-b64f-fae6e5acf8d0","keyword":"循环伏安","originalKeyword":"循环伏安"},{"id":"f38ac512-320d-4d3c-8abd-93c9c0f32bea","keyword":"电子传输","originalKeyword":"电子传输"}],"language":"zh","publisherId":"yyhx200711023","title":"3-(4'-吡啶<span style=\"color:red\">基</span>)/苯基-6-<span style=\"color:red\">芳</span><span style=\"color:red\">基</span>-1,2,4-三<span style=\"color:red\">唑</span>并[3,4-b]-1,3,4-<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>的合成及电化学性质表征","volume":"24","year":"2007"},{"abstractinfo":"以2-氨基-5-取代-l,3,4-<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>为起始原料,设计合成16个含l,3,4-<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>取代<span style=\"color:red\">基</span>的中间体4a～4p,进而使其在POCl3及DMF作用下反应得到16个3-取代-1-(5-<span style=\"color:red\">芳</span><span style=\"color:red\">基</span>-1,3,4-<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>-2-<span style=\"color:red\">基</span>)-1H-吡唑-4-甲醛化合物5a～5p,所合成的32个化合物均为新化合物.采用溶液结晶法获得化合物5a晶体,通过X射线单晶衍射测得该晶体属于三斜晶系,P-1空间群.借助IR、1H NMR、元素分析等技术手段对合成的所有化合物结构进行了表征.利用微量稀释法测试了化合物5a ～5p的抑菌活性,结果表明,部分化合物对金黄色葡萄球菌具有抑制作用,在相同条件下化合物5h的抑菌活性最好,抑菌率达到65.30％.","authors":[{"authorName":"徐畅","id":"238a801d-feb7-4a09-b493-60aa8e162de4","originalAuthorName":"徐畅"},{"authorName":"安悦","id":"f35902cd-6b88-4fa3-9145-20c23e4aa35d","originalAuthorName":"安悦"},{"authorName":"朱浩天","id":"249cecf6-c0df-48ed-9a78-73f7938ae79b","originalAuthorName":"朱浩天"},{"authorName":"林越","id":"df3df5d3-3093-49d2-be31-20d60dc8991e","originalAuthorName":"林越"},{"authorName":"王日楠","id":"9c05ad9b-bda6-4200-b4ad-0f11948b0195","originalAuthorName":"王日楠"}],"doi":"10.11944/j.issn.1000-0518.2015.07.140421","fpage":"748","id":"576cdacc-be0a-4f9b-a96f-0752c6db8904","issue":"7","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"814c48ff-46bc-4d87-923c-bcac86612c54","keyword":"<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>","originalKeyword":"噻二唑"},{"id":"486d3090-f94b-46f4-b253-495c95246b34","keyword":"吡唑","originalKeyword":"吡唑"},{"id":"9f78828e-c004-45ff-a83b-3d443b38cec8","keyword":"合成","originalKeyword":"合成"},{"id":"7a236987-cece-42c2-9b7a-76f382dc4800","keyword":"有机单晶","originalKeyword":"有机单晶"},{"id":"6f9a2198-b637-4402-9813-15a1a1694e4d","keyword":"生物活性","originalKeyword":"生物活性"}],"language":"zh","publisherId":"yyhx201507003","title":"3-取代-1-(5-<span style=\"color:red\">芳</span><span style=\"color:red\">基</span>-1,3,4-<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>-2-<span style=\"color:red\">基</span>)-1H-吡唑-4-甲醛的合成、晶体结构及抑菌活性","volume":"32","year":"2015"},{"abstractinfo":"将1-取代<span style=\"color:red\">芳</span><span style=\"color:red\">基</span>-4-乙氧羰基-5-氨基-1,2,3-连三<span style=\"color:red\">唑</span>与苯甲酰氯,氯乙酰氯,丙酰氯,乙酰氯等反应合成了21种标题连三<span style=\"color:red\">唑</span>化合物(1),收率在61%～91%之间.讨论了酰氯性质与收率之间的关系.所有含杂环化合物的结构皆用元素分析,IR,x1H NMR及MS作了表征.