{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"采用二丁基镁(MgBu2)部分或全部代替三异丁基铝(Al(i-Bu)3)作为<span style=\"color:red\">镍</span><span style=\"color:red\">催化</span><span style=\"color:red\">体系</span>的烷基化试剂,构成Ni(naph)2-MgBu2-BF3OEt2<span style=\"color:red\">体系</span>和Ni(naph)2-Al(i-Bu)3-MgBu2-BF3OEt2<span style=\"color:red\">体系</span>合成高顺式聚丁二烯橡胶.研究了<span style=\"color:red\">体系</span>在不同陈化方式和温度下的聚合反应动力学,并对聚合产物进行了测试表征.动力学研究结果表明,MgBu2的加入能增大Ni-Al-B<span style=\"color:red\">体系</span>的聚合反应活性,且Ni-Mg-B<span style=\"color:red\">体系</span>的聚合反应活性明显高于Ni-Al-B<span style=\"color:red\">体系</span>和Ni-Al-Mg-B<span style=\"color:red\">体系</span>;聚合产物测试结果表明,聚丁二烯的顺1,4-结构稍有下降,其相对分子质量、分子量分布以及门尼黏度等基本保持不变.","authors":[{"authorName":"刘炼","id":"e38ecb6a-c9f6-4b0d-a446-1f15644bf3b7","originalAuthorName":"刘炼"},{"authorName":"胡百九","id":"2dcec1be-dda3-4fab-8a0a-48401b0e1020","originalAuthorName":"胡百九"},{"authorName":"魏志勇","id":"8f7ab19f-ca31-4e18-900b-863898a148a5","originalAuthorName":"魏志勇"},{"authorName":"史云龙","id":"3fe2abcf-ef35-4e74-b28a-06a84d5a7ca2","originalAuthorName":"史云龙"},{"authorName":"张春庆","id":"b33f99b3-f4a5-4caf-bf13-fb9b0ac923d4","originalAuthorName":"张春庆"},{"authorName":"王玉荣","id":"5d88380e-d68f-4f79-91cf-a15ae927ca91","originalAuthorName":"王玉荣"},{"authorName":"廖明义","id":"a8148a99-d5ab-44ef-b098-8021f52be4f9","originalAuthorName":"廖明义"}],"doi":"","fpage":"32","id":"7a944b3b-e7f2-4a47-968a-d16043f96ac7","issue":"6","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"1c58a059-7ff8-4d05-9d94-b04afc3022fd","keyword":"<span style=\"color:red\">镍</span><span style=\"color:red\">催化</span><span style=\"color:red\">体系</span>","originalKeyword":"镍催化体系"},{"id":"65ac0525-509d-4037-96c7-6e62a2810b3e","keyword":"聚丁二烯","originalKeyword":"聚丁二烯"},{"id":"67ea9077-bb4d-4497-b226-153babd78d7b","keyword":"二丁基镁","originalKeyword":"二丁基镁"},{"id":"bfedee28-b2d2-4ca4-b0b3-754d36b75f23","keyword":"动力学","originalKeyword":"动力学"}],"language":"zh","publisherId":"gfzclkxygc200606008","title":"二丁基镁对<span style=\"color:red\">镍</span><span style=\"color:red\">催化</span><span style=\"color:red\">体系</span>合成高顺式聚丁二烯的影响","volume":"22","year":"2006"},{"abstractinfo":"为了研究钴<span style=\"color:red\">镍</span>电极在中性<span style=\"color:red\">体系</span>中的电<span style=\"color:red\">催化</span>性能和<span style=\"color:red\">催化</span>循环稳定性,在金属钛电极上采用电沉积方法制备了不同钴含量的<span style=\"color:red\">镍</span>涂层电极,通过X射线衍射技术、扫描电镜技术、恒电流极化曲线和循环伏安等测试技术,探讨了不同钴元素的添加量对<span style=\"color:red\">镍</span>涂层电极在中性<span style=\"color:red\">体系</span>中析氧电<span style=\"color:red\">催化</span>活性和循环稳定性的影响.