{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"采用间歇及半连续乳液聚合方式,合成得到了甲基丙烯酸甲酯-丙烯酸丁酯-甲基丙烯酸二氨基乙酯三元共聚物胶乳,系统研究了乳化剂类型、复合配比及用量、聚合温度、聚合方式和官能团单体含量对共聚物乳液耐电解质稳定性的影响.试验结果表明,随着乳化剂体系中非离子成分增加,官能团单体含量增多和聚合温度降低,胶乳的耐电解质稳定性增大.半连续乳液聚合所得胶乳的电解质稳定性比间歇聚合得到的胶乳更好,而且随着乳化单体滴加速率的降低,胶乳的电解质稳定性进一步提高.乳化剂用量加大,对胶乳的电解质稳定性无明显的影响.","authors":[{"authorName":"余樟清","id":"e854c986-8350-4c91-88c8-7a3ab5165ac4","originalAuthorName":"余樟清"},{"authorName":"<span style=\"color:red\">李</span><span style=\"color:red\">伯</span><span style=\"color:red\">耿</span>","id":"de3e96ab-db0d-4c7d-8425-b156628f59c7","originalAuthorName":"李伯耿"},{"authorName":"<span style=\"color:red\">李</span>宝芳","id":"ba234087-0f2b-4ed3-8fdd-9e66e582edb1","originalAuthorName":"李宝芳"},{"authorName":"潘祖仁","id":"35f4daf7-61b5-4078-8526-ec0f8a259d63","originalAuthorName":"潘祖仁"}],"doi":"","fpage":"103","id":"042fef34-435b-4a33-9ac3-b94f747d2076","issue":"4","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"0327a310-af3b-460c-a883-f6b1fe9d7f2b","keyword":"乳液共聚合","originalKeyword":"乳液共聚合"},{"id":"74594106-94fb-4613-b351-d862a0d0fce9","keyword":"电解质稳定性","originalKeyword":"电解质稳定性"},{"id":"f57e9ae4-6646-4fe6-8c29-2f3398e8a0e6","keyword":"(甲基)丙烯酸酯","originalKeyword":"(甲基)丙烯酸酯"}],"language":"zh","publisherId":"gfzclkxygc199904031","title":"MMA-BA-DMAEMA三元共聚物胶乳的电解质稳定性","volume":"15","year":"1999"},{"abstractinfo":"采用差示扫描量热法研究了熔融共混聚己内酰胺/聚对(间)苯二甲酸己二胺(PA6/PA6IcoT)相容体系的结晶温度、结晶程度以及结晶动力学,并通过热台偏光显微镜、广角X射线衍射仪观察了PA6/PA6IcoT共混体系的结晶相形态和晶体结构.结果表明,共混物的结晶行为与其组成、结晶温度区域密切相关.在非等温结晶时,随着非晶态PA6IcoT 含量的增加,PA6相的相对结晶度增加,部分晶体结构由γ晶型转变为较完善的α晶型.在较高温度区域结晶时,少量的PA6IcoT就能使串并的晶核分开,形成大量微小晶粒.当PA6IcoT含量继续增加时,球晶数目会减少但尺寸增大.等温结晶动力学研究发现,结晶速度随PA6IcoT含量的提高而下降,Avrami指数值在4.5～6之间,并随着结晶温度升高而增大.","authors":[{"authorName":"周光大","id":"6b99effd-6534-4f90-a451-10770b25e8e5","originalAuthorName":"周光大"},{"authorName":"姚臻","id":"a8c44b75-261c-4aa4-a617-791c989422ad","originalAuthorName":"姚臻"},{"authorName":"曹堃","id":"3d6be29d-333a-4c3c-a965-cfa7207e36b2","originalAuthorName":"曹堃"},{"authorName":"<span style=\"color:red\">李</span><span style=\"color:red\">伯</span><span style=\"color:red\">耿</span>","id":"923a189f-e487-4c3c-b0e1-4e16c08f7907","originalAuthorName":"李伯耿"}],"doi":"","fpage":"101","id":"0ab07011-629f-4acf-9277-a0af22b89f19","issue":"9","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"d85b83da-1bb8-49ed-8976-29296601fc7a","keyword":"聚己内酰胺","originalKeyword":"聚己内酰胺"},{"id":"72fbe244-1982-415e-bc1e-0cc51fac926f","keyword":"聚对(间)苯二甲酸己二胺","originalKeyword":"聚对(间)苯二甲酸己二胺"},{"id":"7c9f1c7d-33fe-4d46-a4f4-5e215ea06ee9","keyword":"相容共混","originalKeyword":"相容共混"},{"id":"124edf22-6113-45ef-8971-1a6bea1ff08b","keyword":"结晶","originalKeyword