筛选了它们对以下细菌的抑菌性能:Klebsiella,Escherichia coli ,Psendomonas aeruginosa ,Stethlococcus aureus 和Proteus vulgaris.","authors":[{"authorName":"陈敏东","id":"8e120800-f5d2-451b-a325-f844ddf60351","originalAuthorName":"陈敏东"},{"authorName":"袁建超","id":"42c26332-4ebb-4f05-b8da-609dfd3c5660","originalAuthorName":"袁建超"},{"authorName":"吕士杰","id":"92f54d1b-6a4c-417f-8521-8e431e4a35d3","originalAuthorName":"吕士杰"},{"authorName":"杜小丽","id":"f054f082-3840-4570-a655-0e3eb7c3e2c5","originalAuthorName":"杜小丽"},{"authorName":"袁光谱","id":"69fa0ecd-0b86-4ca7-b1ed-65667b9d8b49","originalAuthorName":"袁光谱"},{"authorName":"杨世琰","id":"a1799afb-31e9-41df-ba9f-13c4beaeaa3a","originalAuthorName":"杨世琰"}],"doi":"10.3969/j.issn.1000-0518.2001.10.002","fpage":"772","id":"d59f0b0f-04a7-4d9c-905c-4c27c957e623","issue":"10","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"0d3db81b-039b-4b94-8b4a-33295ccb29e5","keyword":"连三<span style=\"color:red\">唑</span>","originalKeyword":"连三唑"},{"id":"9aa72efb-7830-4f93-b262-2fc28d321dab","keyword":"合成","originalKeyword":"合成"},{"id":"09fc39e8-f10f-43a9-9f1f-29bcc94a1b66","keyword":"抑菌性能","originalKeyword":"抑菌性能"},{"id":"29e3efa2-1f20-4216-9535-1e44cb22449f","keyword":"酰氯","originalKeyword":"酰氯"}],"language":"zh","publisherId":"yyhx200110002","title":"新的1-取代<span style=\"color:red\">芳</span><span style=\"color:red\">基</span>-4-乙氧羰基-5-<span style=\"color:red\">酰胺基</span>- 1,2,3-三<span style=\"color:red\">唑</span>的合成及抑菌性能","volume":"18","year":"2001"},{"abstractinfo":"通过2-氨基-5-(1-邻氯苯氧乙基)-1,3,4-<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>与<span style=\"color:red\">芳</span>酰<span style=\"color:red\">基</span>异氰酸酯反应,合成了13种新的<span style=\"color:red\">芳</span>酰<span style=\"color:red\">基</span>脲.采用红外光谱,核磁共振氢谱和元素分析测试技术确证了结构.初步的生物活性测定试验表明,目标化合物具有良好的生长素活性,其中化合物2c、2d和2h的促进率分别为30.1%、32.5%和29.9%.","authors":[{"authorName":"宋新建","id":"57d7ba95-8959-45bd-b218-26fb5c9d272a","originalAuthorName":"宋新建"},{"authorName":"王胜","id":"4a192c85-66a4-4778-862c-832737f55b23","originalAuthorName":"王胜"},{"authorName":"吴绍艳","id":"6c8cfe39-380e-407f-9fda-244b93444d93","originalAuthorName":"吴绍艳"},{"authorName":"汪焱钢","id":"aef7b0c3-f989-4b76-adfc-3e7e5beea702","originalAuthorName":"汪焱钢"}],"doi":"10.3969/j.issn.1000-0518.2006.04.024","fpage":"444","id":"31524e46-f17c-4a80-ab1a-3c5eaf94d2c0","issue":"4","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"80b10c86-696a-45e5-a477-f832af9ef385","keyword":"<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>","originalKeyword":"噻二唑"},{"id":"301d557d-aaf3-49e2-addf-54213117a0db","keyword":"<span style=\"color:red\">芳</span>酰<span style=\"color:red\">基</span>脲","originalKeyword":"芳酰基脲"},{"id":"384a4857-fdf4-4932-bf6f-5eeb3e4c9f42","keyword":"生物活性","originalKeyword":"生物活性"},{"id":"ba5b0f0b-4fad-4ac0-acdf-06ae7b9898ad","keyword":"生长素","originalKeyword":"生长素"},{"id":"86d35751-2523-4aff-a4ac-607861e7cfce","keyword":"细胞分裂素","originalKeyword":"细胞分裂素"}],"language":"zh","publisherId":"yyhx200604024","title":"N-[5-(1-邻氯苯氧乙基)-1,3,4-<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>-2-<span