结果表明,添加适量的钴元素细化了镀层晶粒,增大了电极比表面积,提高了电极的析氧<span style=\"color:red\">催化</span>活性,其中添加40g/L CoSO_4·5H_2O时涂层的晶粒最细,继续增加钴含量颗粒变大但形状多面,比表面积没有减小,对电极析氧<span style=\"color:red\">催化</span>性能影响不大;同时钴的添加不利于晶体的结晶,降低了电极表面状态的循环稳定性能.","authors":[{"authorName":"高红","id":"d8dbadb2-0962-4b6e-a3e6-77992a314073","originalAuthorName":"高红"},{"authorName":"朱承飞","id":"c154b299-3613-4b13-bada-ca39bd2c4338","originalAuthorName":"朱承飞"},{"authorName":"解瑞","id":"32ca57ca-2d72-468a-afac-61583ffea3f1","originalAuthorName":"解瑞"},{"authorName":"王晓钧","id":"62c3c82f-06b3-4307-8046-aea26f01a28c","originalAuthorName":"王晓钧"}],"doi":"","fpage":"15","id":"8356c989-7ba4-4e26-a044-2c47c881d983","issue":"11","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"1044a03b-c161-4b56-adfe-15aba456db5a","keyword":"<span style=\"color:red\">镍</span>电极","originalKeyword":"镍电极"},{"id":"26cbb392-15d6-41c4-a8b3-f8a080d2f3ed","keyword":"钴","originalKeyword":"钴"},{"id":"66bab06f-a149-4440-9729-b4cb5b069b8d","keyword":"析氧","originalKeyword":"析氧"},{"id":"4021f223-9067-4260-9533-7172caa936be","keyword":"中性<span style=\"color:red\">体系</span>","originalKeyword":"中性体系"},{"id":"0c2cac50-cacd-41a7-b1c8-ed8f60833785","keyword":"电<span style=\"color:red\">催化</span>活性","originalKeyword":"电催化活性"},{"id":"a9ca66f7-7e1b-479e-a636-d9b293ab1fae","keyword":"循环稳定性","originalKeyword":"循环稳定性"}],"language":"zh","publisherId":"clbh200911005","title":"中性<span style=\"color:red\">体系</span>中钴对<span style=\"color:red\">镍</span>电极析氧<span style=\"color:red\">催化</span>性能的影响","volume":"42","year":"2009"},{"abstractinfo":"综述了烷基铝对α-二亚胺<span style=\"color:red\">镍</span><span style=\"color:red\">催化</span><span style=\"color:red\">体系</span>在聚合反应中所产生的影响。甲基铝氧烷（MAO）以其较高的活化能力广泛运用于α-二亚胺<span style=\"color:red\">镍</span>等<span style=\"color:red\">催化</span><span style=\"color:red\">体系</span>中。三甲基铝（TMA）、三异丁基铝（TiBA）等无氯烷基铝也都有一定的活化能力,但远不如MAO。二乙基氯化铝（DEAC）、倍半乙基氯化铝（EASC）等含氯烷基铝有较强的活化能力,甚至比MAO的活化作用强得多,其中EASC和α-二亚胺<span style=\"color:red\">镍</span>配合可以使乙烯的聚合速率高达3966 kg PE/（mol