{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"合成了具有<span style=\"color:red\">D-</span>π-A型<span style=\"color:red\">结构</span>的含吡啶基的新型有机化合物4-[4-(2-吡啶基)苯乙烯基]-N,N-二正丁基苯胺,其<span style=\"color:red\">结构</span>经元素分析、UV和X射线衍射进行了表征.利用单光子液体荧光光谱、单光子荧光量子产率、固体荧光光谱和荧光寿命探讨了它的光学性质.该分子晶体属于三斜晶系,P-1空间群,晶胞参数为:a=1.15041(3) nm,b=1.45746(4) nm,c=1.51598(4) nm,Z=4,V=2.33068(11) nm3,R1=0.096 2,wR2=0.263 0.通过研究发现,目标化合物平面性好,分子为<span style=\"color:red\">D-</span>π-A型<span style=\"color:red\">结构</span>,分子间有C—H…π相互作用,使得它具有良好的光学性质.","authors":[{"authorName":"潘月礼","id":"2399b17a-f132-4fea-979d-f747140dd0fb","originalAuthorName":"潘月礼"},{"authorName":"王欣","id":"d7827429-0977-4193-b9bc-851b7119d42a","originalAuthorName":"王欣"},{"authorName":"赵祖志","id":"060cf86b-81e2-465a-bf44-966d3ae8f2bd","originalAuthorName":"赵祖志"},{"authorName":"韦文美","id":"f6bc14fa-ad52-4644-9d6c-095ce5f01b26","originalAuthorName":"韦文美"}],"doi":"10.3724/SP.J.1095.2012.00133","fpage":"155","id":"a0e8725c-6930-4efe-b66b-72c0cda26fa5","issue":"2","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"d1bae08a-d7ac-40fa-8cc1-f021721f61f3","keyword":"吡啶","originalKeyword":"吡啶"},{"id":"2b0dfec7-73f6-49bd-b409-4b3281bbae1b","keyword":"<span style=\"color:red\">D-</span>π-A<span style=\"color:red\">结构</span>","originalKeyword":"D-π-A结构"},{"id":"0ed068dd-6cee-4f23-95a2-a4d655286870","keyword":"光学性质","originalKeyword":"光学性质"},{"id":"07733a7b-2ead-480a-a4b7-ed729fee4f3f","keyword":"平面性","originalKeyword":"平面性"}],"language":"zh","publisherId":"yyhx201202007","title":"4-[4-(2-吡啶基)苯乙烯基]-N,N-二正丁基苯胺的合成、晶体<span style=\"color:red\">结构</span>及光学性质","volume":"29","year":"2012"},{"abstractinfo":"以<span style=\"color:red\">D-</span>萘普生为目标分子,采用差示紫外吸收光谱法研究了萘普生分子与功能单体间的作用力性质,确证了萘普生与丙烯酰胺通过氢键和离子键方式自组装形成超分子复合物.按不同的溶剂(致孔剂)用量合成了一组分子印迹聚合物材料,利用红外光谱对产物<span style=\"color:red\">结构</span>进行了分析,表明合成的产品具有所需的特征<span style=\"color:red\">结构</span>.首次使用透射电镜表征了分子印迹聚合物的微观形貌特征,阐明了溶剂的致孔作用机理,并结合吸附动力学研究了该材料的网孔<span style=\"color:red\">结构</span>对吸附速率的影响.根据选择性吸附实验的结果计算了所合成材料的特异吸附容量和印迹指数,其中,印迹指数最高达3.756.","authors":[{"authorName":"张志良","id":"6029ec3c-6ba1-424b-a246-eae217bd9aae","originalAuthorName":"张志良"},{"authorName":"王兵","id":"84386a1a-cc83-442b-92b3-95d8c897ab74","originalAuthorName":"王兵"}],"doi":"","fpage":"112","id":"728cdf75-012d-4fab-984b-c78ed24fd099","issue":"9","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"e69e1015-fd64-4ba1-9645-f1826c03c565","keyword":"分子识别材料","originalKeyword":"分子识别材料"},{"id":"82a299d7-cfd3-40cd-99b2-c9861a16f7de","keyword":"超分子复合物","originalKeyword":"超分子复合物"},{"id":"ed2f4f47-ca5b-4eea-96ac-e9cc67cc4dfe","keyword":"分子印迹","originalKeyword":"分子印迹"},{"id":"8582eecb-0187-453d-aa4d-bebf5f3bdeec","keyword":"<span