style=\"color:red\">基</span>]-N'-<span style=\"color:red\">芳</span>酰<span style=\"color:red\">基</span>脲的合成及其生物活性","volume":"23","year":"2006"},{"abstractinfo":"合成了同时含有偶氮苯和1,3,4-<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>的新型聚<span style=\"color:red\">酰胺</span>(P1,P2),采用FT-IR、1H NMR、GPC和TGA技术对其结构进行了表征和热性能测试.P1和P2的特性粘数分别为0.14和0.12 dL/g,质均相对分子质量Mw和相对分子质量分布指数PDI分别为28.8、24.8 kg/mol和1.71、1.74,质量损失5％的温度分别为320和322℃.长烷氧基侧链的引入改善了聚合物在氯仿和四氢呋喃等有机溶剂中的溶解性.采用紫外-可见吸收光谱、荧光光谱对聚合物的光学性能进行了研究.结果表明,在365 nm紫外光照射下,聚合物中偶氮苯发生反-顺异构化,P1和P2光稳态时顺式异构体比例分别为86.8％和77.4％,反-顺异构化效率分别为82.7％和73.7％.在366和363 nm光激发下,P1和P2的固体分别在418和425 nm处紫光波长范围内发射荧光.","authors":[{"authorName":"齐程远","id":"a4725085-cc9e-4484-a948-37c73bc33ca8","originalAuthorName":"齐程远"},{"authorName":"于世钧","id":"aa190e88-659a-4440-9530-4cd98127d675","originalAuthorName":"于世钧"},{"authorName":"王红","id":"40082a02-94a3-415b-b609-d3bf3a594099","originalAuthorName":"王红"},{"authorName":"王赫麟","id":"79106f81-4fbd-4e91-803e-9befc3b0777c","originalAuthorName":"王赫麟"},{"authorName":"靳奇峰","id":"e3d05cc0-4d27-4425-a742-9f505bbf44be","originalAuthorName":"靳奇峰"}],"doi":"10.3724/SP.J.1095.2012.00576","fpage":"1240","id":"923d6438-7fb8-4c17-8172-8e6c174540ce","issue":"11","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"b67b2cf8-9ea7-4dc9-99b2-f4fb5149234c","keyword":"偶氮苯","originalKeyword":"偶氮苯"},{"id":"01119d2b-2cc9-45cc-a701-eba05c4baf6a","keyword":"<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>","originalKeyword":"噻二唑"},{"id":"4df5cbeb-67f1-4398-803c-23f3bfff066b","keyword":"聚<span style=\"color:red\">酰胺</span>","originalKeyword":"聚酰胺"},{"id":"8dfc1c28-0ff1-4d8d-8e92-a3f5e4219866","keyword":"合成","originalKeyword":"合成"},{"id":"916058c3-e7e7-4c0a-abf8-cfbfd48b329f","keyword":"光学性能","originalKeyword":"光学性能"}],"language":"zh","publisherId":"yyhx201211003","title":"含1,3,4-<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>和偶氮苯聚<span style=\"color:red\">酰胺</span>的合成及其光学性能","volume":"29","year":"2012"},{"abstractinfo":"1-苯基-3-甲基-5-氯-4-吡唑甲醛与4-氨基-5-取代苯基-1,2,4-三<span style=\"color:red\">唑</span>-3-硫酮缩合生成4-(1-苯基-3-甲基-5-氯吡唑次甲亚<span style=\"color:red\">胺基</span>)-5-(取代苯基)-2H-1,2,4-三<span style=\"color:red\">唑</span>-3(4H)-硫酮,再烷基加成化为新型含吡唑<span style=\"color:red\">基</span>5,6-2H-1,2,4-三<span style=\"color:red\">唑</span>[3,4-b][1,3,4]<span style=\"color:red\">噻</span><span style=\"color:red\">二</span>嗪衍生物.化合物结构经1H NMR、IR以及元素分析确认.