{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"在25℃～100℃的温度范围内,测定了PdY8.5<span style=\"color:red\">Ru</span>0.19<span style=\"color:red\">合金</span>吸放氢、氘的P-C-T曲线.与纯钯相比,<span style=\"color:red\">合金</span>的P-C-T曲线坪区变窄,坪压降低,有显著的同位素效应,但迟滞效应较小.<span style=\"color:red\">合金</span>吸放氢氘的P-C-T曲线可拟合成p=A(er/B-1)形式.吸氘热焓为-13.9 kJ/mol·D2,熵变为-9.4 J/mol K·D2.进行了25℃下<span style=\"color:red\">合金</span>吸氢、氘速率的测量,<span style=\"color:red\">合金</span>吸氢、氘速率常数分别为KH=2.39×10-4 mol·s-1,KD=1.16×10-4 mol·s-1.而且<span style=\"color:red\">合金</span>的氢化过程用渐进转化模型描述.","authors":[{"authorName":"张桂凯","id":"ebf78c4b-67e4-48b7-8b08-5ab385967ee7","originalAuthorName":"张桂凯"},{"authorName":"陆光达","id":"1b20de62-f9f3-4eb0-a8b1-2989797c4a07","originalAuthorName":"陆光达"}],"doi":"","fpage":"1098","id":"80e51159-2f5f-4807-a735-0e90b3eb9ac4","issue":"7","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"a5a619e4-48dd-4b55-b655-2776a2584f2e","keyword":"<span style=\"color:red\">Pd</span>","originalKeyword":"Pd"},{"id":"202cbfa2-ecb8-4831-afb6-bcfa0ded7466","keyword":"<span style=\"color:red\">Pd-Y-Ru</span><span style=\"color:red\">合金</span>","originalKeyword":"Pd-Y-Ru合金"},{"id":"374f66cf-537e-4f34-b69b-b1a0a5e013bd","keyword":"氢同位素","originalKeyword":"氢同位素"},{"id":"0ad8e6a8-8f82-454a-9b5e-2bc5ed59c55f","keyword":"热力学","originalKeyword":"热力学"},{"id":"3208081c-f824-4ec9-8db7-d7006f547969","keyword":"动力学","originalKeyword":"动力学"}],"language":"zh","publisherId":"xyjsclygc200507024","title":"PdY8.5<span style=\"color:red\">Ru</span>0.19<span style=\"color:red\">合金</span>吸放氢氘特性","volume":"34","year":"2005"},{"abstractinfo":"在铂族金属中,<span style=\"color:red\">Ru</span>对<span style=\"color:red\">Pd</span>的强化效果最显著,在<span style=\"color:red\">Pd</span> - <span style=\"color:red\">Ru</span>系中分别加入Zr、Mo、<span style=\"color:red\">Y</span>三种元素,在不改变二元系各种优越性能的前提下,可进一步提高其力学和电学性能.分别介绍了<span style=\"color:red\">Pd</span> - <span style=\"color:red\">Ru</span> -Zr、<span style=\"color:red\">Pd</span> - <span style=\"color:red\">Ru</span> - Mo、<span style=\"color:red\">Pd</span> - <span style=\"color:red\">Ru</span> -<span style=\"color:red\">Y</span>多元系稀贵金属<span style=\"color:red\">合金</span>相的性能及应用、国内外<span style=\"color:red\">Pd</span> - <span style=\"color:red\">Ru</span> -M(Zr,Mo,<span style=\"color:red\">Y</span>)多元系稀贵金属<span style=\"color:red\">合金</span>相的研究进展,以及多元系稀贵金属<span