{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"异佛尔酮二异氰酸酯(IPDI)、二羟甲基丙酸(DMPA)作为硬段,合成了水性聚氨酯.研究了硬段含量(质量分数)对乳液稳定性、膜耐热和力学性能等的影响.当硬段质量分数低于26%时,乳液贮存稳定性较差.随着硬段含量增加,聚氨酯膜拉伸强度迅速增加,断裂伸长率略有降低;红外光谱显示,自由的N-H伸缩振动峰强度减弱,<span style=\"color:red\">氢键</span>化N-H的振动峰强度增加;同时C=O伸缩振动峰整体向低波数方向移动,C=O伸缩振动峰峰形有明显的变化;DSC测试在50～125℃出现明显的<span style=\"color:red\">氢键</span>解离现象,吸热峰增强,证实了<span style=\"color:red\">氢键</span><span style=\"color:red\">作用</span>力随着硬段含量的增加逐渐增强.TG测试表明,水性聚氨酯硬段和软段分步解离,随着硬段含量的增加,硬段分解温度降低,水性聚氨酯耐热性能下降.","authors":[{"authorName":"徐恒志","id":"a75844ce-1ef1-4454-b51a-0d04c6b99b23","originalAuthorName":"徐恒志"},{"authorName":"王焕","id":"6ebc6385-a773-4d43-9cf4-ed146f030b24","originalAuthorName":"王焕"},{"authorName":"鲍俊杰","id":"18708655-55a6-4e59-b310-991d4ea1783f","originalAuthorName":"鲍俊杰"},{"authorName":"黄毅萍","id":"8bd03a1f-781a-4cf9-a6d1-7d79ef4dbd15","originalAuthorName":"黄毅萍"},{"authorName":"许戈文","id":"7041f32a-eef3-497f-a091-9d03b7e4d328","originalAuthorName":"许戈文"}],"doi":"10.3724/SP.J.1095.2011.00492","fpage":"770","id":"28141265-0af1-4269-a386-eb0fb3a35e49","issue":"7","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"bcf976bf-31c7-4123-84e8-499ec5f63704","keyword":"水性聚氨酯","originalKeyword":"水性聚氨酯"},{"id":"1f2f31e1-5ff9-487c-b79c-6dfe2b91c693","keyword":"硬段","originalKeyword":"硬段"},{"id":"3c71409b-a656-4b6f-beb5-c24fd91e0823","keyword":"<span style=\"color:red\">氢键</span><span style=\"color:red\">作用</span>","originalKeyword":"氢键作用"},{"id":"f3b635bc-54cc-4157-80a3-701027c64669","keyword":"热性能","originalKeyword":"热性能"}],"language":"zh","publisherId":"yyhx201107007","title":"水性聚氨酯硬段含量对其<span style=\"color:red\">氢键</span>相互<span style=\"color:red\">作用</span>及性能的影响","volume":"28","year":"2011"},{"abstractinfo":"采用红外光谱(IR)、X射线衍射(XRD)和差示扫描量热仪(DSC)从分子水平上分析了纳米羟基磷灰石/聚酰胺66生物复合材料中纳米羟基磷灰石(n-HA)和聚酰胺66(PA66)之间的相互<span style=\"color:red\">作用</span>机理.结果表明,纳米羟基磷灰石与聚酰胺66之间主要通过<span style=\"color:red\">氢键</span>结合,而<span style=\"color:red\">氢键</span><span style=\"color:red\">作用</span>主要发生在纳米羟基磷灰石的羟基和聚酰胺的仲氨基之间.<span style=\"color:red\">氢键</span>的方向性,削弱了PA66的β结晶取向,复合材料中PA66的结晶形态主要是α晶型.纳米羟基磷灰石和聚酰胺66之间的<span style=\"color:red\">氢键</span><span style=\"color:red\">作用</span>,增加了成核点,起到了异相成核剂的<span