Ni.h）。","authors":[{"authorName":"傅智盛","id":"559137bc-e206-4208-8cc2-99261690bc44","originalAuthorName":"傅智盛"},{"authorName":"蔡俊飞","id":"0ce8bd0d-814e-4a35-b108-70b67c95f961","originalAuthorName":"蔡俊飞"},{"authorName":"杨洪瑞","id":"bb174c9f-1b15-474d-b3fc-45ef69c2d58b","originalAuthorName":"杨洪瑞"},{"authorName":"范志强","id":"c910b1e6-c99c-47eb-a483-21b3d29787e1","originalAuthorName":"范志强"}],"doi":"","fpage":"165","id":"b3e4b0c5-b9b4-4d44-9915-42c4ff0c316f","issue":"2","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"6f28d907-31bd-4f44-a7c9-8dd40129dadd","keyword":"烷基铝","originalKeyword":"烷基铝"},{"id":"b29019b8-72a1-4096-828f-fbba14406d9b","keyword":"<span style=\"color:red\">催化</span>剂","originalKeyword":"催化剂"},{"id":"158f6407-8469-41f7-98cf-d1d6a2bcd39a","keyword":"后过渡金属","originalKeyword":"后过渡金属"},{"id":"95e48eb2-4aba-4deb-bfa3-457dfe43b495","keyword":"活化","originalKeyword":"活化"}],"language":"zh","publisherId":"gfzclkxygc201202044","title":"烷基铝在α-二亚胺<span style=\"color:red\">镍</span><span style=\"color:red\">催化</span><span style=\"color:red\">体系</span>中的应用","volume":"28","year":"2012"},{"abstractinfo":"采用双-(β-酮萘胺)<span style=\"color:red\">镍</span>(Ⅱ)为主<span style=\"color:red\">催化</span>剂,以甲基铝氧烷(MAO)为助<span style=\"color:red\">催化</span>剂,在甲苯溶剂中进行了苯乙烯聚合实验,并考察了聚合温度、Al/Ni摩尔比、单体浓度和聚合时间等因素对聚合反应的影响. 结果表明,双-(β-酮萘胺)<span style=\"color:red\">镍</span>(Ⅱ)/MAO<span style=\"color:red\">催化</span>剂显示出很高的<span style=\"color:red\">催化</span>活性,可<span style=\"color:red\">催化</span>苯乙烯聚合得到中等分子量和分子量分布较窄(Mw/Mn＜1.6)的聚苯乙烯. 采用核磁共振氢谱、核磁共振碳谱、傅里叶变换红外光谱、差示扫描量热法和广角X射线衍射技术对聚合产物进行了表征. 结果表明,所得聚合物为无规聚苯乙烯.","authors":[{"authorName":"刘永明","id":"9b8ad78f-93e3-4f6b-a6ab-d6ca96e5fa05","originalAuthorName":"刘永明"},{"authorName":"贺晓慧","id":"5576775f-005f-4498-ba25-a41564f58a24","originalAuthorName":"贺晓慧"},{"authorName":"陈义旺","id":"0a1522d3-7e1c-4efa-bc1b-9b7afcf36a83","originalAuthorName":"陈义旺"},{"authorName":"伍青","id":"2d9c4900-aabf-49e4-ae9b-50fecb808725","originalAuthorName":"伍青"}],"doi":"","fpage":"349","id":"97c0eea1-5b2c-4960-bfd9-df714f7f1fb6","issue":"4","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"32afd1f8-13b3-4f0f-a06f-72f1e2f2cadf","keyword":"<span style=\"color:red\">镍</span>","originalKeyword":"镍"},{"id":"e9b34f95-542b-4d52-a16e-e6b4d01f34bc","keyword":"络合物","originalKeyword":"络合物"},{"id":"085778c7-8079-4507-9273-a80c81aab554","keyword":"后过渡金属<span style=\"color:red\">催化</span>剂","originalKeyword":"后过渡金属催化剂"},{"id":"c2e037dd-51de-4c8c-b719-ae69428040e1","keyword":"苯乙烯","originalKeyword":"苯乙烯"},{"id":"d3258e41-4430-4263-85d0-2b607190cd45","keyword":"聚合","originalKeyword":"聚合"},{"id":"f64d9b8a-a87d-4fde-ae15-b9c153734f51","keyword":"聚苯乙烯","originalKeyword":"聚苯乙烯"}],"language":"zh","publisherId":"cuihuaxb200604015","title":"双-(β-酮萘胺)<span