{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"负载型 Au基催化剂在工业过程中具有非常广泛的潜在应用,如催化加氢/脱氢过程、精细化学品合成、能源催化转化及环境保护等过程,表现出很高的催化活性和选择性. Au基催化剂活性物种或活性中心基本由纳米粒子或化合物构成,但在应用过程中因 Ostwald熟化效应或粒子迁移作用,尤其是高温高压等苛刻反应条件下,均随应用时间延长从小尺寸粒子逐渐长为大粒子,造成活性降低或完全失活,这也是负载型催化剂失活的最主要原因之一.其中因成本、稀缺等特性,负载型 Au催化剂的烧结问题是影响和制约其应用的主要因素.除可通过载体改性、助剂和官能团配位稳定等方法来延缓其失活过程外,对已烧结催化剂的高效、快捷和绿色的再分散/再生过程也具有基础和应用研究的重要意义.活性炭载 Au催化剂(Au/AC)广泛应用于乙炔氢氯化反应中,以期替代高毒性的汞基催化剂,但在反应过程中因高活性的 Au3+物种易被还原而形成 Au0物种进而烧结导致失活；如新鲜 Au/AC催化剂表面的 Au粒子尺寸为1-2 nm,经乙炔氢氯化反应后变为33 nm左右；随之在453 K、0.1 MPa、乙炔体积空速(GHSV)为600 h-1、氯化氢与乙炔摩尔比为1.1的反应条件下,乙炔转化率从81.8%降至11.2%.如何有效对大粒子 Au再分散/再生可为其应用提供有力支撑.有研究表明,气相 CH3I在甲醇羰基化反应过程中明显改变 Au/AC表面的 Au粒子尺寸；或采用浓盐酸或王水也可将烧结的 Au/AC催化剂进行再分散/再生.但已有的 Au基催化剂再分散/再生过程均伴随着强酸、强氧化或高毒性在分散剂的应用,对环境的影响及后续处理有明显的局限性,且再分散机理尚不明确.在前期工作基础上,本文采用系列卤代烃(碘代烃、溴代烃和氯代烃)对烧结的 Au/AC进行再分散/再生研究.结果表明,在室温常压条件下 CHI3可以快捷高效地对烧结 Au/AC催化剂进行再分散/再生,具有最优的再分散性能；通过对系列碘代烃 C-I键的解离能分析,发现 C-I解离能越低越有利于大粒子 Au的再分散.同时,溴代烃和氯代烃对烧结的 Au/AC催化剂也具有再分散能力,但比碘代烃的再分散效率低. C-X键的解离能与再分散效率有高相关性,即 C-X键的解离能越低越有利于 Au的再分散.总体上,三类卤代烃再分散效率高低顺序为 C-I＞C-Br＞C-Cl.进而,通过不同分散过程中 Au粒子分散状态推测了卤代烃对 Au粒子的再分散机理,即卤代烃先在 Au粒子表面化学吸附,然后 C-X键解离,形成 Au-X物种,小粒子 Au在 AC表面聚集并稳定,最后形成高分散 Au粒子(粒径<1 nm)催化剂.以乙炔氢氯化反应考察了再生 Au/AC催化剂性能,结果表明,该催化剂上乙炔转化率可达79.4%,基本恢复至初始水平,且该方法可对失活催化剂进行多次高效再生.","authors":[{"authorName":"段新平","id":"06b6d747-db60-4308-bf6d-542b60c6e4d8","originalAuthorName":"段新平"},{"authorName":"尹燕","id":"340bf0b7-6ba7-4bf9-98e7-4dbaaafa1238","originalAuthorName":"尹燕"},{"authorName":"田学林","id":"d4f4a827-562c-4d77-a3ee-f04da9d1cb8b","originalAuthorName":"田学林"},{"authorName":"<span style=\"color:red\">柯</span><span style=\"color:red\">金</span><span style=\"color:red\">火</span>","id":"ff98cd37-9985-4a2d-b33f-f972fe66e439","originalAuthorName":"柯金火"},{"authorName":"温兆军","id":"30bf413d-dc68-45ab-9071-55bd762eb462","originalAuthorName":"温兆军"},{"authorName":"郑建伟","id":"0e3e4524-1903-4080-8f48-810ac0df1465","originalAuthorName":"郑建伟"},{"authorName":"胡梦麟","id":"1ee1caf3-b376-4c6d-8dff-bc1b42ff2ab4","originalAuthorName":"胡梦麟"},{"authorName":"叶林敏","id":"7f9cc708-a960-42b5-bbb8-83fcec270132","originalAuthorName":"叶林敏"},{"authorName":"袁友珠","id":"425cc946-2a56-472c-aa6d-22d6cca8b09c","originalAuthorName":"袁友珠"}],"doi":"10.1016/S1872-2067(16)62500-7","fpage":"1794","id":"2b2717d5-7405-455e-8e0a-6e42fec4aaae","issue":"10","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"e09b1d4c-00b0-48ff-a605-7456b5abd96f","keyword":"<span style=\"color:red\">金</span>","originalKeyword":"金"},{"id":"16bdd5fd-6b44-42e0-b457-8b4c54ca6fa5","keyword":"纳米粒子","originalKeyword":"纳米粒子"},{"id":"68dedca9-3d15-4cb9-9d03-1deb1473f465","keyword":"再分散","originalKeyword":"再分散"},{"id":"eb722f15-aaee-4ecd-8941-8564a32daccb","keyword":"卤代烃","originalKeyword":"卤代烃"},{"id":"6489e4ba-7299-4fce-9aeb-5c2dfe8d18ef","keyword":"乙炔氢氯化","originalKeyword":"乙炔氢氯化"}],"language":"zh","publisherId":"cuihuaxb201610026","title":"C-X（X = Cl，Br，I）键解离能作为烧结Au/AC催化剂再分散的描述因子及相关蕴意","volume":"37","year":"2016"},{"abstractinfo":"称取一定量的载<span style=\"color:red\">金</span>炭进行<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>配料,经过熔炼、灰吹得到金银合粒,使用硝酸分金得到<span style=\"color:red\">金</span>粒,再通过计算得到载<span style=\"color:red\">金</span>炭中银含量,从而建立了<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>重量法测定载<span style=\"color:red\">金</span>炭中银含量的方法.