style=\"color:red\">作用</span>,虽然加快了PA66的成核速率,但同时会使体系的粘度增加,影响PA66的有序排列而导致PA66的结晶度降低.","authors":[{"authorName":"张翔","id":"520b9f39-eba2-4fbf-b75c-a448404b0f50","originalAuthorName":"张翔"},{"authorName":"李玉宝","id":"b869e7c6-6173-4cb0-b8d8-32d6ab079662","originalAuthorName":"李玉宝"},{"authorName":"吕国玉","id":"51ab52dd-5087-4817-9345-1d2c6e790ddb","originalAuthorName":"吕国玉"},{"authorName":"左奕","id":"e91104f9-8388-4f18-b8d6-5f379b4852bf","originalAuthorName":"左奕"},{"authorName":"牟元华","id":"25a88333-90be-49cc-b129-21aba392b6c6","originalAuthorName":"牟元华"},{"authorName":"吴兰","id":"e01d92c5-05ed-41fa-94d6-0ad547a6f63d","originalAuthorName":"吴兰"}],"doi":"","fpage":"896","id":"133c0ecc-e631-408f-a246-2080e1c2163b","issue":"6","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"7643bc60-9d77-41da-bd87-b2c4ab00aa80","keyword":"纳米羟基磷灰石","originalKeyword":"纳米羟基磷灰石"},{"id":"3aa3babc-e949-4305-b561-82ab9b8034be","keyword":"聚酰胺66","originalKeyword":"聚酰胺66"},{"id":"ea7f99a3-7105-4fba-aadb-c01c6c35404c","keyword":"<span style=\"color:red\">作用</span>机理","originalKeyword":"作用机理"},{"id":"b65a2e62-dd6f-4c30-998f-8c75a47c3596","keyword":"<span style=\"color:red\">氢键</span><span style=\"color:red\">作用</span>","originalKeyword":"氢键作用"}],"language":"zh","publisherId":"gncl200506028","title":"n-HA/PA66复合材料中两相间<span style=\"color:red\">作用</span>机理研究","volume":"36","year":"2005"},{"abstractinfo":"以芳香胺和肉桂醛为原料,合成的芳香族亚胺为亲电试剂,亚磷酸二乙酯或亚磷酸三乙酯为亲核试剂,在10％(摩尔分数)磷酸催化剂(Brφnsted acid)的<span style=\"color:red\">作用</span>下,通过催化剂与亲电试剂、亲核试剂之间共同形成的双<span style=\"color:red\">氢键</span>或单<span style=\"color:red\">氢键</span>的<span style=\"color:red\">作用</span>,成功地合成了α-氨基膦酸酯类化合物,收率可达到79％～85％.","authors":[{"authorName":"姚元勇","id":"4291be55-8944-4cad-b321-7cdd13289f60","originalAuthorName":"姚元勇"},{"authorName":"吴兰艳","id":"9a2002c3-02ee-42c6-99d7-d1061923500f","originalAuthorName":"吴兰艳"},{"authorName":"舒华","id":"fb6ec08e-0aaa-4eda-8539-bef279c68ee5","originalAuthorName":"舒华"},{"authorName":"唐帮成","id":"dc26eb4a-204a-4ef4-8bed-b9e8052618f9","originalAuthorName":"唐帮成"},{"authorName":"薛伟","id":"49d25e44-4503-4349-b215-34d18bbb132c","originalAuthorName":"薛伟"}],"doi":"10.3724/SP.J.1095.2014.40052","fpage":"1428","id":"f92dca1e-977a-4aa4-a893-4f1699680513","issue":"12","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"b323c69f-06b6-4297-8fb5-fed49ab5816d","keyword":"Brφnsted酸","originalKeyword":"Brφnsted酸"},{"id":"c96d7d77-8d72-4a63-9126-d4e695b85427","keyword":"α-氨基膦酸酯","originalKeyword":"α-氨基膦酸酯"},{"id":"da36c31c-d014-40cc-83d6-208b7e3be67d","keyword":"<span style=\"color:red\">氢键</span><span style=\"color:red\">作用</span>","originalKeyword":"氢键作用"},{"id":"87b45766-6f66-4b01-bbe3-1c5d6eb8d0f7","keyword":"催化","originalKeyword":"催化"},{"id":"96d897c1-3704-4355-9d55-fd1ee2f1aaaa","keyword":"磷氢化反应","originalKeyword":"磷氢化反应"}],"language":"zh","publisherId":"yyhx201412010","title":"Brφnsted酸催化合成α-氨基膦酸酯","volume":"31","year":"2014"},{"abstractinfo":"在L-脯氨酸催化的芳香醛与丙酮直接不对称aldol反应体系中添加二醇或二酚类助剂可有效提高反应活性.