style=\"color:red\">镍</span>(Ⅱ)/MAO<span style=\"color:red\">催化</span>剂<span style=\"color:red\">体系</span><span style=\"color:red\">催化</span>苯乙烯聚合","volume":"27","year":"2006"},{"abstractinfo":"评价了一系列中性水杨醛亚胺<span style=\"color:red\">镍</span>(Ⅱ)膦配合物在烷基铝作用下<span style=\"color:red\">催化</span>丙烯二聚反应的性能,并从铝<span style=\"color:red\">镍</span>比,烷基铝助剂的种类,丙烯压力,水杨醛亚胺配体上不同取代基等方面进行了考察. 结果表明,这一<span style=\"color:red\">催化</span><span style=\"color:red\">体系</span>对丙烯二聚具有相当高的活性(30000～100*!000 h-1)和较高的二聚选择性(40%～70%);二聚体以4-甲基戊烯为主,含部分2-甲基戊烯和己烯,以及少量的二甲基丁烯.","authors":[{"authorName":"吴思忠","id":"48cca2e4-9494-4a62-87c3-407ef14305b0","originalAuthorName":"吴思忠"},{"authorName":"陆世维","id":"d9b86647-a585-4ee8-bfd0-3d0718e8cad2","originalAuthorName":"陆世维"}],"doi":"","fpage":"133","id":"973a1eac-02b6-43a8-a2cd-bf4e745cf8aa","issue":"2","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"197c238a-cdd3-4154-aaa4-b1f5ce8f02f8","keyword":"水杨醛亚胺配体,<span style=\"color:red\">镍</span>(Ⅱ)膦配合物,丙烯,二聚,甲基戊烯,己烯,二甲基丁烯,烷基铝助剂","originalKeyword":"水杨醛亚胺配体,镍(Ⅱ)膦配合物,丙烯,二聚,甲基戊烯,己烯,二甲基丁烯,烷基铝助剂"}],"language":"zh","publisherId":"cuihuaxb200202012","title":"中性水杨醛亚胺<span style=\"color:red\">镍</span>(Ⅱ)膦<span style=\"color:red\">体系</span><span style=\"color:red\">催化</span>丙烯二聚反应","volume":"23","year":"2002"},{"abstractinfo":"采用双-(β-酮萘胺)<span style=\"color:red\">镍</span>(Ⅱ)/B(C6F5)3/AlEt3<span style=\"color:red\">体系</span>可在20～90 ℃范围内在甲苯溶剂中<span style=\"color:red\">催化</span>醋酸降冰片烯酯聚合,得到中等分子量(Mw＝7.0×103～3.1×104 g/mol)和分子量分布较窄(Mw/Mn为1.8～2.0)的醋酸降冰片烯酯聚合物.采用1H NMR、13C NMR、FT-IR、DSC、TGA及广角X射线衍射(WAXD)等技术对所得聚合物进行了结构表征和性能测试.结果表明,所得的聚醋酸降冰片烯酯为加成型产物,证明此<span style=\"color:red\">催化</span><span style=\"color:red\">体系</span><span style=\"color:red\">催化</span>醋酸降冰片烯酯聚合是按乙烯基加成模式进行的;所得聚合产物为非晶态,具有短程有序长程无序的特征,分子链间的距离为1.24 nm;聚合产物具有较好的热稳定性(Td＞330 ℃),并能够溶解在大部分普通有机溶剂中.","authors":[{"authorName":"陈木青","id":"3949823e-6ea5-4037-9106-9c65e07e1a8a","originalAuthorName":"陈木青"},{"authorName":"贺晓慧","id":"d621b0ae-c0cb-4783-a503-d80a13cfeda7","originalAuthorName":"贺晓慧"},{"authorName":"陈义旺","id":"2209bbef-3781-4143-968a-d00d224c2214","originalAuthorName":"陈义旺"},{"authorName":"周魏华","id":"c8ae85a5-2760-4779-85a0-bc02e2994cb3","originalAuthorName":"周魏华"},{"authorName":"石玲","id":"af454ed4-bcfe-4413-97df-36a32e2179ab","originalAuthorName":"石玲"},{"authorName":"何福平","id":"38d13922-977f-43cf-a0c1-86d47b9f8b20","originalAuthorName":"何福平"},{"authorName":"伍青","id":"d0c2f343-e1f9-42db-89c1-8bb635cd17d5","originalAuthorName":"伍青"}],"doi":"10.3969/j.issn.1000-0518.2009.08.010","fpage":"923","id":"e0878e9a-ff89-4648-aac1-a4bf562fb02d","issue":"8","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"6311f8d5-a049-464d-89e1-1a05afe34da1","keyword":"<span