style=\"color:red\">D-</span>萘普生","originalKeyword":"D-萘普生"}],"language":"zh","publisherId":"gfzclkxygc201009030","title":"分子识别材料<span style=\"color:red\">D-</span>萘普生印迹聚合物的制备与<span style=\"color:red\">结构</span>性能","volume":"26","year":"2010"},{"abstractinfo":"本文报道了两种新的有机加合物非线性光学材料--水合<span style=\"color:red\">D</span>(或L)-酒石酸苯胺晶体的制备、单晶生长,用X射线衍射仪测定了<span style=\"color:red\">D-</span>酒石酸苯胺晶体<span style=\"color:red\">结构</span>,其晶体学数据为:单斜晶系,P21空间群,a=0.9610(3)nm,b=0.7285(2)nm,c=1.7323(6)nm,β=96.489(6)°,V=1.2050(7)nm3,Z=4,R1=0.0455,wR2=0.0879.经测定表明,<span style=\"color:red\">D-</span>酒石酸苯胺和L-酒石酸苯胺晶体具有相同单晶<span style=\"color:red\">结构</span>.这两种晶体在1064nm的Nd3+:YAG调Q脉冲激光束照射下均产生绿色的532nm的倍频光,其倍频光强度与KDP晶体基本相同,具有稳定的物理化学性质.","authors":[{"authorName":"陈伟","id":"f1dac08f-5a62-4315-916f-8da3ea0a24e6","originalAuthorName":"陈伟"},{"authorName":"郑吉民","id":"fd748abd-4e11-4a2d-8f70-c2cb117f612d","originalAuthorName":"郑吉民"},{"authorName":"车云霞","id":"d3cb1d12-bd80-4db0-9350-5fbc85a4e334","originalAuthorName":"车云霞"}],"doi":"10.3969/j.issn.1000-985X.2005.02.016","fpage":"265","id":"727725da-cc54-42a6-8666-39d8aabcf50f","issue":"2","journal":{"abbrevTitle":"RGJTXB","coverImgSrc":"journal/img/cover/RGJTXB.jpg","id":"57","issnPpub":"1000-985X","publisherId":"RGJTXB","title":"人工晶体学报"},"keywords":[{"id":"6ae2779c-a0cf-4339-98cf-0219cde1ac30","keyword":"<span style=\"color:red\">D-</span>酒石酸","originalKeyword":"D-酒石酸"},{"id":"bd9e8246-722e-4f9f-9478-0182d2b01c5e","keyword":"苯胺","originalKeyword":"苯胺"},{"id":"6836ac7a-3b0a-471a-b9ac-6f8ab4d4e99f","keyword":"加合物","originalKeyword":"加合物"},{"id":"b83826b5-0971-44d5-b874-9df68d7d95c9","keyword":"晶体<span style=\"color:red\">结构</span>","originalKeyword":"晶体结构"},{"id":"8c17c8b8-d3b5-4785-ad80-777e140e1479","keyword":"非线性光学","originalKeyword":"非线性光学"}],"language":"zh","publisherId":"rgjtxb98200502016","title":"新的有机非线性光学倍频材料--水合<span style=\"color:red\">D-</span>酒石酸苯胺加合物的制备和晶体<span style=\"color:red\">结构</span>","volume":"34","year":"2005"},{"abstractinfo":"以吡咯并四硫富瓦烯衍生物(1)为原料,经过Vilsmeier甲酰化、Wittig反应或交叉偶联反应得到<span style=\"color:red\">D-</span>π-A型化合物(6a,7a),为了比较N-甲基的影响,以N-甲基吡咯并四硫富瓦烯衍生物(2)出发,用同样的方法合成了N-甲基化的<span style=\"color:red\">D-</span>π-A型化合物(6b,7b). 用循环伏安法(CV)和UV-Vis研究了目标化合物的电化学和光物理性质,并进行了非线性光学性质的理论计算. 结果表明,目标化合物的紫外最大吸收波长在325～383 nm之间,具有较长共轭<span style=\"color:red\">结构</span>的化合物7a和7b显示出较好的三阶非线性光学性质, 它们在λ=1 064 nm基频下的三阶非线性系数γ值达5×10-33 