助剂的使用降低了该反应体系中L-脯氨酸的用量.特别是以邻苯二酚为助剂时,最佳反应条件下,仅用5mol％L-脯氨酸与1mol％助剂催化2-硝基苯甲醛与丙酮直接不对称aldol反应,aldol产物产率高达90％,对映选择性为80％.该反应产率比未加助剂条件下,L-脯氨酸用量为30mol％时的反应产率高.采用量子化学计算研究了助剂对该反应的促进<span style=\"color:red\">作用</span>.结果表明,助剂可与芳香醛的醛基形成<span style=\"color:red\">氢键</span>,从而活化醛基,提高反应效率.邻苯二酚结构中相邻的羟基能与底物芳香醛羰基的氧原子形成双<span style=\"color:red\">氢键</span>,大大活化了底物芳香醛的羰基.因此,该助剂可有效促进L-脯氨酸催化剂的直接不对称aldol反应.","authors":[{"authorName":"骆建轻","id":"2bc98313-03e1-4313-ab26-db993fbfe1f0","originalAuthorName":"骆建轻"},{"authorName":"谭蓉","id":"ff4ad0a0-89f3-4079-a75e-9816fd5563a3","originalAuthorName":"谭蓉"},{"authorName":"孔瑜","id":"a46b02f9-de08-496e-ad13-b6d90321d80d","originalAuthorName":"孔瑜"},{"authorName":"黎成勇","id":"6412e79e-7b80-4f49-a625-374105aac2f4","originalAuthorName":"黎成勇"},{"authorName":"银董红","id":"66ab7037-8251-47f3-a2ac-128496430dfe","originalAuthorName":"银董红"}],"doi":"10.1016/S1872-2067(11)60394-X","fpage":"1133","id":"9f554c2c-bdb3-4f90-97b8-f97b41e84d57","issue":"7","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"186a9197-2ff4-447b-902c-acae9261fb52","keyword":"L-脯氨酸","originalKeyword":"L-脯氨酸"},{"id":"3f9f7740-e67b-49b7-b5da-55d7001b51a6","keyword":"邻苯二酚","originalKeyword":"邻苯二酚"},{"id":"a9888cf2-66ab-41ef-bdc1-6a007f40799b","keyword":"芳香醛","originalKeyword":"芳香醛"},{"id":"6d5c59f1-9724-48f6-bc72-9708b2b26969","keyword":"丙酮","originalKeyword":"丙酮"},{"id":"a928696f-26d3-4055-b9f2-acfa16aceaf3","keyword":"直接不对称aldol反应","originalKeyword":"直接不对称aldol反应"},{"id":"f35e7e81-6374-4f9e-94d2-991c0d864f70","keyword":"<span style=\"color:red\">氢键</span><span style=\"color:red\">作用</span>","originalKeyword":"氢键作用"}],"language":"zh","publisherId":"cuihuaxb201207011","title":"助剂对L-脯氨酸催化直接不对称Aldol反应的影响","volume":"33","year":"2012"},{"abstractinfo":"针对污水处理中产生的大量剩余污泥的絮凝脱水问题,研究制备了壳聚糖/蒙脱土(CTS/MMT)复合絮凝剂,并利用CTS聚电解质的电中和与架桥<span style=\"color:red\">作用</span>,以及MMT的吸附<span style=\"color:red\">作用</span>来提高污泥的脱水性能.结果表明,复合材料两相间存在<span style=\"color:red\">氢键</span><span style=\"color:red\">作用</span>,通过形成物理交联网络使其弹性储能模量增加,损耗因子减小;复合材料中CTS分子链插层进入MMT层间,且采取单分子层的方式排列;CTS/MMT质量比为1∶1.5、质量浓度为0.1 g/L时有利于降低污泥的比阻和含水率,提高污泥上清液的透光率,降低浊度,增强复合材料的污泥脱水性能.","authors":[{"authorName":"黄朋","id":"eac43b4e-5254-4943-83b2-c7821b0b4733","originalAuthorName":"黄朋"},{"authorName":"叶林","id":"912dad0a-9f4f-4373-8705-4b39c863f598","originalAuthorName":"叶林"}],"doi":"","fpage":"119","id":"42e19626-cc27-4b97-a5c4-d187403c2a61","issue":"4","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"a3308868-b81b-4dd8-84aa-0011ecd2a240","keyword":"壳聚糖/蒙脱土复合絮凝剂","originalKeyword":"壳聚糖/蒙脱土复合絮凝剂"},{"id":"d6f945e5-9fab-4435-8674-f174823d93b2","keyword":"<span