style=\"color:red\">镍</span>(Ⅱ)配合物","originalKeyword":"镍(Ⅱ)配合物"},{"id":"a958f9c4-7e8b-49b2-b347-65b9bfe9b3bc","keyword":"醋酸降冰片烯酯","originalKeyword":"醋酸降冰片烯酯"},{"id":"66136b8b-0de2-4b22-9073-290ad3c8f08b","keyword":"<span style=\"color:red\">催化</span>聚合","originalKeyword":"催化聚合"}],"language":"zh","publisherId":"yyhx200908010","title":"双-(β-酮萘胺)<span style=\"color:red\">镍</span>(Ⅱ)/B(C6F5)3/AlEt3<span style=\"color:red\">体系</span><span style=\"color:red\">催化</span>醋酸降冰片烯酯的聚合","volume":"26","year":"2009"},{"abstractinfo":"硫酸盐镀<span style=\"color:red\">镍</span>是目前国内应用最广的镀<span style=\"color:red\">镍</span><span style=\"color:red\">体系</span>.本文阐述了硫酸盐镀<span style=\"color:red\">镍</span>的机理,介绍了镀暗<span style=\"color:red\">镍</span>、光亮镀<span style=\"color:red\">镍</span>、珍珠<span style=\"color:red\">镍</span>、黑<span style=\"color:red\">镍</span>以及<span style=\"color:red\">镍</span>基合金的工艺配方及添加剂的发展历程.","authors":[{"authorName":"丰志文","id":"56a67112-aa28-4ff9-8659-5c3610b3a569","originalAuthorName":"丰志文"}],"doi":"10.3969/j.issn.1004-227X.2002.01.013","fpage":"46","id":"7b456134-5ed0-47f6-a4f6-8b39abb63d7c","issue":"1","journal":{"abbrevTitle":"DDYTS","coverImgSrc":"journal/img/cover/DDYTS.jpg","id":"21","issnPpub":"1004-227X","publisherId":"DDYTS","title":"电镀与涂饰   "},"keywords":[{"id":"5812f6da-584d-4427-929e-c1bca5bc36dd","keyword":"镀<span style=\"color:red\">镍</span>","originalKeyword":"镀镍"},{"id":"ec5e6549-9191-41c9-8345-3c0f3b754a19","keyword":"硫酸盐","originalKeyword":"硫酸盐"}],"language":"zh","publisherId":"ddyts200201013","title":"硫酸盐镀<span style=\"color:red\">镍</span><span style=\"color:red\">体系</span>的研究","volume":"21","year":"2002"},{"abstractinfo":"主要讨论了氢对甲醇气相羰基化<span style=\"color:red\">催化</span><span style=\"color:red\">体系</span>的影响. 采用多孔碳化聚偏二氯乙烯小球负载金属<span style=\"color:red\">镍</span><span style=\"color:red\">催化</span><span style=\"color:red\">体系</span>,在不同进气条件下进行甲醇羰基化反应,得到不同氢含量时<span style=\"color:red\">催化</span>剂的活性和稳定性数据,以及氢对<span style=\"color:red\">催化</span><span style=\"color:red\">体系</span>的微扰数据,并对<span style=\"color:red\">催化</span>剂的表面形态用SEM进行了表征,以评价氢的影响. 