{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"介绍了几种有代表性的鎓盐类阳离子光引发剂--芳基重氮盐、芳基翰盐和二烷基苯甲酰硫盐的研究进展情况,探讨了各引发剂的光解机理和优缺点,并提出了增强鎓盐光敏性的方法和相关机理,介绍了有代表性的3类光敏剂以及近年来研制的一些新型光敏剂,概述了大分子鎓盐引发剂的研究情况,最后简要说明了鎓盐阳离子引发刺的发展趋势及应用.","authors":[{"authorName":"周健","id":"27c81a71-e5cf-4af7-b7c7-d3236bf8e79d","originalAuthorName":"周健"},{"authorName":"张秋禹","id":"90bd7b6f-727f-43ee-b127-a5cc85ca5793","originalAuthorName":"张秋禹"},{"authorName":"张和鹏","id":"94be02d7-c7ef-40d6-91f4-7c1f98eb6441","originalAuthorName":"张和鹏"},{"authorName":"刘清","id":"b995f141-237b-4229-9c23-8c132ca8bbbf","originalAuthorName":"刘清"},{"authorName":"王为强","id":"7f234c3d-fde1-49d8-8fee-6c665f9080ac","originalAuthorName":"王为强"},{"authorName":"周艳阳","id":"483175bf-be1d-4dd6-b929-363ab9f94979","originalAuthorName":"周艳阳"}],"doi":"","fpage":"16","id":"00707657-f8c4-4861-9593-b04785344aa8","issue":"1","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"2da1b1a7-67d5-473c-be31-89fe485263f0","keyword":"鎓盐","originalKeyword":"鎓盐"},{"id":"bb1daeef-5054-4dbc-8f83-a67f53e5b13e","keyword":"阳离子引发剂","originalKeyword":"阳离子引发剂"},{"id":"11b651e7-9feb-41ff-b01c-4f49bc616a9d","keyword":"机理","originalKeyword":"机理"},{"id":"b8212ccd-f8b1-4823-8cc2-3ffb2be66ca6","keyword":"光敏剂","originalKeyword":"光敏剂"},{"id":"9297aa7a-aeaf-48df-934c-ea3d6072360a","keyword":"大分子鎓盐","originalKeyword":"大分子鎓盐"}],"language":"zh","publisherId":"cldb201101003","title":"鎓盐类阳离子光引发剂的研究进展","volume":"25","year":"2011"},{"abstractinfo":"常用的阳离子光引发剂吸收波长在250-300 nm,与紫外光固化设备的辐射波长不匹配,光引发速率和效率低.本文介绍了阳离子光引发剂的种类、特点以及使引发剂体系吸收红移的研究,着重总结了阳离子光引发剂的敏化理论和技术.概述的敏化机理包括:能量转移、自由基氧化、激发态复合物和碎片加成.常用敏化方法有:添加光敏剂、扩大分子共轭使吸收红移和键合生色基团.文章还对新型阳离子光引发剂和光敏剂的设计和应用给予了展望.","authors":[{"authorName":"张洪","id":"01c25a72-2b58-4202-8a85-e3ab49c825bf","originalAuthorName":"张洪"},{"authorName":"李建雄","id":"fbb4805e-8c50-43b8-8269-1fe859e6a6ad","originalAuthorName":"李建雄"},{"authorName":"刘安华","id":"a25eed8c-4787-45fe-8105-f2d3d024865f","originalAuthorName":"刘安华"}],"doi":"10.7517/j.issb.1674-0475.2013.01.009","fpage":"69","id":"c148fca3-5116-46af-bb60-0adce61540f3","issue":"1","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学 "},"keywords":[{"id":"585ab7a9-6cc4-49bd-b898-714a5ad7c15f","keyword":"紫外光固化","originalKeyword":"紫外光固化"},{"id":"72d34edd-bcf9-4d01-a4c5-0fa756564bb3","keyword":"阳离子光引发剂","originalKeyword":"阳离子光引发剂"},{"id":"4b75be1c-1a97-4406-8034-368a401dcfc6","keyword":"光敏剂","originalKeyword":"光敏剂"},{"id":"60c2fa81-6b8c-46eb-ad2d-e6aa1ed0f017","keyword":"光敏化机理","originalKeyword":"光敏化机理"}],"language":"zh","publisherId":"ggkxyghx201301009","title":"阳离子光引发剂敏化的研究进展","volume":"31","year":"2013"},{"abstractinfo":"以苯乙烯、甲基丙烯酸二甲胺乙酯、丙烯酸异辛酯为单体、改性PVA-0588为乳化剂,采用无皂乳液聚合的方式,合成了含功能性单体丙烯酸酯的阳离子共聚乳液。