style=\"color:red\">合金</span>相的发展前景.","authors":[{"authorName":"胡洁琼","id":"8d5a63fd-3458-49fc-a336-41c3be6087fd","originalAuthorName":"胡洁琼"},{"authorName":"谢明","id":"3d3e714e-f333-4507-8dfb-104b8dbdf088","originalAuthorName":"谢明"},{"authorName":"杨有方","id":"ca1716b3-4797-4995-b777-a8935830da44","originalAuthorName":"杨有方"},{"authorName":"崔浩","id":"6632da3d-6a54-4078-81ac-339fa48c93b4","originalAuthorName":"崔浩"},{"authorName":"陈永泰","id":"531753e8-4ff0-4572-91f8-acdc7272fffd","originalAuthorName":"陈永泰"},{"authorName":"刘满门","id":"fd5f0e20-65d6-4012-a072-7cb4bbe7ca02","originalAuthorName":"刘满门"},{"authorName":"张吉明","id":"8646ab8d-fbbd-4a6b-bba4-9833921a6231","originalAuthorName":"张吉明"}],"doi":"10.3969/j.issn.1004-0676.2011.04.015","fpage":"79","id":"1e87192d-8692-4237-9e36-fd30fe834450","issue":"4","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"5b764dae-f290-40b7-a59a-553111f1802a","keyword":"金属材料","originalKeyword":"金属材料"},{"id":"01953254-8ccd-43a7-8855-a5d9fcc3ff11","keyword":"钯-钌系","originalKeyword":"钯-钌系"},{"id":"400d1c70-55a2-4790-9830-3ce347bc56e6","keyword":"固溶体","originalKeyword":"固溶体"},{"id":"32741cd6-a941-48c7-951f-a4b393423548","keyword":"金属间化合物","originalKeyword":"金属间化合物"},{"id":"1621a0c2-c28d-4dc6-bb70-ab2c4f7bd266","keyword":"马氏体转变","originalKeyword":"马氏体转变"}],"language":"zh","publisherId":"gjs201104015","title":"<span style=\"color:red\">Pd</span> - <span style=\"color:red\">Ru</span> -Zr,Mo,<span style=\"color:red\">Y</span>)多元系稀贵金属<span style=\"color:red\">合金</span>相的研究进展","volume":"32","year":"2011"},{"abstractinfo":"为了解<span style=\"color:red\">Pd</span>及其<span style=\"color:red\">合金</span>贮氚(T)老化后,~3He在材料中的存在形式及分布状态,利用XRD与TEM分别分析了贮T老化1.6和3.5 a的<span style=\"color:red\">Pd</span>粉,以及贮T老化41和295 d的<span style=\"color:red\">Pd_91.31Y_8.50Ru</span>_0.19<span style=\"color:red\">合金</span>膜的结构变化.结果表明:T老化使得<span style=\"color:red\">Pd</span>粉的XRD峰变宽且峰强降低,品格发生畸变,同时,衍射峰略向低角度偏移,品格发生膨胀,1.6和3.5 a老化后,晶格常数分别增加0.095%和0.11%;在老化41 d的<span style=\"color:red\">Pd_91.31Y_8.50Ru</span>_0.19<span style=\"color:red\">合金</span>膜中,观察到分布均匀,直径约为1 nm的He泡,同时存在高密度的位错及位错环,在老化295 d的样品中,He泡直径略微增加,达1.2-1.4 nm,且分布均匀,位错及位错环密度降低.","authors":[{"authorName":"陈淼","id":"e2280ef7-ea5c-4260-aad8-750f96186541","originalAuthorName":"陈淼"},{"authorName":"陆光达","id":"81d21d3d-e10b-4dff-a185-5895d8d3abb1","originalAuthorName":"陆光达"},{"authorName":"张桂凯","id":"7427ff80-be5e-4239-adef-4217a2e36183","originalAuthorName":"张桂凯"},{"authorName":"张延志","id":"42b0c178-2eb2-4ad2-8945-8d71f3f2c7df","originalAuthorName":"张延志"},{"authorName":"王小英","id":"c7d7fb52-0205-4618-9ac0-a9d5296b703a","originalAuthorName":"王小英"},{"authorName":"任大鹏","id":"d7008497-f176-4a35-a2f9-52442ed52a70","originalAuthorName":"任大鹏"}],"doi":"10.3321/j.issn:0412-1961.2009.10.021","fpage":"1277","id":"e2c673d9-0e28-4c60-9c91-7258e92d5b23","issue":"10","journal":{"abbrevTitle":"JSXB","coverImgSrc":"journal/img/cover/JSXB.jpg","id":"48","issnPpub":"0412-1961","publisherId":"JSXB","title":"金属学报"},"keywords":[{"id":"7258b89d-570b-4f15-b6aa-41934f5342d6","keyword":"<span