从三个方面分析了氢对气相甲醇羰基化<span style=\"color:red\">催化</span><span style=\"color:red\">体系</span>的影响,认为适量存在的氢对长时间保持<span style=\"color:red\">催化</span>剂活性是有利的.","authors":[{"authorName":"李峰波","id":"946fef90-c01a-4eaa-8a11-614699b9d792","originalAuthorName":"李峰波"},{"authorName":"邹瑾","id":"51dd0151-a38f-49e6-b399-aae4e6785abc","originalAuthorName":"邹瑾"},{"authorName":"袁国卿","id":"811b578c-24cd-46a6-b1aa-2aac098657c6","originalAuthorName":"袁国卿"}],"doi":"","fpage":"539","id":"65993a5a-1614-4e7f-88ce-3c1aac9a189a","issue":"7","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"387d80c0-b108-4690-a13a-5b983f47a84b","keyword":"多孔碳小球","originalKeyword":"多孔碳小球"},{"id":"6767e303-22ec-4fc7-8d2e-ada82a55557c","keyword":"<span style=\"color:red\">镍</span>","originalKeyword":"镍"},{"id":"b7f84b3a-9483-476c-acb9-5c48514253bf","keyword":"负载型<span style=\"color:red\">催化</span>剂","originalKeyword":"负载型催化剂"},{"id":"a1002edb-7313-4882-adeb-e0fde861cfbf","keyword":"甲醇","originalKeyword":"甲醇"},{"id":"aebb7816-2f6c-4fb2-aab6-95eb303f8fd3","keyword":"羰基化","originalKeyword":"羰基化"},{"id":"8d829fd2-75b6-4ee1-a2e4-dc1d138cced9","keyword":"氢","originalKeyword":"氢"}],"language":"zh","publisherId":"cuihuaxb200307014","title":"氢对气相甲醇羰基化<span style=\"color:red\">催化</span><span style=\"color:red\">体系</span>的影响","volume":"24","year":"2003"},{"abstractinfo":"制备了两种多核苊二亚胺<span style=\"color:red\">镍</span>配合物NimL1Cl2m和NimL2Cl2m,并将其负载于MgCl2和SiO2上制备复合载体<span style=\"color:red\">催化</span>剂,与通用烷基铝组成新的<span style=\"color:red\">催化</span><span style=\"color:red\">体系</span><span style=\"color:red\">催化</span>乙烯聚合.研究结果表明,在AlEt2Cl为助<span style=\"color:red\">催化</span>剂的条件下,两种多核苊二亚胺<span style=\"color:red\">镍</span>配合物能高效<span style=\"color:red\">催化</span>乙烯进行聚合,制得不同支链的各种支化聚乙烯;聚合条件对乙烯聚合活性和产物性能有较大的影响.制得产物的支链使聚乙烯的熔融峰变宽,并且支化度越高,熔融峰越宽.","authors":[{"authorName":"王春丽","id":"273dc438-28b6-4905-882a-a7e17f9ff963","originalAuthorName":"王春丽"},{"authorName":"江洪流","id":"6fe2c365-92da-4618-974e-6ddb035833ca","originalAuthorName":"江洪流"},{"authorName":"胡杨剑","id":"7aea5a15-cead-4b5a-8740-877350f79ee9","originalAuthorName":"胡杨剑"},{"authorName":"王海华","id":"2eae7510-8c05-4fb6-bc0c-75944e3d4d3f","originalAuthorName":"王海华"}],"doi":"","fpage":"60","id":"58e80a20-dfa0-49c5-ab5e-29ed8f804228","issue":"4","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"60b08536-8c83-4bdf-aa1b-d832dd5062d4","keyword":"苊二亚胺<span