style=\"color:red\">氢键</span><span style=\"color:red\">作用</span>","originalKeyword":"氢键作用"},{"id":"11c60a7c-a027-4ec1-a699-6b4cbda6462a","keyword":"插层结构","originalKeyword":"插层结构"},{"id":"b629d437-2277-44c2-a694-1385527d7a6f","keyword":"污泥脱水","originalKeyword":"污泥脱水"}],"language":"zh","publisherId":"gfzclkxygc201404025","title":"壳聚糖/蒙脱土复合絮凝剂的结构及污泥脱水性能","volume":"30","year":"2014"},{"abstractinfo":"设计合成了2种新型缩双芳氨基硫脲受体分子(S1,S2),利用紫外-可见吸收光谱考察了其与F-、Cl-、Br-、I-、CH3COO-、HSO-4、H2PO-4和NO-3 8种阴离子的识别<span style=\"color:red\">作用</span>.结果表明,当加入F-、CH3COO-和H2PO-4时,溶液颜色立刻由无色变为黄色,而加入其它阴离子则无变化,实现了对这3种阴离子的裸眼检测.通过计算可知,2种受体分子对这3种阴离子的识别<span style=\"color:red\">作用</span>呈现出有规律的变化.对同种阴离子,受体分子S1与之络合常数大于S2;且主客体间形成1:1的配合物.质子溶剂效应实验进一步证明,受体分子与阴离子之间以<span style=\"color:red\">氢键</span><span style=\"color:red\">作用</span>方式相结合.","authors":[{"authorName":"徐维霞","id":"e30719dd-daed-40bb-9d92-18790fb5d59f","originalAuthorName":"徐维霞"},{"authorName":"张有明","id":"bb22e296-0cfc-4a0c-8bce-8785a126624a","originalAuthorName":"张有明"},{"authorName":"魏太保","id":"ea853f01-9433-4c4f-b3df-ea3a80b86aeb","originalAuthorName":"魏太保"}],"doi":"10.3969/j.issn.1000-0518.2008.12.018","fpage":"1460","id":"9469d544-7d70-4e8e-a53b-8c592b55faae","issue":"12","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"a13f56a1-e6ae-4b77-a238-f86bb0a4630f","keyword":"缩双芳氨基硫脲","originalKeyword":"缩双芳氨基硫脲"},{"id":"72f67d0c-3f8c-4be7-8e8a-1b1c19b79099","keyword":"合成","originalKeyword":"合成"},{"id":"ec4bce5f-97d0-490c-b68f-c70ec82f6214","keyword":"阴离子识别","originalKeyword":"阴离子识别"},{"id":"0ba3ff8c-556e-4a20-a28e-16f1481e1eb3","keyword":"<span style=\"color:red\">氢键</span><span style=\"color:red\">作用</span>","originalKeyword":"氢键作用"}],"language":"zh","publisherId":"yyhx200812018","title":"一类缩双芳氨基硫脲受体的合成及阴离子识别","volume":"25","year":"2008"},{"abstractinfo":"目前市售钠基蒙脱石实际上多为钠钙基蒙脱石(Na-Ca-MMT),以此为原料制备出具有介孔结构的PVA/(Na-Ca-MMT)纤维.PVA中的O-H与MMT中的Si-O键,以及PVA中的\"醋酸根\"与MMT微粒板面上的O-H形成<span style=\"color:red\">氢键</span>,发生偶联<span style=\"color:red\">作用</span>,增强了PVA插入MMT片中的动力.通过增加MMT鳞片状微粒的层间距和改善其分散性,促使MMT在冰晶诱导下尽可能多地呈现单向排列,有利于PVA/MMT纤维的形成.