":"结晶"}],"language":"zh","publisherId":"gfzclkxygc200909028","title":"PA6/PA6IcoT相容共混物的结晶行为","volume":"25","year":"2009"},{"abstractinfo":"综述了均相茂金属催化剂负载化的研究现状,详细评述了载体,包括无机载体,尤其是聚合物载体及其负载化技术,并对今后负载化研究的方向作了展望.","authors":[{"authorName":"范荣","id":"03866d91-b4eb-4674-89c4-178b9eb66407","originalAuthorName":"范荣"},{"authorName":"刘伟","id":"f9e5de53-0577-4aca-be0b-e608dfbb118e","originalAuthorName":"刘伟"},{"authorName":"<span style=\"color:red\">李</span><span style=\"color:red\">伯</span><span style=\"color:red\">耿</span>","id":"0df8b680-a43d-486e-a443-1d21057273f9","originalAuthorName":"李伯耿"},{"authorName":"<span style=\"color:red\">李</span>宝芳","id":"93349ffb-37ac-4546-8258-c9d0dc37150d","originalAuthorName":"李宝芳"}],"doi":"","fpage":"1","id":"2619b32e-f502-4da1-9910-aca4a71b63d7","issue":"6","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"28db54ba-4737-403c-b86b-914ddef02196","keyword":"茂金属催化剂","originalKeyword":"茂金属催化剂"},{"id":"08055fd7-7f03-495e-868f-e6e013c8956b","keyword":"甲基铝氧烷","originalKeyword":"甲基铝氧烷"},{"id":"a97901d8-2ebf-4286-9e7f-a906a5fa8845","keyword":"负载化","originalKeyword":"负载化"},{"id":"35e68502-8280-477b-9221-131df19fdf82","keyword":"α-烯烃聚合","originalKeyword":"α-烯烃聚合"}],"language":"zh","publisherId":"gfzclkxygc199906001","title":"烯烃聚合负载型茂金属催化剂的研究进展","volume":"15","year":"1999"},{"abstractinfo":"用DSC方法研究了具有反应活性的有机蒙脱土与聚对苯二甲酸乙二酯(PET)原位聚合和熔融共混后的两种插层复合材料的等温结晶行为.结果表明,有机蒙脱土起异相成核作用,使PET的结晶过程更加复杂,对聚合样由于有机处理剂参与PET链的反应,特殊的结构有利于成核过程,但对总的结晶速率有一定影响,结晶速率的提高程度依赖于有机蒙脱土的添加量;有机蒙脱土使共混样品的结晶速率大大加快.","authors":[{"authorName":"徐锦龙","id":"03e627d7-fd28-426f-aa40-318f11bacc4a","originalAuthorName":"徐锦龙"},{"authorName":"<span style=\"color:red\">李</span><span style=\"color:red\">伯</span><span style=\"color:red\">耿</span>","id":"ea77dbac-9a37-4177-96b9-1b6d7341c648","originalAuthorName":"李伯耿"},{"authorName":"<span style=\"color:red\">李</span>乃祥","id":"dca1c348-8e58-42b8-8f83-c767a8a642ce","originalAuthorName":"李乃祥"},{"authorName":"巢平","id":"55cb8734-e2ce-4f3f-8100-27e37edfca13","originalAuthorName":"巢平"}],"doi":"","fpage":"149","id":"3ab668ef-b30b-4dea-9fec-bb710492b15f","issue":"6","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"b35c37fa-2827-4b1c-b4d1-33ce3bbb1790","keyword":"聚对苯二甲酸乙二酯","originalKeyword":"聚对苯二甲酸乙二酯"},{"id":"8fd0d04e-1b08-4857-8c1c-8ff97e51afb2","keyword":"蒙脱土","originalKeyword":"蒙脱土"},{"id":"9f3516ec-99a4-4c3f-9745-a566a64aa693","keyword":"纳米复合","originalKeyword":"纳米复合"},{"id":"1ea55c23-181a-4564-b63a-e82db675af1c","keyword":"结晶动力学","originalKeyword":"结晶动力学"}],"language":"zh","publisherId":"gfzclkxygc200206038","title":"PET/有机蒙脱土纳米复合材料等温结晶动力学过程研究","volume":"18","year":"2002"},{"abstractinfo":"以丙氧基化多元醇为原料,通过端基转化法合成了脂肪族甘油三缩水甘油醚(PGTE),用FT-IR,GPC对其结构进行了表征,化学分析测得其环氧值为0.43.