经过试验,确定了<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>配料中试样量、氧化铅加入量、灰吹温度等最佳试验条件.根据目前国内载<span style=\"color:red\">金</span>炭的生产水平,在载<span style=\"color:red\">金</span>炭国家标准物质加入一定量的共存元素,进行了银量测定的干扰试验,结果表明载<span style=\"color:red\">金</span>炭中共存元素(Cu、Fe、Pb、Cd、Zn、Bi、Cr、Ca、Mg、As)对银测定无影响.将方法用于3个载<span style=\"color:red\">金</span>炭国家标准物质中银的测定,测定值与认定值基本吻合,相对标准偏差(RSD,n=11)为0.82%~4.2%.","authors":[{"authorName":"夏珍珠","id":"ae2def66-61f8-4a33-8789-5dec712b132d","originalAuthorName":"夏珍珠"}],"doi":"10.13228/j.boyuan.issn1000-7571.010052","fpage":"54","id":"4b8246f5-46d3-4c21-add1-aec3ad1a51f6","issue":"2","journal":{"abbrevTitle":"YJFX","coverImgSrc":"journal/img/cover/YJFX.jpg","id":"71","issnPpub":"1000-7571","publisherId":"YJFX","title":"冶金分析   "},"keywords":[{"id":"47d546ce-8dc2-4590-a95d-577be2bda394","keyword":"载<span style=\"color:red\">金</span>炭","originalKeyword":"载金炭"},{"id":"d39a523e-9fce-4000-9dc3-679e231f7a0a","keyword":"银","originalKeyword":"银"},{"id":"4fe9ac55-04a7-4da9-9b38-d814d71ea793","keyword":"<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>","originalKeyword":"火试金"}],"language":"zh","publisherId":"yjfx201702011","title":"<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>重量法测定载<span style=\"color:red\">金</span>炭中银","volume":"37","year":"2017"},{"abstractinfo":"采用样品与试剂混合, 直接在灰皿中进行熔融、灰吹,合粒用硝酸分解,<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>法测定树脂中的<span style=\"color:red\">金</span>.实验结果表明,该方法对测定树脂中的<span style=\"color:red\">金</span>具有较好的准确度,相对标准偏差为1.27 %.","authors":[{"authorName":"李小玲","id":"b12237c4-4d34-445c-b77f-18d61ac74404","originalAuthorName":"李小玲"}],"doi":"10.3969/j.issn.1001-1277.2010.04.015","fpage":"54","id":"e10aef27-91ba-40dc-b6e0-852bef8a2b4f","issue":"4","journal":{"abbrevTitle":"HJ","coverImgSrc":"journal/img/cover/HJ.jpg","id":"44","issnPpub":"1001-1277","publisherId":"HJ","title":"黄金"},"keywords":[{"id":"0a96019f-9436-44b9-9da4-e15ec8bce2d1","keyword":"<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>法","originalKeyword":"火试金法"},{"id":"3bf169fe-5d80-47b4-8de5-b27501454c8d","keyword":"树脂","originalKeyword":"树脂"},{"id":"e554c720-bf1e-47a1-ba42-5a3891e30487","keyword":"<span style=\"color:red\">金</span>","originalKeyword":"金"}],"language":"zh","publisherId":"huangj201004015","title":"<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>法测定树脂中的<span style=\"color:red\">金</span>","volume":"31","year":"2010"},{"abstractinfo":"根据史料分析,叙述了<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>法在中国古代的产生和发展.