style=\"color:red\">Pd</span>","originalKeyword":"Pd"},{"id":"2fd6b2c5-88b6-481b-ab54-a3b6e586ad28","keyword":"<span style=\"color:red\">Pd_91.31Y_8.50Ru</span>_0.19","originalKeyword":"Pd_91.31Y_8.50Ru_0.19"},{"id":"d0124dde-e9ea-4999-8a51-4f8e00fbb1a3","keyword":"氚老化","originalKeyword":"氚老化"},{"id":"3e46bac7-aa39-4c9e-8393-9840b0fa1585","keyword":"~3He","originalKeyword":"~3He"},{"id":"95de25ef-4d13-42db-ba74-b8a7fd1aa673","keyword":"He泡","originalKeyword":"He泡"}],"language":"zh","publisherId":"jsxb200910021","title":"<span style=\"color:red\">Pd</span>粉及<span style=\"color:red\">Pd_91.31Y_8.50Ru</span>_0.19<span style=\"color:red\">合金</span>膜的氚老化效应","volume":"45","year":"2009"},{"abstractinfo":"针对<span style=\"color:red\">Pd8Y0.23Ru</span><span style=\"color:red\">合金</span>膜在透氢起始阶段氢渗透率不稳定的问题,分别采用XPS、SEM以及XRD对<span style=\"color:red\">合金</span>膜的表面成分、形貌以及相结构进行了研究.结果表明,氢渗透率升高是由两方面原因造成的:一是氢渗透过程中除去了占据<span style=\"color:red\">合金</span>膜表面活性解离位点的含C杂质,加快了氢气的解离,渗透控速过程逐渐转变为体扩散过程,使实验初期渗透率显著升高；二是氢渗透过程中,<span style=\"color:red\">合金</span>膜存在再结晶现象,导致晶粒细化,增加了晶界扩散占比,使氢原子体扩散系数变大.","authors":[{"authorName":"程亮","id":"ffd1bec0-e776-4b27-9ab7-781d2ba4a5d0","originalAuthorName":"程亮"},{"authorName":"陆光达","id":"3902467a-d4d4-498a-a955-f8925338a27e","originalAuthorName":"陆光达"},{"authorName":"张桂凯","id":"388c3ee8-987a-46dc-b2c6-348c9349c27f","originalAuthorName":"张桂凯"},{"authorName":"王晓英","id":"188d6403-4fe8-41c8-9815-95d05df280e2","originalAuthorName":"王晓英"}],"doi":"","fpage":"96","id":"2437203d-929c-4a16-a23f-bdec137cac17","issue":"2","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"09403ded-c3d0-462c-9182-e4c6ec32a4b8","keyword":"钯<span style=\"color:red\">合金</span>膜","originalKeyword":"钯合金膜"},{"id":"6040646f-e940-410c-8031-5cf060a1906e","keyword":"氢","originalKeyword":"氢"},{"id":"c37c39fa-c523-4172-b680-6668efa13377","keyword":"渗透率","originalKeyword":"渗透率"},{"id":"3097d977-3715-4e40-a7e5-e247ddeb406e","keyword":"稳定性","originalKeyword":"稳定性"}],"language":"zh","publisherId":"cldb201302026","title":"<span style=\"color:red\">Pd8Y0.23Ru</span><span style=\"color:red\">合金</span>膜氢渗透率稳定性的研究","volume":"27","year":"2013"},{"abstractinfo":"在Au-<span style=\"color:red\">Pd</span>、Pt-Ir、<span style=\"color:red\">Pd-Ru</span>系中分别加入Zr、Mo、<span style=\"color:red\">Y</span>3种元素,研究稀有金属元素的加入对3种<span style=\"color:red\">合金</span>系组织结构及力学和电学性能的影响.<span style=\"color:red\">合金</span>相在真空高频炉中熔炼.首先用X射线衍射仪和金相显微镜对<span style=\"color:red\">合金</span>相的显微组织和结构进行分析,用电桥、涡流导电仪测量<span style=\"color:red\">合金</span>相的电阻率,再用AG-X100KN型拉力试验机测量<span style=\"color:red\">合金</span>相的力学性能.