研究了不同的引发剂种类、不同的引发剂用量、不同的季铵化剂用量等因素对聚合物粒径的影响。研究发现,采用引发剂-还原剂体系,可获得平均粒径100 nm左右,粒径分布窄的阳离子苯丙乳液;作为纸张表面施胶剂,施胶效果得到明显提高,在同等条件下,比粒径宽分布的样品施胶效果提高7%左右。","authors":[{"authorName":"朱先梅","id":"e62e436e-9507-41e5-837a-08013797f9d3","originalAuthorName":"朱先梅"},{"authorName":"成刚虎","id":"3a7be11a-6562-43ca-88a7-536dc84b4e8a","originalAuthorName":"成刚虎"},{"authorName":"刘宏昭","id":"ee889c18-01a7-4a13-889f-d030a3eb17a8","originalAuthorName":"刘宏昭"}],"doi":"","fpage":"103","id":"ac443fc8-1e74-439b-a2e8-de0a93e61e21","issue":"9","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"3e7ce93d-fb49-4e96-8ec9-ef521c3a5007","keyword":"苯乙烯","originalKeyword":"苯乙烯"},{"id":"5c46b3ed-d138-4ae8-a861-2b12bf3e4423","keyword":"丙烯酸酯","originalKeyword":"丙烯酸酯"},{"id":"6a0fb230-ad67-4164-be42-e498c3c43b2f","keyword":"乳液","originalKeyword":"乳液"},{"id":"5b4f44e0-b6b7-424e-abc5-fff025f329c0","keyword":"引发剂","originalKeyword":"引发剂"},{"id":"d7719920-08d9-4707-8e02-439ad6aefff3","keyword":"季铵化剂","originalKeyword":"季铵化剂"},{"id":"3efd2a97-c7ee-4279-a99e-aea74bad2a51","keyword":"粒径","originalKeyword":"粒径"}],"language":"zh","publisherId":"gfzclkxygc201109028","title":"引发剂对阳离子苯丙乳液表面施胶剂粒径和性能的影响","volume":"27","year":"2011"},{"abstractinfo":"本文用羟基对甲苯磺酰氧基碘苯与聚苯乙烯进行亲电取代反应,得到大分子阳离子碘鎓盐光引发剂聚苯乙烯碘锗-六氟锑酸盐(PS-I·SbF6).用核磁共振仪、傅立叶红外光谱仪、凝胶渗透色谱仪、差示扫描量热仪、紫外分光光度仪对其进行了表征.与小分子碘鎓盐系光引发剂相比,PS-I·SbF6的紫外最大吸收波长λmax红移,在240-270 nm范围内有较强的吸收;固化成膜后其相对迁移率较小分子光引发剂有显著下降.初步研究了PS-I·SbF6在环氧体系中的光固化性能,结果表明该体系有较好的光固化和后固化特性.","authors":[{"authorName":"夏朝荣","id":"26ae127e-04b5-4975-91ce-95bd7592672f","originalAuthorName":"夏朝荣"},{"authorName":"刘仁","id":"ccbc5302-52b2-476b-9563-8b60f6d7b975","originalAuthorName":"刘仁"},{"authorName":"黄强","id":"9a891f3f-c09d-47b9-adcc-9eac263dba0e","originalAuthorName":"黄强"},{"authorName":"张胜文","id":"f6b1d3fb-d00c-4dcb-a76e-3bab3834fdb2","originalAuthorName":"张胜文"},{"authorName":"江金强","id":"f0a0e796-1b61-4aeb-b434-81b4a61c7a28","originalAuthorName":"江金强"},{"authorName":"刘晓亚","id":"6356e501-093e-4ea2-9bdd-b897aed2e29d","originalAuthorName":"刘晓亚"}],"doi":"","fpage":"438","id":"ad03f41a-8735-4d58-8702-72a44767f003","issue":"6","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学 "},"keywords":[{"id":"6369ea81-a6ab-4a0c-827e-6f55420afb6d","keyword":"碘鎓盐","originalKeyword":"碘鎓盐"},{"id":"3a47c813-77e5-4959-a220-3a8fdf622aa7","keyword":"阳离子大分子光引发剂","originalKeyword":"阳离子大分子光引发剂"},{"id":"0e636a5d-b910-492f-a0f9-01fae9d7a5e2","keyword":"紫外光固化","originalKeyword":"紫外光固化"},{"id":"06760d32-bcc3-4252-8871-1c418ccbe0c5","keyword":"感光性能","originalKeyword":"感光性能"}],"language":"zh","publisherId":"ggkxyghx200806002","title":"大分子阳离子光引发剂聚苯乙烯-碘(鎓)六氟锑酸盐的合成及其感光性能的研究","volume":"26","year":"2008"},{"abstractinfo":"通过在阳离子引发型紫外光固化涂料中添加不同类型以及不同比例的抗氧剂,监测其在热老化过程中的黄变现象,考察了抗氧剂对涂料热老化黄变的影响和其不同的抗黄变能力.利用紫外-可见光谱仪表征老化过程试样的透光率变化.结果表明:抗氧剂能较好地减小阳离子型紫外光固化涂料的热老化黄变,抗氧剂中的羟基的抗黄变能力存在差异,羟基及羟基数量决定了抗氧剂的抗黄变能力.","authors":[{"authorName":"蔡万泼","id":"e308390f-fb36-4a14-b4d4-8447b87574c7","originalAuthorName":"蔡万泼"},{"authorName":"王德海","id":"44738e11-cbb4-4531-ba4f-b3aa895c6ca9","originalAuthorName":"王德海"},{"authorName":"盛伟明","id":"00a571bb-d030-4dfc-94c7-38b88f2fe03d","originalAuthorName":"盛伟明"}],"doi":"10.3969/j.issn.0253-4312.2012.09.015","fpage":"61","id":"b201dfad-4f43-4d5b-a8ac-152a873b84c5","issue":"9","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业 "},"keywords":[{"id":"7cce4ee2-fc38-402f-afec-ef194ec37610","keyword":"阳离子光固化","originalKeyword":"阳离子光固化"},{"id":"98487e22-adae-4f6a-af5d-686c92bd5f49","keyword":"热老化","originalKeyword":"热老化"},{"id":"4467af17-b785-4504-a150-fd953a576c5b","keyword":"抗氧剂","originalKeyword":"抗氧剂"},{"id":"eed4462e-b4f2-4aeb-b058-8c0e6dd35099","keyword":"黄变因数","originalKeyword":"黄变因数"},{"id":"60455247-3f05-4443-b915-31d346f530f4","keyword":"羟基","originalKeyword":"羟基"}],"language":"zh","publisherId":"tlgy201209015","title":"阳离子引发型紫外光固化涂料热老化黄变的研究","volume":"42","year":"2012"},{"abstractinfo":"利用电子束引发预辐射接枝技术,在高密度聚乙烯(HDPE)上接枝丙烯酸(AA)和对苯乙烯磺酸钠(SSS),制备一种含羧酸基团和磺酸基团的双功能基阳离子交换膜,详细研究了反应温度、单体总浓度、pH值变化及溶剂类型对接枝率的影响规律,明确了实验条件与接枝率的对应关系.接枝膜的吸水性随接枝率的增加而增强.X射线衍射测试表明,接枝膜结晶度随接枝率的升高而降低.","authors":[{"authorName":"俎建华","id":"18a657e0-a625-422c-9a5b-6732d2688c3e","originalAuthorName":"俎建华"},{"authorName":"吴明红","id":"24cefb52-2a6f-4d7c-a6bd-d7b6b3e01705","originalAuthorName":"吴明红"},{"authorName":"张剑秋","id":"cff16d55-749f-43ac-aa19-8603bf178c4e","originalAuthorName":"张剑秋"},{"authorName":"刘兆民","id":"20df76fa-66f0-40c3-9091-51d4f7f2f497","originalAuthorName":"刘兆民"},{"authorName":"王燕","id":"e8ec3c5e-06b3-4bb1-9bff-3ac6a942df3e","originalAuthorName":"王燕"}],"doi":"","fpage":"218","id":"35bdc046-584d-41ac-a0a4-c0cb3855e6bd","issue":"1","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"07690a45-9f8d-4981-9a2c-a4356cc2eb0e","keyword":"高密度聚乙烯","originalKeyword":"高密度聚乙烯"},{"id":"d132fbbd-b7d8-4407-92ab-3ccab9bb0cb4","keyword":"丙烯酸","originalKeyword":"丙烯酸"},{"id":"4bb48cf2-2681-4c39-9fc6-c06444516a8b","keyword":"对苯乙烯磺酸