表明用火试<span style=\"color:red\">金</span>法冶炼和鉴定金、银,在中国古代早已有之.","authors":[{"authorName":"杨丙雨","id":"de4e3d7f-2e32-4b06-b431-d07e5484b7e4","originalAuthorName":"杨丙雨"},{"authorName":"冯玉怀","id":"a7e0c981-6d6e-45ad-9b5b-7f530cfaebf4","originalAuthorName":"冯玉怀"}],"doi":"10.3969/j.issn.1004-0676.2009.01.012","fpage":"59","id":"fcee5770-7794-4f12-8385-325a24f3c6b2","issue":"1","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"ee16f9c7-f391-4254-9f53-d6f4792797ca","keyword":"分析化学","originalKeyword":"分析化学"},{"id":"6a5f0f63-2c03-42fd-8a58-b9e6c3097bd5","keyword":"<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>法","originalKeyword":"火试金法"},{"id":"8fb73f49-37ee-418d-bd61-fefcd75d39dc","keyword":"<span style=\"color:red\">金</span>、银","originalKeyword":"金、银"},{"id":"a7de8333-7ea6-4032-8bd2-e354e1c2d9aa","keyword":"中国古代","originalKeyword":"中国古代"}],"language":"zh","publisherId":"gjs200901012","title":"中国古代的<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>法","volume":"30","year":"2009"},{"abstractinfo":"近代<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>分析技术明末传入中国至今已近400年,由于明末的社会动乱和清中叶的拒外闭关政策,使初入中国的该技术未流传就被扼杀.鸦片战争后,经过洋务运动,又使<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>分析技术在中国起死回生,逐渐孕育和萌芽.辛亥革命和新文化运动推动了近代<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>分析法在中国的诞生和传播.新中国的成立,为<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>分析的普及、提高、创新提供了发展的条件,使该法深深的扎根于中国本土并发扬光大,现已成为分析贵金属的一种完善方法.","authors":[{"authorName":"杨丙雨","id":"c1a066ac-4f3b-4f97-a86e-0f2f60b751ff","originalAuthorName":"杨丙雨"},{"authorName":"马亚丽","id":"b1410b4a-684d-4c44-9ddf-017075d2c772","originalAuthorName":"马亚丽"}],"doi":"10.3969/j.issn.1004-0676.2010.01.011","fpage":"43","id":"32b6983b-fa77-47b1-9aa5-f7d4dc805a81","issue":"1","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"ff651b86-0d55-4909-b8fd-334f04ff65d5","keyword":"分析化学","originalKeyword":"分析化学"},{"id":"b7576bca-4cf5-4af2-b342-8ce31eb34094","keyword":"贵金属","originalKeyword":"贵金属"},{"id":"c15f4477-a557-4376-bd3f-f81f2e133c71","keyword":"<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>分析法","originalKeyword":"火试金分析法"},{"id":"b0692ce0-3569-4f64-ab1b-9b9ccb8b8736","keyword":"流传和发展","originalKeyword":"流传和发展"},{"id":"1b538b54-c3fc-472b-8ecd-b3958071244f","keyword":"中国","originalKeyword":"中国"}],"language":"zh","publisherId":"gjs201001011","title":"近代<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>分析在中国的传播","volume":"31","year":"2010"},{"abstractinfo":"采用加Au的方法解决<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>测Ag时灰吹合粒\"开花\"的问题,讨论了Au的加入量与Ag回收率的关系,此法测Ag快速和简便准确.","authors":[{"authorName":"管有祥","id":"4d86f294-dd88-450f-8db6-4f225df5fa6e","originalAuthorName":"管有祥"}],"doi":"10.3969/j.issn.1004-0676.1999.01.010","fpage":"42","id":"19d9b7c4-6131-476e-8f4c-1eceb3b36c33","issue":"1","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"a2f1d50d-e12e-428d-bf37-a7a693185f19","keyword":"<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>","originalKeyword":"火试金"},{"id":"e4f5151b-d8a8-4c7e-a659-9458fa2c8ad9","keyword":"\"开花\"","originalKeyword":"\"开花\""},{"id":"3bd95d8c-f3e0-4194-96a4-0785bc68d6f3","keyword":"加Au","originalKeyword":"加Au"}],"language":"zh","publisherId":"gjs199901010","title":"<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>灰吹合粒\"开花\"的讨论","volume":"","year":"1999"},{"abstractinfo":"研究了铅扣中铜对钯灰吹时的影响及铅扣中铜、氧化铅和硅酸度(K)三者间的关系.