研究了在室温快速固化的E-51/聚硫醇体系中,PGTE的加入对体系固化速度、粘接性能及固化物热稳定性的影响.结果表明,PGTE对该体系具有良好的降粘和提高粘接强度的作用.当PGTE加入量为30(pbw)时,室温快速固化特性和固化物的耐热性基本不变,铁片粘接的剪切强度与不均匀扯离强度则分别提高了116%和126%.","authors":[{"authorName":"王春飞","id":"6f1456c3-941d-4c70-a1d9-a0af434e0529","originalAuthorName":"王春飞"},{"authorName":"范宏","id":"c2ed7574-2a74-4ca8-939e-63436e6d51fa","originalAuthorName":"范宏"},{"authorName":"卜志扬","id":"160ff330-e203-4a00-90e6-cfeff123c716","originalAuthorName":"卜志扬"},{"authorName":"<span style=\"color:red\">李</span><span style=\"color:red\">伯</span><span style=\"color:red\">耿</span>","id":"e5e41725-4bc8-40f2-903e-e1392a9bb97d","originalAuthorName":"李伯耿"}],"doi":"","fpage":"209","id":"6245d290-caa6-4537-98cd-d36e91304f13","issue":"5","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"f7c78df9-0dcb-410f-b7d3-f026bbf29aa8","keyword":"脂肪族甘油三缩水甘油醚","originalKeyword":"脂肪族甘油三缩水甘油醚"},{"id":"faad7357-a1d2-4bea-862b-b1cd26cfa19a","keyword":"环氧树脂","originalKeyword":"环氧树脂"},{"id":"6d34c5d8-4e2a-4135-ac41-4ccc6624aeb4","keyword":"聚硫醇","originalKeyword":"聚硫醇"},{"id":"ad716e55-eccc-4ec5-9873-8697fa73e9e4","keyword":"增韧","originalKeyword":"增韧"}],"language":"zh","publisherId":"gfzclkxygc200605053","title":"脂肪族三缩水甘油醚改性室温快速固化体系的研究","volume":"22","year":"2006"},{"abstractinfo":"采用邻苯二甲酸二辛酯(DOP)做增塑剂,加入到聚氨酯丙烯酸酯紫外光(UV)固化胶粘剂中,发现DOP对胶粘剂具有良好的稀释增塑作用.通过透射电镜(TEM)照片发现,部分增塑剂DOP以微小的团聚体分散在固化后的体系当中.DOP的加入能降低胶粘剂的初始施工黏度,同时胶粘剂的拉伸剪切强度降低,而不均匀扯离强度增大.DOP的加入使胶粘剂固化后的交联密度降低,而玻璃化温度(Tg)先明显降低后又有所升高.胶粘剂固化后放置一段时间,其强度还会上升.","authors":[{"authorName":"周俊成","id":"f5572b49-b7aa-4fcb-8f51-7143fd4eeba0","originalAuthorName":"周俊成"},{"authorName":"范宏","id":"1e2a4ee7-b04c-43e2-b04b-6a7690004042","originalAuthorName":"范宏"},{"authorName":"卜志扬","id":"599fd28e-c1ed-45fb-9ca4-a7d5865720fa","originalAuthorName":"卜志扬"},{"authorName":"<span style=\"color:red\">李</span><span style=\"color:red\">伯</span><span style=\"color:red\">耿</span>","id":"00041edc-93dd-4dc3-b926-231c8be90348","originalAuthorName":"李伯耿"}],"doi":"","fpage":"109","id":"7201c6dc-624d-423b-b755-1ddb6877e8f6","issue":"1","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"8ce1ff1d-7594-4998-9187-797b987672c6","keyword":"增塑剂","originalKeyword":"增塑剂"},{"id":"5febca47-57fa-441a-ac47-2dd3d5539a0d","keyword":"紫外光固化","originalKeyword":"紫外光固化"},{"id":"ebaa70bf-9881-4686-a5e3-4be4d2acf777","keyword":"玻璃化温度","originalKeyword":"玻璃化温度"},{"id":"b665c18f-6bf5-467e-bdb6-8920659edb55","keyword":"黏度","originalKeyword":"黏度"}],"language":"zh","publisherId":"gfzclkxygc200601026","title":"增塑剂DOP对紫外光固化胶粘剂性能的影响","volume":"22","year":"2006"},{"abstractinfo":"相变材料是一类通过相变吸收或释放大量热量、实现热能存储和利用的材料,作为传热介质,相变材料的使用有助于热能使用效率的提高和低密度能源的开发利用.