esu.","authors":[{"authorName":"安彩霞","id":"982d1016-e4c3-4d90-91d4-bd634583794a","originalAuthorName":"安彩霞"},{"authorName":"侯瑞斌","id":"0ae529a4-715a-477a-96ff-17b48d7d1caf","originalAuthorName":"侯瑞斌"},{"authorName":"邱寒","id":"434aa7d4-16bc-4595-8c43-38a08cc22b3e","originalAuthorName":"邱寒"},{"authorName":"赵亮","id":"72db0413-8271-4fa5-9184-f8b630e0efd2","originalAuthorName":"赵亮"},{"authorName":"尹炳柱","id":"0ae5da2b-62b3-4769-891b-0e31c5115ba3","originalAuthorName":"尹炳柱"},{"authorName":"苏忠民","id":"1340e79d-6682-42c4-a7ca-9d9aef4176e9","originalAuthorName":"苏忠民"}],"doi":"10.3969/j.issn.1000-0518.2009.07.011","fpage":"795","id":"6d68d5c2-44c5-4d1e-830b-7aae73eafab9","issue":"7","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"f5dadd38-e3b0-4b16-8e6e-bf0c3fb8c80b","keyword":"吡咯并四硫富瓦烯","originalKeyword":"吡咯并四硫富瓦烯"},{"id":"f41ed26b-fda5-4b46-9ee4-76dd9a6cd32c","keyword":"电化学","originalKeyword":"电化学"},{"id":"73d3baa7-79f9-4830-87b7-6c445e03e8f4","keyword":"光物理性质","originalKeyword":"光物理性质"},{"id":"f8e756fc-b0fe-4956-9ea4-616c138b296b","keyword":"非线性光学性质","originalKeyword":"非线性光学性质"},{"id":"95b5768b-92ad-4897-b130-8dfeb08a02a9","keyword":"理论计算","originalKeyword":"理论计算"}],"language":"zh","publisherId":"yyhx200907011","title":"基于吡咯并四硫富瓦烯<span style=\"color:red\">结构</span>的<span style=\"color:red\">D-</span>π-A型化合物的合成及其非线性光学性质的理论计算","volume":"26","year":"2009"},{"abstractinfo":"以葡萄糖为原料,经乙酰化、选择性脱C1位乙酰基、转化成三氯乙酰亚胺酯、与受体醇偶联和脱保护5步反应合成了11种不同碳链长度的烷基-β-<span style=\"color:red\">D-</span>吡喃葡萄糖苷.利用核磁共振、偏光显微镜和热失重分析法对其进行<span style=\"color:red\">结构</span>表征和性能测试.结果表明,当烷基-β-<span style=\"color:red\">D-</span>吡喃葡萄糖苷疏水烷基链长n为6～10时,均具有发泡和乳化性能,特别是正壬基-β-<span style=\"color:red\">D-</span>吡喃葡萄糖苷(n=9)具有更加优异的发泡和乳化性能；当烷基-β-<span style=\"color:red\">D-</span>吡喃葡萄糖苷疏水链的长度n≥7时,均具有热致液晶行为,特别是正十二烷基-β<span style=\"color:red\">D-</span>吡喃葡萄糖苷(n＝12)和十四烷基-β-<span style=\"color:red\">D-</span>吡喃葡萄糖苷(n=14)能够形成更加稳定的液晶态.","authors":[{"authorName":"刘灯峰","id":"15881fa9-15d3-45cb-acb1-6e039d6fa683","originalAuthorName":"刘灯峰"},{"authorName":"陈朗秋","id":"df0bf39e-dee4-4298-bf61-890ba08952fb","originalAuthorName":"陈朗秋"},{"authorName":"李宏伟","id":"fde20078-1564-46e3-9d68-5ee1728d75c0","originalAuthorName":"李宏伟"},{"authorName":"曾森","id":"60aa8b6d-684c-4f8e-8031-1e2caf029151","originalAuthorName":"曾森"},{"authorName":"旷娜","id":"9f4275fd-25aa-40ef-a7dc-dfeb7ba72485","originalAuthorName":"旷娜"},{"authorName":"田静","id":"a2e874e4-b6b3-410f-bcb4-d8c6ed010718","originalAuthorName":"田静"}],"doi":"10.3724/SP.J.1095.2013.20592","fpage":"1120","id":"49013a3d-363b-4349-89d5-8c5e11d8cdf6","issue":"10","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"bd568c56-2d83-41d4-856a-70b671030e7d","keyword":"葡萄糖","originalKeyword":"葡萄糖"},{"id":"e63b0a65-b67b-420e-a6b3-45aa355e3b33","keyword":"烷基-β-<span style=\"color:red\">D-</span>吡喃葡萄糖苷","originalKeyword":"烷基-β-D-吡喃葡萄糖苷"},{"id":"fd8fec9f-fb01-4b08-8b16-21927cfb9ce6","keyword":"发泡","originalKeyword":"发泡"},{"id":"d06405e4-da62-457d-9ac7-a5fd308e32d1","keyword":"乳化","originalKeyword":"乳化"},{"id":"b74f57ca-cdf0-47da-9c5d-77934bac18e8","keyword":"热致液晶","originalKeyword":"热致液晶"}],"language":"zh","publisherId":"yyhx201310004","title":"烷基-β-<span style=\"color:red\">D-</span>吡喃葡萄糖苷的合成与性能","volume":"30","year":"2013"},{"abstractinfo":"根据关拉德反应(Maillard reaction)原理,以<span style=\"color:red\">D-</span>核糖为交联剂,氨水为pH调节剂,对胶原膜交联条件进行优化.