提出了对粗铜样品不经预先分离铜而直接进行<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>,连续测定样品中的金和钯量.方法准确,精密度高.","authors":[{"authorName":"林海山","id":"0b885736-1497-475f-9911-bc7cebb939ef","originalAuthorName":"林海山"}],"doi":"10.3969/j.issn.1000-7571.2002.01.020","fpage":"53","id":"2315ff49-3b90-40b7-a5b2-1a9030c429c8","issue":"1","journal":{"abbrevTitle":"YJFX","coverImgSrc":"journal/img/cover/YJFX.jpg","id":"71","issnPpub":"1000-7571","publisherId":"YJFX","title":"冶金分析   "},"keywords":[{"id":"58627cbd-6788-497b-aba2-7e3baf6aafac","keyword":"<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>","originalKeyword":"火试金"},{"id":"2935a686-14d6-421e-8658-d7872a47202e","keyword":"粗铜","originalKeyword":"粗铜"},{"id":"d0d0d571-57f9-46b7-a47d-00d06bf48c7b","keyword":"试<span style=\"color:red\">金</span>配料","originalKeyword":"试金配料"},{"id":"013a59d4-5140-41e5-82cf-d77e31008e95","keyword":"<span style=\"color:red\">金</span>","originalKeyword":"金"},{"id":"54344541-ab47-4cbc-b6c7-e92e20441e37","keyword":"钯","originalKeyword":"钯"}],"language":"zh","publisherId":"yjfx200201020","title":"<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>法测定粗铜中金和钯","volume":"22","year":"2002"},{"abstractinfo":"建立了样品焙烧处理—<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>重量法测定载<span style=\"color:red\">金</span>炭中的<span style=\"color:red\">金</span>量;经过了一系列条件实验,分别确定了称样量范围、焙烧温度、配料、熔样温度、分金时间、分金酸度及金银质量比例等最佳实验条件.在最佳实验条件下,该方法加入标准物质的回收率为99.85 ％～100.1％,与原子吸收光谱法对比,体现了更好的重复性和再现性.在载<span style=\"color:red\">金</span>炭交易中,该方法被推荐为仲裁分析方法.","authors":[{"authorName":"马丽军","id":"6768dfdb-3530-488a-9d93-1f0ab30c47fa","originalAuthorName":"马丽军"},{"authorName":"陈永红","id":"5ac59b89-d7d2-4dea-9c22-e5e9e2151d26","originalAuthorName":"陈永红"},{"authorName":"腾飞","id":"6d20e110-9155-40fb-9f55-e990679138be","originalAuthorName":"腾飞"},{"authorName":"芦新根","id":"1ce113b3-6ebb-4ed5-b1b0-d68573b7c776","originalAuthorName":"芦新根"}],"doi":"10.11792/hj20131118","fpage":"68","id":"031dab89-a481-4201-bcbf-680191560ad2","issue":"11","journal":{"abbrevTitle":"HJ","coverImgSrc":"journal/img/cover/HJ.jpg","id":"44","issnPpub":"1001-1277","publisherId":"HJ","title":"黄金"},"keywords":[{"id":"27a49c13-1b1f-40cb-8b6d-4d6a1cac9063","keyword":"载<span style=\"color:red\">金</span>炭","originalKeyword":"载金炭"},{"id":"fe57d337-dd21-4f75-b6f6-8d875f4cc7fc","keyword":"<span style=\"color:red\">金</span>","originalKeyword":"金"},{"id":"cd477d2b-4419-4c19-97b5-7ef553f579a0","keyword":"<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>","originalKeyword":"火试金"},{"id":"13f56eb7-08cc-46f3-96e9-e3789e6a9687","keyword":"重量法","originalKeyword":"重量法"}],"language":"zh","publisherId":"huangj201311018","title":"<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>重量法测定载<span style=\"color:red\">金</span>炭中的<span style=\"color:red\">金</span>量","volume":"34","year":"2013"},{"abstractinfo":"对锡含量高的Sn-Pb-Au-Sb合金中<span style=\"color:red\">金</span>含量的<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>测定,作者采用熔炼、灰吹手段,解决了Sn干扰测定结果的问题.