由相变材料在表面活性剂的作用下分散于传热流体中形成性能稳定的微/纳米相变乳液,是一种集储热与强化传热功能于一体的潜热型功能热流体.本文评述了相变乳液的制备及性能的研究进展,着重分析了相变乳液的稳定性、热性能及流变特性等主要性能,介绍了相变乳液的应用现状,并对相变乳液发展进行了展望.","authors":[{"authorName":"石李明","id":"c4ccb495-2205-4228-bfb7-69473db53945","originalAuthorName":"石李明"},{"authorName":"王文俊","id":"45d51a17-8e50-48ff-aed2-9eeaa20242a8","originalAuthorName":"王文俊"},{"authorName":"<span style=\"color:red\">李</span><span style=\"color:red\">伯</span><span style=\"color:red\">耿</span>","id":"e4970c3f-463b-434e-9fdf-6957e2842c23","originalAuthorName":"李伯耿"},{"authorName":"朱世平","id":"fd5e306b-b7dd-4b04-bd98-4ecdac2f6906","originalAuthorName":"朱世平"}],"doi":"","fpage":"142","id":"78eb03e3-735b-4ddf-af14-6b7a1fb52e42","issue":"1","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"e76b1def-2745-427d-afb7-903c5c2335b8","keyword":"相变材料","originalKeyword":"相变材料"},{"id":"00d73e1a-95a4-472e-9296-690c4091f678","keyword":"相变乳液","originalKeyword":"相变乳液"},{"id":"0a09d88d-7894-4118-bbfb-bcb0f78c0b4c","keyword":"功能性流体","originalKeyword":"功能性流体"},{"id":"545b060b-5ed8-4785-a208-afad20ac9f28","keyword":"潜热","originalKeyword":"潜热"}],"language":"zh","publisherId":"clkxygc201301029","title":"相变乳液的制备、性能与应用","volume":"31","year":"2013"},{"abstractinfo":"采用RSMA为增容剂制备了PA6/PP共混物,研究了RSMA增容PA6/PP共混物的形态结构和热行为以及晶态结构,并探讨RSMA增容PA6/PP共混物的增容机理.结果表明,PA6/PP共混物为热力学不相容的海岛型两相结构,RSMA的加入改善了PA6与PP相间的相容性,使两相分散均匀,分散度提高.RSMA对PA6/PP共混物的增容机理可用界面-分散相复合模型描述.","authors":[{"authorName":"解孝林","id":"1ae4f4f5-d57c-414a-8d72-846665379f59","originalAuthorName":"解孝林"},{"authorName":"<span style=\"color:red\">李</span><span style=\"color:red\">伯</span><span style=\"color:red\">耿</span>","id":"d23c553f-5f80-47cc-b4a0-7c3fac68c334","originalAuthorName":"李伯耿"},{"authorName":"陈媛","id":"c7afdf6a-92f3-4a9d-b63d-473b1f10956a","originalAuthorName":"陈媛"},{"authorName":"潘祖仁","id":"26fa641a-9d7e-46a3-832e-8d383a2fecb6","originalAuthorName":"潘祖仁"}],"doi":"","fpage":"107","id":"7bd80593-6132-43f0-818b-693f4caa248a","issue":"5","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"46a31f2a-c1e1-42da-b392-d14c2db33695","keyword":"苯乙烯-马来酸酐无规共聚物","originalKeyword":"苯乙烯-马来酸酐无规共聚物"},{"id":"996efdf2-4b32-402c-940e-ba294b4756b9","keyword":"尼龙6/聚丙烯共混物","originalKeyword":"尼龙6/聚丙烯共混物"},{"id":"f2ff3cf7-8089-4d7b-b96a-90974070b594","keyword":"形态结构","originalKeyword":"形态结构"},{"id":"9992f7e6-57f4-4eb9-af65-c04021aa21e6","keyword":"增容机理","originalKeyword":"增容机理"}],"language":"zh","publisherId":"gfzclkxygc199905030","title":"RSMA增容PA6/PP共混物的形态结构与增容机理","volume":"15","year":"1999"},{"abstractinfo":"采用剑麻纤维(SF)作增强填料,辅以其它助荆,与酚醛树脂(PF)混合、辊炼、粉碎制备酚醛模塑料.研究了SF表面处理方法、含量变化对酚醛模塑料性能的影响,对比了SF、玻璃纤维(GF)和普通木粉填料的增强效果.