对交联的胶原膜与未交联胶原膜进行XPS、IR、AFM、SEM表征,进一步考察了<span style=\"color:red\">D-</span>核糖与甲醛分别交联得到的胶原膜对I型胶原酶的耐受性.研究结果表明,在对酶的耐受性方面经<span style=\"color:red\">D-</span>核糖交联的胶原膜等同于甲醛交联的胶原膜.","authors":[{"authorName":"史佳巍","id":"f14ad74e-6d32-4559-901d-670c81da3ed1","originalAuthorName":"史佳巍"},{"authorName":"李学敏","id":"ce035b0b-5bd2-4325-87c2-7ee846adf8e9","originalAuthorName":"李学敏"},{"authorName":"刘玲蓉","id":"ddadae3f-893b-4caa-b522-a78efabaeb39","originalAuthorName":"刘玲蓉"},{"authorName":"关嫚","id":"4f04b174-4a7b-488a-8d6a-704f4e9afb2e","originalAuthorName":"关嫚"},{"authorName":"张其清","id":"bad20fe3-114d-408a-aa02-12e75394ac71","originalAuthorName":"张其清"}],"doi":"","fpage":"1013","id":"5f194461-fb40-4fb5-b577-ba4928fd115e","issue":"6","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"ca8a107c-edb1-471d-ae9a-e5fbced85cf3","keyword":"胶原膜","originalKeyword":"胶原膜"},{"id":"0274b519-f29a-4439-90b1-a72ad187b847","keyword":"交联剂","originalKeyword":"交联剂"},{"id":"9fbf8d4e-877f-4299-9caf-38d6897d0868","keyword":"<span style=\"color:red\">D-</span>核糖","originalKeyword":"D-核糖"},{"id":"5b37aea7-abbc-4356-8e28-edf9fff1382f","keyword":"美拉德反应","originalKeyword":"美拉德反应"}],"language":"zh","publisherId":"gncl200906039","title":"<span style=\"color:red\">D-</span>核糖交联胶原膜的性质研究","volume":"40","year":"2009"},{"abstractinfo":"报道了两种<span style=\"color:red\">D-</span>π-A<span style=\"color:red\">结构</span>的化合物,通过红外、元素分析、核磁及单晶X衍射对化合物的<span style=\"color:red\">结构</span>进行了表征.用Nd∶YAG脉冲激光器通过Z扫描技术研究了它们的三阶非线性光学特性.结果表明在532nm的激光作用下,不仅表现出显著的非线性光学折射率,而且表现出有大的非线性光学吸收系数.","authors":[{"authorName":"马文","id":"a71c71f8-1caa-40b0-ade8-819e4d8c0049","originalAuthorName":"马文"},{"authorName":"陈鹤平","id":"70349834-7341-44b2-bb4b-3f13819989a8","originalAuthorName":"陈鹤平"},{"authorName":"于文涛","id":"3ea903e4-3b5f-4acd-bc1d-5530baadb487","originalAuthorName":"于文涛"},{"authorName":"张胜义","id":"e9b09edb-8469-4e27-ba4f-2a43f677d2a4","originalAuthorName":"张胜义"},{"authorName":"吴杰颖","id":"fab260d2-19ef-4a92-8a14-5789982bc9ab","originalAuthorName":"吴杰颖"},{"authorName":"田玉鹏","id":"53d61608-20bc-4189-bf57-0135f53afaf8","originalAuthorName":"田玉鹏"},{"authorName":"蒋民华","id":"00391c08-a951-42dd-acb1-3861c1d91753","originalAuthorName":"蒋民华"}],"doi":"","fpage":"101","id":"279b574b-5c36-4563-95d7-69d2828332f4","issue":"1","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"d8a9a5fa-5546-4c82-85d0-d39b24d99aaa","keyword":"单晶<span