结果表明:稀有金属元素的加入可以有效地细化<span style=\"color:red\">合金</span>相的显微组织,并且提高<span style=\"color:red\">合金</span>相的熔点、密度、力学性能和电阻率,但是<span style=\"color:red\">合金</span>相的延伸率有所降低.","authors":[{"authorName":"李嘉艳","id":"362c7879-0c62-458a-9a4a-2b7b2ffdab4d","originalAuthorName":"李嘉艳"},{"authorName":"谢明","id":"ff5104bf-8360-4e1c-a4e6-249dbd9e003e","originalAuthorName":"谢明"},{"authorName":"杨有才","id":"f7159354-7bec-4692-b917-50d9042ff5a4","originalAuthorName":"杨有才"},{"authorName":"张吉明","id":"cfc8cca2-b3e8-44bb-ac23-19cfd73f81ba","originalAuthorName":"张吉明"},{"authorName":"陈永泰","id":"a3746ff5-1dd9-41a4-a44d-ed2d4820fe64","originalAuthorName":"陈永泰"},{"authorName":"刘满门","id":"dc3855fd-2db7-4baa-8b1e-ba7c950a37f9","originalAuthorName":"刘满门"},{"authorName":"王塞北","id":"fb29b13a-0960-4f0b-ac07-e81a9932a35d","originalAuthorName":"王塞北"},{"authorName":"胡洁琼","id":"661fb11f-5b0f-4a55-9d1f-af1972b20eef","originalAuthorName":"胡洁琼"},{"authorName":"宁平","id":"5156451b-56c7-44ad-8cd8-347670a0ff37","originalAuthorName":"宁平"}],"doi":"","fpage":"2027","id":"eda2eaa8-8277-4eb1-8890-a4ce7eee5ee0","issue":"10","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"58f3f047-cc4d-43b2-8836-6c1d8e7bfb29","keyword":"贵金属","originalKeyword":"贵金属"},{"id":"75cb3fe2-bcd2-456b-9bbe-908030a28f4e","keyword":"稀有金属","originalKeyword":"稀有金属"},{"id":"1415d8fa-8250-482b-bcd5-12fc6fb079df","keyword":"掺杂","originalKeyword":"掺杂"},{"id":"2ddc8433-bf8d-485f-8519-32fbffa04978","keyword":"固溶","originalKeyword":"固溶"},{"id":"e57755a5-b6bf-4f4f-8644-d5dc3983d949","keyword":"力学性能","originalKeyword":"力学性能"}],"language":"zh","publisherId":"xyjsclygc201310010","title":"掺杂Zr、Mo、<span style=\"color:red\">Y</span>元素对Au-<span style=\"color:red\">Pd</span>、Pt-Ir、<span style=\"color:red\">Pd-Ru</span><span style=\"color:red\">合金</span>相性能的影响","volume":"42","year":"2013"},{"abstractinfo":"研究了厚度40 μm的<span style=\"color:red\">Pd8.5Y0.19Ru</span>(原子分数)<span style=\"color:red\">合金</span>膜的氢渗透性能.结果表明,在573～723 K温度范围内,氢在膜中的渗透符合Fick第一定律,氕、氘的渗透率表达式分别为φH=2.566×10-6exp(-3542.45/T) mol/m·s·Pa05和φD=1.398× 10-6exp(-3443.72/T) mol/m·s·Pa0.5,与钯钇<span style=\"color:red\">合金</span>相比,<span style=\"color:red\">合金</span>元素钌的加入降低了氕氘的渗透率和渗透分离系数.另外,CH4对膜还具有较强的毒化作用.","authors":[{"authorName":"陆光达","id":"1ebbab3c-6162-45c3-bd9d-7709b007f91f","originalAuthorName":"陆光达"},{"authorName":"张桂凯","id":"9177ed15-f075-42a6-ad60-7eeb9b33bb23","originalAuthorName":"张桂凯"},{"authorName":"陈淼","id":"cf419baa-5577-4a52-8a06-8241b900b48f","originalAuthorName":"陈淼"},{"authorName":"王晓英","id":"07afe590-ea0f-4e53-b61c-bceec80f291b","originalAuthorName":"王晓英"}],"doi":"","fpage":"74","id":"aaca2c50-6aae-4d8d-a097-ce89aa3a12df","issue":"1","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"38b5d32d-6abb-4ed9-a0f6-c1f491270d65","keyword":"d8.5<span