具体的作法是,用碳酸钠和硼砂配制成混合熔剂,将该混合熔剂与合金试样混合,经高温熔炼,使Sn转变成锡酸钠造渣而不进入铅扣,试样经灰吹富集形成Au-Ag合金.用硝酸分Ag,重量法测Au.合成样回收率99.93%～100.09%,相对标准偏(RSD%)为0.369%.","authors":[{"authorName":"管有祥","id":"fe6bad56-f481-4d99-9b53-24558e8e2406","originalAuthorName":"管有祥"},{"authorName":"温结胜","id":"4aef01a5-19c1-43f0-b078-b9d9084e220d","originalAuthorName":"温结胜"},{"authorName":"甘建壮","id":"d1e0bdfa-088f-4af3-b6a7-f369765942e3","originalAuthorName":"甘建壮"},{"authorName":"段颖","id":"48729570-54f7-43f9-9540-9ea9c4fefa9c","originalAuthorName":"段颖"}],"doi":"10.3969/j.issn.1004-0676.2005.04.008","fpage":"31","id":"1618c192-81b9-418b-9dcc-972426c1a7b5","issue":"4","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"ce5ba970-71f5-40b2-87aa-0a8e097c7726","keyword":"分析化学","originalKeyword":"分析化学"},{"id":"1d9ad7ac-ec19-49b4-8f28-40c6337dc943","keyword":"<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>法","originalKeyword":"火试金法"},{"id":"e1f11ab5-75bb-4605-8147-30474f04cea4","keyword":"锡铅<span style=\"color:red\">金</span>锑合金","originalKeyword":"锡铅金锑合金"},{"id":"5188de92-47fe-49a8-af1b-fd9e997c99de","keyword":"<span style=\"color:red\">金</span>含量","originalKeyword":"金含量"}],"language":"zh","publisherId":"gjs200504008","title":"<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>测定锡铅<span style=\"color:red\">金</span>锑合金中<span style=\"color:red\">金</span>含量","volume":"26","year":"2005"},{"abstractinfo":"文中针对含有碳酸盐及金属氧化物硅酸盐的含<span style=\"color:red\">金</span>富矿块<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>分析测定方法在配料上进行了研究,提出了二硅酸度及造渣成分为53%硅酸盐、33%硼酸盐、14%铅酸盐的面粉法配料方案.该方法使熔渣具有熔点低、流动性好等物理性能,从而使<span style=\"color:red\">金</span>捕收率高达99.95%,且测定结果重现性好.","authors":[{"authorName":"曹永刚","id":"f6e49d6e-295d-4c97-a7f2-7ebfd49deea7","originalAuthorName":"曹永刚"}],"doi":"10.3969/j.issn.1001-1277.2005.10.015","fpage":"45","id":"85131bff-4c76-4ebb-a7e0-bdb88df0ea48","issue":"10","journal":{"abbrevTitle":"HJ","coverImgSrc":"journal/img/cover/HJ.jpg","id":"44","issnPpub":"1001-1277","publisherId":"HJ","title":"黄金"},"keywords":[{"id":"b60eb429-c22f-4829-a23b-7d178bbac384","keyword":"含<span style=\"color:red\">金</span>富矿块","originalKeyword":"含金富矿块"},{"id":"649d9b17-5e50-476e-8c13-12b96d7eb671","keyword":"面粉法","originalKeyword":"面粉法"},{"id":"c7959c1a-305d-4ebc-9dd4-5fb794ea0daf","keyword":"硝石法","originalKeyword":"硝石法"},{"id":"033d3998-5f0a-4fcc-a7ee-f6efcf8a7d62","keyword":"硅酸度","originalKeyword":"硅酸度"}],"language":"zh","publisherId":"huangj200510015","title":"含<span style=\"color:red\">金</span>富矿块<span style=\"color:red\">火</span>试<span style=\"color:red\">金</span>法配料的探讨","volume":"26","year":"2005"}],"totalpage":292,"totalrecord":2919}