style=\"color:red\">结构</span>","originalKeyword":"单晶结构"},{"id":"33fd52ab-7715-492c-91d0-81348abb0645","keyword":"<span style=\"color:red\">D-</span>π-A<span style=\"color:red\">结构</span>化合物","originalKeyword":"D-π-A结构化合物"},{"id":"76ba358f-76a1-4b6f-8b3d-f6d68b158664","keyword":"三阶非线性光学特性","originalKeyword":"三阶非线性光学特性"}],"language":"zh","publisherId":"gncl200401035","title":"两种具有<span style=\"color:red\">D-</span>π-A<span style=\"color:red\">结构</span>化合物的合成、表征及三阶非线性光学特性","volume":"35","year":"2004"},{"abstractinfo":"针对目前国内工业上生产<span style=\"color:red\">d-</span>酒石酸方法的缺点,提出了以<span style=\"color:red\">d-</span>酒石酸钠为原料用电渗析生产<span style=\"color:red\">d-</span>酒石酸的方法.该法操作简单,技术可靠,得到的<span style=\"color:red\">d-</span>酒石酸产品质量分数99.5%以上,回收率95%,生产1t纯<span style=\"color:red\">d-</span>酒石酸晶体,电耗约2 000 kWh.对电渗析由<span style=\"color:red\">d-</span>酒石酸钠生产<span style=\"color:red\">d-</span>酒石酸方法与旧法作了简单的经济比较后认为,该法可用于工业生产.","authors":[{"authorName":"葛道才","id":"e657b2aa-d62d-4e84-a569-fd9736341666","originalAuthorName":"葛道才"},{"authorName":"迟仁清","id":"2d6f8dbb-85a2-44af-969f-7453bcc08ebc","originalAuthorName":"迟仁清"}],"doi":"10.3969/j.issn.1007-8924.2003.05.008","fpage":"32","id":"89085dd1-3f4b-49b2-be01-2eab98ab6192","issue":"5","journal":{"abbrevTitle":"MKXYJS","coverImgSrc":"journal/img/cover/MKXYJS.jpg","id":"54","issnPpub":"1007-8924","publisherId":"MKXYJS","title":"膜科学与技术   "},"keywords":[{"id":"03a753c1-5d03-4284-aec1-5142af1a55ff","keyword":"均相离子交换膜","originalKeyword":"均相离子交换膜"},{"id":"dc738dae-82a1-4cb4-8035-a70198c5ffb2","keyword":"电渗析","originalKeyword":"电渗析"},{"id":"3a12009f-81b9-4c36-a44e-aff16ecea79f","keyword":"<span style=\"color:red\">d-</span>酒石酸","originalKeyword":"d-酒石酸"}],"language":"zh","publisherId":"mkxyjs200305008","title":"电渗析法由<span style=\"color:red\">d-</span>酒石酸钠直接生产<span style=\"color:red\">d-</span>酒石酸的新工艺","volume":"23","year":"2003"},{"abstractinfo":"以<span style=\"color:red\">D-</span>葡萄糖为原料，经全乙酰化、在SnCl 4催化下与脂肪醇糖苷化、脱保护3步反应合成了7种不同碳链长度的烷基-α-<span style=\"color:red\">D-</span>吡喃葡萄糖苷。利用核磁共振、表面张力仪和偏光显微镜等对其进行<span style=\"color:red\">结构</span>、表面张力和热致液晶等性能测试，结果表明，当烷基-α-<span style=\"color:red\">D-</span>吡喃葡萄糖苷烷基链长（ n）为6～9时，均有发泡和乳化性能，其中正壬基-α-<span style=\"color:red\">D-</span>吡喃葡萄糖苷具有最佳的发泡和乳化性能；烷基糖苷（n＝6～9）的表面张力（γCMC）及临界胶束浓度（CMC）均比较低；饱和吸附量（Γmax）随烷基链的增长而减小，饱和吸附面积（Amin）随烷基链增长而增大；形成胶束时的标准自由能（ΔGmic ）和吸附自由能（ΔGads ）均为负值，其绝对值随烷基链增长而越来越大，其中正辛基-α-<span