style=\"color:red\">Y0.19Ru</span><span style=\"color:red\">合金</span>膜","originalKeyword":"d8.5Y0.19Ru合金膜"},{"id":"c20f6cef-7ffb-409e-859c-653eddac12f8","keyword":"氢同位素","originalKeyword":"氢同位素"},{"id":"705b3d97-1304-4e70-bcb6-e27957143401","keyword":"渗透","originalKeyword":"渗透"},{"id":"4ea1095b-f2aa-4773-9030-95972d484f70","keyword":"分离系数","originalKeyword":"分离系数"}],"language":"zh","publisherId":"xyjsclygc201201017","title":"<span style=\"color:red\">Pd8.5Y0.19Ru</span><span style=\"color:red\">合金</span>膜的氕氘渗透特性","volume":"41","year":"2012"},{"abstractinfo":"在300～450℃范围内,研究氢中加入CO2对<span style=\"color:red\">Pd8Y0.23Ru</span><span style=\"color:red\">合金</span>膜氢渗透性能的影响.结果表明,CO2的加入会大大降低膜的氢渗透率,CO2浓度越高,氢渗透率降低越多;CO2对<span style=\"color:red\">Pd8Y0.23Ru</span><span style=\"color:red\">合金</span>膜存在一定的毒化作用,使氢渗透率下降,450℃下的毒化作用明显强于300℃,但随着时间的延长,渗透率降低速率趋缓.CO2降低氢渗透率还有另外2个因素:当CO2浓度较高(＞3％,摩尔分数)时,聚集在膜表面附近的CO2对氢气传质的阻塞作用是氢渗透率降低的主要因素;当CO2浓度较低(＜1％)时,CO2在膜表面吸附,占据氢的活性点位,是氢渗透率降低的主要因素.","authors":[{"authorName":"程亮","id":"2717ae7c-a9dd-40c3-867e-003af89ef4e6","originalAuthorName":"程亮"},{"authorName":"陆光达","id":"1d3664e0-e231-4862-8585-9628b00a9702","originalAuthorName":"陆光达"},{"authorName":"张桂凯","id":"03978c98-254d-4a79-ba6e-44f0bd906bca","originalAuthorName":"张桂凯"},{"authorName":"王晓英","id":"19ea693e-3d17-4e19-871f-20fb7442777f","originalAuthorName":"王晓英"}],"doi":"","fpage":"1246","id":"7704bec5-6340-4900-b6e0-4f6ef7efc27b","issue":"6","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"e8ba2244-de92-4224-b3f6-8356ab3d89bc","keyword":"CO2","originalKeyword":"CO2"},{"id":"cd365e4d-3494-4232-a6aa-b26dee83fcaa","keyword":"钯<span style=\"color:red\">合金</span>膜","originalKeyword":"钯合金膜"},{"id":"225db67e-c3f6-4d3d-8c5a-e3175e096f83","keyword":"氢渗透率","originalKeyword":"氢渗透率"}],"language":"zh","publisherId":"xyjsclygc201306031","title":"CO2对<span style=\"color:red\">Pd8Y0.23Ru</span><span style=\"color:red\">合金</span>膜氢渗透性能的影响","volume":"42","year":"2013"},{"abstractinfo":"用图像仪测定了分别添加<span style=\"color:red\">Pd</span>、少量<span style=\"color:red\">Ru</span>、微量Ce的Pt-<span style=\"color:red\">Pd</span>-Rh<span style=\"color:red\">合金</span>在900~1200℃退火0.5h的晶粒度.在金相显微镜下观察了上述<span style=\"color:red\">合金</span>的显微组织,发现在Pt-<span style=\"color:red\">Pd</span>-Rh<span style=\"color:red\">合金</span>中Ce添加剂显示了大的晶界偏析和强的抑制晶体长大作用.