初步生物活性测试结果表明,在100 mg/L浓度下,化合物8a(3-(2-甲基苯基)-6-(5-氯-2-甲基4-苯基吡唑)-7-(4-硝基苯基)-5H-1,2,4-三<span style=\"color:red\">唑</span>[3,4-b][1,3,4]<span style=\"color:red\">噻</span><span style=\"color:red\">二</span>嗪)对黄瓜炭疽病的抑制率达90％.","authors":[{"authorName":"郑玉国","id":"b696fef1-4152-4b2f-b8c0-9e9ac182e583","originalAuthorName":"郑玉国"},{"authorName":"郭晴晴","id":"e1e210d3-f96b-4773-a4c0-2b11ecc0ee1f","originalAuthorName":"郭晴晴"},{"authorName":"周莉","id":"f2a26d34-9356-42a8-a6c4-83ac1b1bd944","originalAuthorName":"周莉"},{"authorName":"李世杰","id":"ac302c30-cb8f-4537-93a1-c34955cf2b8c","originalAuthorName":"李世杰"},{"authorName":"余忠林","id":"00c4a2f5-3c8e-4c0a-8034-02c18c18faa6","originalAuthorName":"余忠林"},{"authorName":"刘翠菊","id":"35a4d34b-ce42-4cc7-a47e-0700282f2e58","originalAuthorName":"刘翠菊"},{"authorName":"熊香","id":"d315d33a-3467-4f52-b626-6390444660a2","originalAuthorName":"熊香"}],"doi":"10.11944/j.issn.1000-0518.2015.02.140163","fpage":"151","id":"6cbdc434-1543-400e-bcd0-825ef64a281e","issue":"2","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"aba77f0c-9099-4b80-a89d-a5fcb99aa207","keyword":"吡唑","originalKeyword":"吡唑"},{"id":"d164eb86-7c8c-459a-aa9e-3624b4b2aea6","keyword":"三<span style=\"color:red\">唑</span>[3,4-b][1,3,4]<span style=\"color:red\">噻</span><span style=\"color:red\">二</span>嗪","originalKeyword":"三唑[3,4-b][1,3,4]噻二嗪"},{"id":"7e0b727b-a022-41f7-9721-4be01e4751b0","keyword":"合成","originalKeyword":"合成"},{"id":"caecc975-fe6f-4b19-88c2-e7055ddcbdae","keyword":"生物活性","originalKeyword":"生物活性"}],"language":"zh","publisherId":"yyhx201502004","title":"含吡唑1,2,4-三<span style=\"color:red\">唑</span><span style=\"color:red\">噻</span><span style=\"color:red\">二</span>嗪衍生物的合成及抑菌活性","volume":"32","year":"2015"},{"abstractinfo":"合成了两个系列以1,3,4-<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>为中心基团的弯曲型分子,结合偏光显微熔点仪(POM)观察和差示量热扫描法(DSC)研究了它们的液晶性能.研究发现,这两类弯曲型分子都会出现N相.其中,对称型五环酯类<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>弯曲型分子的熔点都较高,清亮点均超过360℃；含烯丙基非对称<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>类弯曲型分子熔点和清亮点温度大幅度降低,N相的温区较宽,以庚基为端<span style=\"color:red\">基</span>链的弯曲型分子出现N相的温度区间超过120℃.","authors":[{"authorName":"李双全","id":"e5bf21ef-0e7c-41d3-912c-003a7595fd07","originalAuthorName":"李双全"},{"authorName":"沈冬","id":"77c289bd-ab0e-45de-95a1-e4b3fd3c3bd9","originalAuthorName":"沈冬"}],"doi":"10.3788/YJYXS20112604.0421","fpage":"421","id":"73dafbde-7ee5-435a-b458-c38444e07bbb","issue":"4","journal":{"abbrevTitle":"YJYXS","coverImgSrc":"journal/img/cover/YJYXS.jpg","id":"72","issnPpub":"1007-2780","publisherId":"YJYXS","title":"液晶与显示   "},"keywords":[{"id":"f6ab93d4-d562-4015-9976-89e307552d4f","keyword":"1,3,4-<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>","originalKeyword":"1,3,4-噻二唑"},{"id":"2799b8b9-8a19-4e23-a435-f838fb8c9f8b","keyword":"弯曲型分子","originalKeyword":"弯曲型分子"},{"id":"2dd6a720-32dc-43d9-adb8-085cd79c5716","keyword":"向列相","originalKeyword":"向列相"}],"language":"zh","publisherId":"yjyxs201104001","title":"<span style=\"color:red\">噻</span><span style=\"color:red\">二</span><span style=\"color:red\">唑</span>类弯曲型液晶分子的合成和性能研究","volume":"26","year":"2011"}],"totalpage":4681,"totalrecord":46810}