style=\"color:red\">D-</span>吡喃葡萄糖苷的表面活性最好；烷基糖苷（n＝4～9）对皮肤均无急性刺激作用；所合成的烷基糖苷均具有热致液晶行为，随烷基链长的增加，液晶相的温度范围变宽，液晶相的稳定性越好。","authors":[{"authorName":"李贞操","id":"2d5594f7-8525-40d2-8217-0351e452778c","originalAuthorName":"李贞操"},{"authorName":"陈国勇","id":"29abcb5f-1480-46f3-8622-ea8547bb7566","originalAuthorName":"陈国勇"},{"authorName":"陈朗秋","id":"cfc778ee-62ab-45de-ab4b-29ba8837cf00","originalAuthorName":"陈朗秋"},{"authorName":"申望珍","id":"b1c3e3d8-0259-41e8-aed8-a285488c71d2","originalAuthorName":"申望珍"},{"authorName":"季善伟","id":"0e9c74f5-2170-467b-b75f-79251af8c0d0","originalAuthorName":"季善伟"}],"doi":"10.11944/j.issn.1000-0518.2016.11.160017","fpage":"1265","id":"8f6ee1a7-519a-4208-92c9-34c8f5c5b7be","issue":"11","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"987704fe-b704-4c14-b02b-8d3fce813d93","keyword":"<span style=\"color:red\">D-</span>葡萄糖","originalKeyword":"D-葡萄糖"},{"id":"a888c6ff-34e1-4d56-82a8-fa71f95f3e75","keyword":"烷基-α-<span style=\"color:red\">D-</span>吡喃葡萄糖苷","originalKeyword":"烷基-α-D-吡喃葡萄糖苷"},{"id":"8f625f88-e00c-4950-9469-b9ea8f0b0484","keyword":"SnCl4","originalKeyword":"SnCl4"},{"id":"c7d2534b-b014-414d-bb73-9b12cc8430f1","keyword":"表面性能","originalKeyword":"表面性能"},{"id":"9659bc3c-5f52-4743-83bd-f4bcd162649e","keyword":"热致液晶","originalKeyword":"热致液晶"}],"language":"zh","publisherId":"yyhx201611006","title":"烷基-α-<span style=\"color:red\">D-</span>吡喃葡萄糖苷的合成与性能","volume":"33","year":"2016"},{"abstractinfo":"以五苄基-<span style=\"color:red\">D-</span>甘露糖为原料,经Wittig反应制得<span style=\"color:red\">D-</span>甘露庚糖烯(产率88％),然后在二乙酰氧基亚碘酰苯/LiBr体系下催化氧化糖基烯制得五苄基-<span style=\"color:red\">D-</span>甘露庚糖醇(产率65％),最后脱苄基得到<span style=\"color:red\">D-</span>甘露庚糖醇(产率90％),总得率51％.方法简便、环保,可用于糖醇的合成.","authors":[{"authorName":"程杰","id":"b88ce34f-572e-4763-b913-1b6ad59042c0","originalAuthorName":"程杰"},{"authorName":"翟洪","id":"e56b4b41-30ec-423b-b139-c053e1fb08d4","originalAuthorName":"翟洪"},{"authorName":"柏俊","id":"c41f2fc8-d543-4e0f-be1f-53ac2adb17e0","originalAuthorName":"柏俊"},{"authorName":"吕凌","id":"948b25a8-d77d-4a65-9a7d-6607ff7dbd92","originalAuthorName":"吕凌"},{"authorName":"孙备","id":"b5c4dc2a-4a22-4487-b742-bbba793466c6","originalAuthorName":"孙备"}],"doi":"10.3724/SP.J.1095.2012.00253","fpage":"483","id":"da22166a-72a1-4604-b74d-131a01a1ecd5","issue":"4","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"eddafbd4-90c0-4a0c-82e3-f2f59bc49df1","keyword":"<span style=\"color:red\">D-</span>甘露庚糖醇","originalKeyword":"D-甘露庚糖醇"},{"id":"70b6bbae-be63-4f7b-a24d-50c6a68855e0","keyword":"糖基烯","originalKeyword":"糖基烯"},{"id":"07914e9f-927a-4217-920c-ba238a6b2742","keyword":"二乙酰氧基亚碘酰苯","originalKeyword":"二乙酰氧基亚碘酰苯"},{"id":"ba653fa9-1c4b-4835-b31a-4757937c53f4","keyword":"双羟基化反应","originalKeyword":"双羟基化反应"}],"language":"zh","publisherId":"yyhx201204019","title":"二乙酰氧基亚碘酰苯氧化糖基烯合成<span style=\"color:red\">D-</span>甘露庚糖醇","volume":"29","year":"2012"}],"totalpage":6532,"totalrecord":65311}