讨论了<span style=\"color:red\">Pd</span>、<span style=\"color:red\">Ru</span>、Ce溶质对Pt-<span style=\"color:red\">Pd</span>-Rh<span style=\"color:red\">合金</span>晶粒长大的影响的作用机制.","authors":[{"authorName":"胡新","id":"a26bd338-f23d-49a6-a475-4e7a92686f3c","originalAuthorName":"胡新"},{"authorName":"张文莉","id":"85e4ebb9-3c48-4b59-9ccd-55d71cd2d7f8","originalAuthorName":"张文莉"},{"authorName":"杨桂生","id":"6b273315-240d-47ea-a86e-bb1d46be23fb","originalAuthorName":"杨桂生"},{"authorName":"宁远涛","id":"379f3bb2-c046-40b6-82f1-23456c1aa7a5","originalAuthorName":"宁远涛"}],"doi":"10.3969/j.issn.1004-0676.2009.01.005","fpage":"22","id":"549d8e1d-1640-49ee-bea2-940503b5a5ed","issue":"1","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"ab048ebe-20c8-4d9d-abaa-6662a95ee2f7","keyword":"金属材料","originalKeyword":"金属材料"},{"id":"35ec2424-1018-4fbd-bf6d-13f9a47249a2","keyword":"溶质","originalKeyword":"溶质"},{"id":"0238f17b-aa4f-4c1e-bcea-c90cb7586e38","keyword":"Pt-<span style=\"color:red\">Pd</span>-Rh<span style=\"color:red\">合金</span>","originalKeyword":"Pt-Pd-Rh合金"},{"id":"11e7f1d4-0c90-4634-ba78-644e0e350084","keyword":"晶粒长大","originalKeyword":"晶粒长大"},{"id":"55d56089-4603-43d2-a50a-e3d5a56d5dd1","keyword":"晶界富集","originalKeyword":"晶界富集"},{"id":"6869fa95-ff8a-471d-9af3-fce156dfab21","keyword":"体扩散","originalKeyword":"体扩散"}],"language":"zh","publisherId":"gjs200901005","title":"<span style=\"color:red\">Pd</span>、<span style=\"color:red\">Ru</span>、Ce溶质对Pt-<span style=\"color:red\">Pd</span>-Rh<span style=\"color:red\">合金</span>晶粒长大的影响","volume":"30","year":"2009"},{"abstractinfo":"在Ag-<span style=\"color:red\">Pd</span>-Gd, Ag-<span style=\"color:red\">Pd-Ru</span>, Ag-<span style=\"color:red\">Ru</span> -Gd和<span style=\"color:red\">Pd-Ru</span>-Gd三元系<span style=\"color:red\">合金</span>相图的基础上, 采用X射线衍射, 差热分析、扫描电镜和显微金相分析等方法研究了Ag-<span style=\"color:red\">Pd-Ru</span>-Gd(x( <span style=\"color:red\">Ru</span>) =5%, x(Gd)<25%)四元系相图的700℃等温截面. 结果表明: 该截面上包含有2个单相区, 即<span style=\"color:red\">Pd</span>(Ag)和<span style=\"color:red\">Pd</span> 3Gd; 4个两相区, 即<span style=\"color:red\">Pd</span>(Ag)+(<span style=\"color:red\">Ru</span>), <span style=\"color:red\">Pd</span>(Ag)+<span style=\"color:red\">Pd</span>3Gd, (<span style=\"color:red\">Ru</span>)+Ag51Gd14, (<span style=\"color:red\">Ru</span>)+<span style=\"color:red\">Pd</span> 3Gd; 3个三相区, 即<span style=\"color:red\">Pd</span>(A g)+<span style=\"color:red\">Pd</span>3Gd+(<span style=\"color:red\">Ru</span>), <span style=\"color:red\">Pd</span>(Ag)+Ag51Gd14+(<span style=\"color:red\">Ru</span>), <span style=\"color:red\">Pd</span>3Gd+Ag51Gd14 +(<span style=\"color:red\">Ru</span>); 1个四相区, 即<span style=\"color:red\">Pd</span>(Ag)+<span style=\"color:red\">Pd</span>3Gd+Ag51Gd14+(<span style=\"color:red\">Ru</span>). 