结果表明,SF对于模塑料的增强作用优于普通木粉填料,耐冲击性能则优于GF.SF含量对酚醛模塑料的力学性能、热性能和吸水性能影响较大.SEM观察结果表明,经碱热和偶联剂表面处理的SF与基体树脂的界面粘接作用得到了明显改善,酚醛模塑料具有较好的综合性能.","authors":[{"authorName":"孙同甲","id":"e2214f12-e653-480d-aff3-7a3a4d08dd91","originalAuthorName":"孙同甲"},{"authorName":"范宏","id":"bddb8a85-f1fd-496f-95a6-03a65a6b876f","originalAuthorName":"范宏"},{"authorName":"谭军","id":"898a0b5a-f0d8-4981-8c40-8ce86c72ce08","originalAuthorName":"谭军"},{"authorName":"<span style=\"color:red\">李</span><span style=\"color:red\">伯</span><span style=\"color:red\">耿</span>","id":"42d7f6d6-218a-459e-8025-c1ba0ea48a5d","originalAuthorName":"李伯耿"}],"doi":"","fpage":"45","id":"7eef940d-4100-424d-b629-29f22c3ab5dc","issue":"7","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"632ba2da-56dc-421c-b4a7-e822699af3e3","keyword":"剑麻纤维","originalKeyword":"剑麻纤维"},{"id":"4b1c27e8-9754-4ff6-9fcd-29847706a596","keyword":"酚醛树脂","originalKeyword":"酚醛树脂"},{"id":"8c774d5b-fd60-4880-9123-8ad5ac899789","keyword":"酚醛模塑料","originalKeyword":"酚醛模塑料"},{"id":"269b3359-3fd3-4f3a-a25e-e86f1fe00579","keyword":"增强","originalKeyword":"增强"}],"language":"zh","publisherId":"gfzclkxygc200907013","title":"剑麻纤维增强酚醛模塑料的性能","volume":"25","year":"2009"},{"abstractinfo":"合成了一系列乳液型紫外光(UV)固化聚氨酯丙烯酸酯,针对其涂膜性能进行研究,考察了辐射时间、膜厚、光引发剂用量、分子结构等因素对涂膜性能的影响;通过对各种影响因素的研究,得到了具有优良的涂膜性能和装饰性的乳液型UV固化聚氨酯丙烯酸酯,附着力在0～1级,正反耐冲击性都在50 cm以上,铅笔硬度可以达到3H以上.","authors":[{"authorName":"魏燕彦","id":"bb09cd17-05e6-406d-91bb-5c45a5c7e351","originalAuthorName":"魏燕彦"},{"authorName":"罗英武","id":"9be43529-bb6c-4b95-91eb-07f203685826","originalAuthorName":"罗英武"},{"authorName":"<span style=\"color:red\">李</span>宝芳","id":"15389cc7-90a1-4b4f-88ba-fb20f69f2a70","originalAuthorName":"李宝芳"},{"authorName":"<span style=\"color:red\">李</span><span style=\"color:red\">伯</span><span style=\"color:red\">耿</span>","id":"ffdfbfea-cf64-4fd2-b72d-60420f979dfd","originalAuthorName":"李伯耿"}],"doi":"10.3969/j.issn.0253-4312.2007.05.010","fpage":"30","id":"81676d0b-5846-450f-ac55-65dc98a67d76","issue":"5","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业   "},"keywords":[{"id":"7ae2df54-ea0c-4c44-b7e0-c6b4b3a4f8b4","keyword":"低VOC","originalKeyword":"低VOC"},{"id":"3a6770b8-9f72-4712-8286-36a152ed0151","keyword":"水性涂料","originalKeyword":"水性涂料"},{"id":"893b1913-d6f3-462b-8fe4-4c29348bb154","keyword":"紫外光固化","originalKeyword":"紫外光固化"},{"id":"aca31a8c-fe82-43e1-ba61-9ad5bb391068","keyword":"聚氨酯丙烯酸酯","originalKeyword":"聚氨酯丙烯酸酯"},{"id":"100a61cf-06ad-4d5b-9b4f-7a5f2956f4a2","keyword":"涂膜性能","originalKeyword":"涂膜性能"}],"language":"zh","publisherId":"tlgy200705010","title":"乳液型紫外光固化聚氨酯丙烯酸酯的涂膜性能及其影响因素","volume":"37","year":"2007"}],"totalpage":32,"totalrecord":314}