style=\"color:red\">镍</span>配合物","originalKeyword":"苊二亚胺镍配合物"},{"id":"4b80de16-716c-479c-802e-2ae7207d40e6","keyword":"烷基铝","originalKeyword":"烷基铝"},{"id":"7456ee6a-e4f6-408c-9a82-ac03055af8ac","keyword":"乙烯聚合","originalKeyword":"乙烯聚合"},{"id":"2c6b38b6-6f89-4b7a-bce2-d5a42d35bf20","keyword":"负载<span style=\"color:red\">催化</span>剂","originalKeyword":"负载催化剂"},{"id":"f7e748b1-6147-4cd5-adcc-a7f9b2fa9109","keyword":"支化聚乙烯","originalKeyword":"支化聚乙烯"}],"language":"zh","publisherId":"gfzclkxygc200604015","title":"新型多核苊二亚胺<span style=\"color:red\">镍</span>配合物复合负载<span style=\"color:red\">催化</span>剂<span style=\"color:red\">催化</span>乙烯聚合","volume":"22","year":"2006"},{"abstractinfo":"通过交流伏安法,发现碱性<span style=\"color:red\">体系</span>中<span style=\"color:red\">镍</span>电极在很负的电位下有非常规的法拉第电流响应.根据金属水合氧化物<span style=\"color:red\">催化</span>理论,电流响应是由<span style=\"color:red\">镍</span>表面缺陷处原子氧化成<span style=\"color:red\">镍</span>的水合氧化物引起的,由于其起始电位与次亚磷酸根氧化的起始电位相同,所以认为<span style=\"color:red\">镍</span>的水合氧化物是<span style=\"color:red\">催化</span>次亚磷酸根氧化的真正物种.","authors":[{"authorName":"田栋","id":"2137cea7-c057-4da5-b0ea-949d34e87e7b","originalAuthorName":"田栋"},{"authorName":"谢金平","id":"cfce4284-0ba9-4421-b122-7b7a2cb93cd0","originalAuthorName":"谢金平"},{"authorName":"李树泉","id":"16bbf83d-8750-4dc6-888e-9d109df5880a","originalAuthorName":"李树泉"},{"authorName":"范小玲","id":"f7d70569-7460-4c29-9aee-058bdd03a207","originalAuthorName":"范小玲"},{"authorName":"黎德育","id":"75744338-2539-407d-a02c-b0c3feea3b76","originalAuthorName":"黎德育"},{"authorName":"李宁","id":"cbf3815f-267f-44fd-8fcf-b3c89eb38033","originalAuthorName":"李宁"}],"doi":"10.3969/j.issn.1001-3660.2012.03.019","fpage":"63","id":"bb64b334-a64d-4d66-b607-7c54a70280e0","issue":"3","journal":{"abbrevTitle":"BMJS","coverImgSrc":"journal/img/cover/BMJS.jpg","id":"3","issnPpub":"1001-3660","publisherId":"BMJS","title":"表面技术   "},"keywords":[{"id":"7d327137-e51e-4e81-a91b-8c80a50c2b45","keyword":"交流伏安法","originalKeyword":"交流伏安法"},{"id":"1941f571-d520-4ef2-a1d0-7d138e087037","keyword":"次亚磷酸根","originalKeyword":"次亚磷酸根"},{"id":"d394b774-7d19-4f34-8e94-fd16a7f4620b","keyword":"<span style=\"color:red\">镍</span>的水合氧化物","originalKeyword":"镍的水合氧化物"},{"id":"76de6911-7cb5-4ba5-8bea-008748929bfb","keyword":"<span style=\"color:red\">催化</span>氧化","originalKeyword":"催化氧化"}],"language":"zh","publisherId":"bmjs201203019","title":"交流伏安法研究<span style=\"color:red\">镍</span>基体对次亚磷酸根的<span style=\"color:red\">催化</span>氧化","volume":"41","year":"2012"}],"totalpage":3152,"totalrecord":31518}