未发现新的四元中间相. ","authors":[{"authorName":"张康侯","id":"03acbcd4-2e3d-4849-88e6-ae5db66e5787","originalAuthorName":"张康侯"},{"authorName":"徐云","id":"eab85ca6-2877-438f-ac02-77bce9273a9b","originalAuthorName":"徐云"},{"authorName":"李曲波","id":"d4cb00f3-46ab-427a-8d11-e98ac735e841","originalAuthorName":"李曲波"}],"doi":"","fpage":"231","id":"9b396e82-fa72-443d-bea2-f2b747d9098c","issue":"2","journal":{"abbrevTitle":"ZGYSJSXB","coverImgSrc":"journal/img/cover/ZGYSJSXB.jpg","id":"88","issnPpub":"1004-0609","publisherId":"ZGYSJSXB","title":"中国有色金属学报"},"keywords":[{"id":"62e13bbc-5f34-490c-aba5-d3994b05293a","keyword":"银","originalKeyword":"银"},{"id":"1dcbe8d3-299b-4e50-b848-c1f52cc55b3e","keyword":"钯","originalKeyword":"钯"},{"id":"73d76887-b431-4db4-b550-b3c1a07a9418","keyword":"钌","originalKeyword":"钌"},{"id":"c4097d32-d9ef-4d5a-b05c-61b4de0304c1","keyword":"钆","originalKeyword":"钆"},{"id":"26f88518-96f1-479c-89c9-4484b5392b94","keyword":"Ag-<span style=\"color:red\">Pd-Ru</span>-Gd四元系","originalKeyword":"Ag-Pd-Ru-Gd四元系"},{"id":"0afe8df8-1f97-4451-ba6f-0e1efe8211d7","keyword":"相图","originalKeyword":"相图"}],"language":"zh","publisherId":"zgysjsxb200202006","title":"Ag-<span style=\"color:red\">Pd-5Ru</span>-Gd四元系部分相图的700℃等温截面","volume":"12","year":"2002"},{"abstractinfo":"用光电子能谱及量子化学计算研究了<span style=\"color:red\">Pd-Y</span>-Si非晶态<span style=\"color:red\">合金</span>的电子结构。结果表明:在该体系中,<span style=\"color:red\">Y</span>向Si迁移电子并形成极性共价键,<span style=\"color:red\">Y</span>-Si极性共价键可能阻碍结晶时原子重排。","authors":[{"authorName":"骆梅青","id":"5521d570-db0e-4dfb-822e-ceef04a6c9f3","originalAuthorName":"骆梅青"},{"authorName":"陈念贻","id":"9ac96db3-4e2e-4282-bad4-fcdc99ddf95c","originalAuthorName":"陈念贻"},{"authorName":"俞志中","id":"5f960894-dda6-4b99-ae2c-a0dab7724333","originalAuthorName":"俞志中"},{"authorName":"宁远涛","id":"6e986661-311e-470f-93f0-c6f3a6a3a283","originalAuthorName":"宁远涛"},{"authorName":"周新铭","id":"db3bc32c-8ab8-4ec8-aca9-62090a55f498","originalAuthorName":"周新铭"}],"categoryName":"|","doi":"","fpage":"147","id":"64949f9f-e534-4ddd-9a67-c7a6dc99932a","issue":"5","journal":{"abbrevTitle":"JSXB","coverImgSrc":"journal/img/cover/JSXB.jpg","id":"48","issnPpub":"0412-1961","publisherId":"JSXB","title":"金属学报"},"keywords":[{"id":"02444235-c555-4a00-add7-5a0c9478201b","keyword":"非晶态<span style=\"color:red\">Pd-Y</span>-Si","originalKeyword":"非晶态Pd-Y-Si"},{"id":"fb598d41-3e59-4b98-8bee-ddca7a0159e3","keyword":"electronic structure","originalKeyword":"electronic structure"},{"id":"a246299b-0fea-4956-9d12-c2a6d56a65c7","keyword":"ESCA","originalKeyword":"ESCA"},{"id":"66c716fa-8043-4997-9c06-be284334775d","keyword":"EHMO","originalKeyword":"EHMO"}],"language":"zh","publisherId":"0412-1961_1989_5_21","title":"非晶态<span style=\"color:red\">Pd-Y</span>-Si<span style=\"color:red\">合金</span>的电子结构","volume":"25","year":"1989"}],"totalpage":4401,"totalrecord":44005}