对比两种Na-Ca-MMT的纤维形貌,1#样品纤维长径比大,直径均匀,可以作为制备PVA/(Na-Ca-MMT)纤维的首选原料.","authors":[{"authorName":"杨魁","id":"2810be68-06d0-41b3-803c-3cf91a417f51","originalAuthorName":"杨魁"},{"authorName":"杨长辉","id":"80b03e9e-61fb-4b60-a1e2-11d72daa37e6","originalAuthorName":"杨长辉"},{"authorName":"李贞","id":"e9ecf9fd-806c-42bf-92a0-51f80e17c606","originalAuthorName":"李贞"}],"doi":"","fpage":"113","id":"ac6024f3-bd71-4935-9820-6607f6f83b2a","issue":"20","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"a6671c2e-e2a0-402b-9e61-59bfdf40eb3a","keyword":"Na-Ca-MMT","originalKeyword":"Na-Ca-MMT"},{"id":"a2032723-19ee-4e61-a74d-11b3b1cde055","keyword":"纤维","originalKeyword":"纤维"},{"id":"fb347282-b544-4cef-9454-552895db13ce","keyword":"<span style=\"color:red\">氢键</span><span style=\"color:red\">作用</span>","originalKeyword":"氢键作用"}],"language":"zh","publisherId":"cldb201020032","title":"Na-Ca-MMT制备介孔纤维材料的机理分析","volume":"24","year":"2010"},{"abstractinfo":"以环氧氯丙烷作为交联溶剂合成和表征了纤维素功能化的b-环糊精,考察了这种超分子聚合物作为一种多相催化剂用于苯甲醛的合成的催化性能。结果表明,该催化剂在温和的反应条件下具有较高的催化活性和选择性,容易恢复和重新利用,且活性没有大的损失。进一步研究指出,b-环糊精聚合物中的b-环糊精能通过非极性共价键与肉桂醛形成主客包结物,此外,b-环糊精和纤维素的功能基团能与肉桂醛通过O-H×××O的<span style=\"color:red\">氢键</span>形成多重<span style=\"color:red\">氢键</span>的相互<span style=\"color:red\">作用</span>,这种<span style=\"color:red\">氢键</span>的协同<span style=\"color:red\">作用</span>明显提高了催化剂的性能。","authors":[{"authorName":"杨祖金","id":"42b73a12-69c0-4571-ba4a-7b957f766644","originalAuthorName":"杨祖金"},{"authorName":"纪红兵","id":"92e293b4-bc07-48d5-9f24-b274b3a31104","originalAuthorName":"纪红兵"}],"doi":"10.1016/S1872-2067(14)60056-5","fpage":"590","id":"8f8c9872-6890-4b5a-aa6d-9fa2c14912a1","issue":"4","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"2c70011f-e472-43ec-ad82-a1f963d483ec","keyword":"纤维素功能化β-环糊精","originalKeyword":"纤维素功能化β-环糊精"},{"id":"b1b9b650-876b-49fc-b55f-7199a045ba13","keyword":"<span style=\"color:red\">氢键</span>","originalKeyword":"氢键"},{"id":"710c0f41-ec7d-406d-b26c-4acded70775a","keyword":"底物专一性","originalKeyword":"底物专一性"},{"id":"7d96f1a9-2c06-42c5-9ac5-ce7c088f5488","keyword":"肉桂醛氧化","originalKeyword":"肉桂醛氧化"},{"id":"adc3a256-3300-4a5b-8ad7-7b76f43cd476","keyword":"苯甲醛","originalKeyword":"苯甲醛"}],"language":"zh","publisherId":"cuihuaxb201404021","title":"<span style=\"color:red\">氢键</span>的协同<span style=\"color:red\">作用</span>驱动水中苯甲醛的合成","volume":"","year":"2014"},{"abstractinfo":"测试分析了几种不同纤维的蠕变性能,研究了分子结构对纤维蠕变性能的影响.分析结果表明,超高分子量聚乙烯纤维的蠕变中,普弹形变和高弹形变部分很少,主要为分子间滑移造成的粘流形变部分;而粘胶强力丝、聚丙烯腈炭纤维原丝和高性能涤纶丝的蠕变中粘流形变较少,这是由于分子间的结构差异造成的.","authors":[{"authorName":"陈聚文","id":"62077f0e-4141-47d1-9426-d1d4e1bd1204","originalAuthorName":"陈聚文"},{"authorName":"潘婉莲","id":"addf3ae5-696a-4997-81c9-e4112d88790c","originalAuthorName":"潘婉莲"},{"authorName":"于俊荣","id":"2224ee95-5a67-4c0a-acb7-27cffa039c4e","originalAuthorName":"于俊荣"},{"authorName":"诸静","id":"08e25b52-fbe7-4a6c-b244-1201e301ee07","originalAuthorName":"诸静"}],"doi":"","fpage":"114","id":"c0a991be-6a34-4d4a-b90b-69175cf3aad0","issue":"2","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"3f09b436-7d04-439e-8286-e902710c3b85","keyword":"蠕变","originalKeyword":"蠕变"},{"id":"6d75ddf4-17bf-47f4-a202-9b8bea11d377","keyword":"超高分子量聚乙烯","originalKeyword":"超高分子量聚乙烯"},{"id":"61c019c2-610c-4774-9333-4b54cb5642d1","keyword":"聚丙烯腈","originalKeyword":"聚丙烯腈"},{"id":"31dcc589-27f5-4eae-bdda-0b1891761a86","keyword":"粘胶强力丝","originalKeyword":"粘胶强力丝"},{"id":"914e9185-9fd7-479a-a0ba-1aa95496c81e","keyword":"高性能涤纶","originalKeyword":"高性能涤纶"},{"id":"072fc1fb-007f-4249-ae87-291c769a9d22","keyword":"分子结构","originalKeyword":"分子结构"},{"id":"96c10dce-4a85-4d2f-a58c-5010f78c8630","keyword":"<span style=\"color:red\">氢键</span><span style=\"color:red\">作用</span>","originalKeyword":"氢键作用"}],"language":"zh","publisherId":"gfzclkxygc200402030","title":"纤维分子结构与蠕变性能的关系","volume":"20","year":"2004"},{"abstractinfo":"极性有机分子可以和聚酰胺类纳滤膜表面形成众多<span style=\"color:red\">氢键</span>,从而削弱纳滤膜的荷电效应.论文选择几种典型极性分子,探讨<span style=\"color:red\">氢键</span><span style=\"color:red\">作用</span>对纳滤过程荷电效应的影响.结果表明,在极性分子和聚酰胺类纳滤膜形成<span style=\"color:red\">氢键</span>的过程中,聚酰胺纳滤膜对电解质的截留率有所下降.这种影响随分子极性增强而更加明显;当温度升高时,<span style=\"color:red\">氢键</span>遭到破坏,截留率有所回升.","authors":[{"authorName":"王刚","id":"f6322e7d-e608-466d-9f23-8243a55a4962","originalAuthorName":"王刚"},{"authorName":"王翔","id":"67d06d1a-3197-4f32-8970-103b5f6a917b","originalAuthorName":"王翔"},{"authorName":"张宇峰","id":"b78a12d3-b148-4c4f-ae2f-329c16d17575","originalAuthorName":"张宇峰"},{"authorName":"杜启云","id":"1b714c5b-a655-485a-bd9b-4cb582b05d44","originalAuthorName":"杜启云"},{"authorName":"张宏伟","id":"3d8e2998-2a47-47ac-a971-f6d10a58757f","originalAuthorName":"张宏伟"}],"doi":"","fpage":"610","id":"9ec85dd3-b524-496d-9d1e-ba615aa79b2b","issue":"4","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"8b4ce02a-5534-4396-aed0-cb23f51643d7","keyword":"<span style=\"color:red\">氢键</span>","originalKeyword":"氢键"},{"id":"992831ba-7789-4195-ac06-c35fc20b8cc7","keyword":"极性分子","originalKeyword":"极性分子"},{"id":"1f036f48-bbb5-46ca-a51d-9ff4a4b218ae","keyword":"纳滤","originalKeyword":"纳滤"},{"id":"fefec63b-773e-4a6b-8272-7dc4aa43279b","keyword":"截留率","originalKeyword":"截留率"},{"id":"72e0bb04-5748-4923-a018-69f7b4ef554c","keyword":"电子传递","originalKeyword":"电子传递"}],"language":"zh","publisherId":"clkxygc200904029","title":"<span style=\"color:red\">氢键</span><span style=\"color:red\">作用</span>对纳滤过程荷电效应的影响","volume":"27","year":"2009"}],"totalpage":3092,"totalrecord":30915}