钠","originalKeyword":"对苯乙烯磺酸钠"},{"id":"26c1b6dc-2b16-41c4-95ac-61326db06702","keyword":"预辐射接枝","originalKeyword":"预辐射接枝"},{"id":"f043629d-073f-44aa-9b90-309e7745c57d","keyword":"X射线衍射","originalKeyword":"X射线衍射"}],"language":"zh","publisherId":"gfzclkxygc200601055","title":"电子束引发双功能基阳离子交换膜的制备","volume":"22","year":"2006"},{"abstractinfo":"比较了阴、阳离子型引发剂以及各种不同阳离子型乳化剂和功能单体甲基丙烯酸二甲氨基乙酯用量对乳液合成转化率的影响.用激光粒度仪和电镜分析表征了乳液的粒径,研究了乳化剂用量对乳液粒径的影响.","authors":[{"authorName":"李敏","id":"0852eef5-854a-4c9c-bf7f-a075934f1f03","originalAuthorName":"李敏"},{"authorName":"马吉康","id":"610b26ca-a62c-4db7-b93a-0f2041de688b","originalAuthorName":"马吉康"},{"authorName":"刘兴","id":"c8fdbc5e-a47a-4a85-93a8-42d4283ebe60","originalAuthorName":"刘兴"},{"authorName":"马胜军","id":"fbc207d7-c053-4cd8-9abd-c59577fce856","originalAuthorName":"马胜军"},{"authorName":"潘煜怡","id":"13b327dd-232d-4e75-a5c9-53568628295c","originalAuthorName":"潘煜怡"}],"doi":"10.3969/j.issn.0253-4312.2008.01.009","fpage":"31","id":"2c3ad5e6-f15c-4887-92a9-aefca9d45abb","issue":"1","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业 "},"keywords":[{"id":"80b89061-698e-4307-ac58-00b43ffb57fd","keyword":"阳离子","originalKeyword":"阳离子"},{"id":"3948d3bc-f551-4a2f-afc9-b0dfd3572ff0","keyword":"微乳液","originalKeyword":"微乳液"},{"id":"44c9c5c4-66e3-4ae2-8330-7a97cd9ae21f","keyword":"粒径","originalKeyword":"粒径"}],"language":"zh","publisherId":"tlgy200801009","title":"阳离子微乳液的合成","volume":"38","year":"2008"},{"abstractinfo":"以天然有机高分子玉米芯准纳米粉(QCCP)为母体,用三乙胺与环氧氯丙烷共聚产物为阳离子单体,采用H2O2-FeSO4作引发剂,制得一种新型天然有机高分子阳离子改性絮凝剂DXSL-I,确定了优化的反应条件为:2.0 g QCCP与含有0.6 g NaOH的8 mL水混合,40 ℃碱化60 min,然后加入8 mL醚化单体三乙胺基环氧丙烷(TAEP,triethylamino-epoxypropane)和体系总质量0.01%的引发剂以及0.1%的氯化钠作为抑制剂,55 ℃醚化3.5 h. 结果表明,絮凝剂DXSL-I制备中,醚化单体与QCCP的转化率为83%,用该絮凝剂处理高岭土悬浊液时,5 min内中层溶液透光率就能达到95%. 其絮凝性能达到传统絮凝剂聚丙烯酰胺的技术指标.","authors":[{"authorName":"许映军","id":"bd78980f-c053-4ebd-8c42-35c418a01d1b","originalAuthorName":"许映军"},{"authorName":"丁永生","id":"2c4f7a93-415d-49d7-8f18-d3ef398671b1","originalAuthorName":"丁永生"},{"authorName":"公维民","id":"e2c2ac77-3c6c-4530-8c62-d6bf2a1b123a","originalAuthorName":"公维民"},{"authorName":"陈捷","id":"6cc9ce5d-5e97-4a8f-9584-3366cbf2e139","originalAuthorName":"陈捷"},{"authorName":"盛雪芹","id":"0a9efceb-2708-4147-b279-a8ea26742127","originalAuthorName":"盛雪芹"},{"authorName":"于志伟","id":"1a4ef363-536b-41e2-931f-cf33d5dcc218","originalAuthorName":"于志伟"},{"authorName":"许晓磊","id":"89e333b0-94f3-4caf-8457-46ea49ffb100","originalAuthorName":"许晓磊"}],"doi":"10.3969/j.issn.1000-0518.2004.05.015","fpage":"498","id":"fd622206-cd4e-4a76-b783-c6f4881291b8","issue":"5","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"fce26d78-40c8-4fb8-8590-a64ffe26b882","keyword":"玉米芯","originalKeyword":"玉米芯"},{"id":"4349b08f-1ae6-4a00-8c31-356b5aa92d4b","keyword":"天然有机高分子","originalKeyword":"天然有机高分子"},{"id":"a95647a2-eee8-47ba-a71d-29135eb0c674","keyword":"阳离子改性","originalKeyword":"阳离子改性"}],"language":"zh","publisherId":"yyhx200405015","title":"新型天然有机高分子阳离子改性絮凝剂的制备","volume":"21","year":"2004"},{"abstractinfo":"研究了阳离子引发体系Me3SiCl(TMSCl)/EtAlCl2在正己烷中引发的1,3-戊二烯(PD)聚合反应.研究结果表明,在EtAlCl2引发的PD聚合反应中引入TMSCl后大幅度提高了聚合物产率,同时使聚合反应速率明显提高,在[TMSCl]/[EtAlCl2]=0~1范围内,TMSCl/EtAlCl2体系制备的聚合物分子量高于EtAlCl2引发制备的聚合物,这些结果表明Me3SiCl/EtAlCl2体系对PD具有较高的引发活性.1H NMR和结构分析证明TMSCl水解生成的HCl和EtAlCl2络合物引发PD聚合.","authors":[{"authorName":"石伟民","id":"b0c7366a-07c8-426f-8ec6-0c2d29e23a9f","originalAuthorName":"石伟民"},{"authorName":"彭宇行","id":"deefaa4a-7a40-4775-aad2-9bd4004ccac0","originalAuthorName":"彭宇行"}],"doi":"","fpage":"39","id":"7260e7fc-88c3-4990-b7db-005ea8d6ac05","issue":"1","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"d00ed6bf-1e69-4469-bd37-4b66177a02f6","keyword":"1","originalKeyword":"1"},{"id":"b92bf243-358f-416b-bb92-151e3b9926bc","keyword":"3-戊二烯","originalKeyword":"3-戊二烯"},{"id":"400df817-9875-4b5b-b879-2b0d6a550d01","keyword":"阳离子聚合","originalKeyword":"阳离子聚合"},{"id":"e1fe09a0-021a-4dfa-8e20-21935091b14d","keyword":"引发体系","originalKeyword":"引发体系"},{"id":"c33353f0-6557-45f6-b1ba-b6aaa20294ac","keyword":"三甲基硅卤化物","originalKeyword":"三甲基硅卤化物"}],"language":"zh","publisherId":"gfzclkxygc200001012","title":"1,3-戊二烯阳离子聚合引发体系(CH3)3SiCl/EtAlCl2的研究","volume":"16","year":"2000"},{"abstractinfo":"综述了光固化涂料用引发剂的反应机理.介绍了自由基和阳离子光引发聚合体系用引发剂的类型及其典型品种的主要性质、特点和应用.指出了近年来国内外光引发剂的发展方向.","authors":[{"authorName":"郑耀臣","id":"e4fec5d3-e677-4430-a748-7f08a3b5fd94","originalAuthorName":"郑耀臣"},{"authorName":"魏无际","id":"10665412-105c-4639-9c9d-64ab956cc0e2","originalAuthorName":"魏无际"}],"doi":"10.3969/j.issn.0253-4312.2002.01.013","fpage":"31","id":"fd1211aa-9c9f-40c8-8237-4e5b427a0ea6","issue":"1","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业 "},"keywords":[{"id":"857debf0-d96f-41b2-9b76-0ba619968745","keyword":"光引发剂","originalKeyword":"光引发剂"},{"id":"47fa49f2-ca80-42df-ac8d-1020982fcdfe","keyword":"光固化涂料","originalKeyword":"光固化涂料"},{"id":"da6814a3-b55a-45d1-ae78-56a46becd6bf","keyword":"光聚合反应","originalKeyword":"光聚合反应"}],"language":"zh","publisherId":"tlgy200201013","title":"光固化涂料用光引发剂的进展","volume":"32","year":"2002"}],"totalpage":4737,"totalrecord":47369}