{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"采用聚醋酸乙烯酯(PVAc)醇解的方法制备出了不同醇解度的聚乙烯醇(PVA).以丙烯酰胺(AM)和<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>性功能单体Macromer为共聚单体,通过自由基水溶液<span style=\"color:red\">聚合</span>方法制备出了二元<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>水溶性共聚<span style=\"color:red\">物</span>P(AM-Macromer).研究了PVA、P(AM-Macromer)及其复合溶液的性能.结果表明,P(AM-Macromer)溶液具有<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>性.PVA溶液黏度随温度的变化规律与其结构有关.PVA与P(AM-Macromer)复合效应明显,该复合溶液具有盐增稠和升温增粘的特性,溶液的弹性随温度的升高而增强;不具备升温增粘效应的高醇解度PVA与P(AM-Macromer)复合具有升温增粘的效应.醇解度较低的PVA与P(AM-Macromer)复合后,溶液出现升温增粘效应的温度明显降低.","authors":[{"authorName":"朱莉","id":"e4ea5c1a-dfb8-4215-9b34-1aa933dbbc46","originalAuthorName":"朱莉"},{"authorName":"李昱","id":"37a28b59-89da-4687-8130-c4b8e755c7a0","originalAuthorName":"李昱"},{"authorName":"张熙","id":"754c0ca2-d54a-4192-acfd-440fdd4ed40f","originalAuthorName":"张熙"},{"authorName":"张晓飞","id":"fffadd93-c7da-4457-906a-388c9fba3f74","originalAuthorName":"张晓飞"},{"authorName":"代华","id":"4d7df33a-275f-4b76-832d-6e22b5d6addb","originalAuthorName":"代华"}],"doi":"","fpage":"68","id":"598d3ea1-a611-46b8-a618-d4a475133604","issue":"5","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"1f124a88-107e-4780-834c-d0a2cd33e556","keyword":"聚乙烯醇","originalKeyword":"聚乙烯醇"},{"id":"413c551d-4368-40f5-ab71-d6a69e06b5f9","keyword":"<span style=\"color:red\">聚合物</span>复合溶液","originalKeyword":"聚合物复合溶液"},{"id":"90d2871c-ca85-4353-9935-6cb89588df70","keyword":"<span style=\"color:red\">温</span><span style=\"color:red\">敏</span><span style=\"color:red\">聚合物</span>","originalKeyword":"温敏聚合物"},{"id":"72c9ffb4-7ac7-4f33-8b07-b57c45fddc77","keyword":"<span style=\"color:red\">聚合物</span>水溶液","originalKeyword":"聚合物水溶液"},{"id":"45fbbfe5-266b-453f-8a87-604954f10953","keyword":"流变性","originalKeyword":"流变性"}],"language":"zh","publisherId":"gfzclkxygc200805017","title":"<span style=\"color:red\">温</span><span style=\"color:red\">敏</span><span style=\"color:red\">聚合物</span>/聚乙烯醇复合溶液的性能","volume":"24","year":"2008"},{"abstractinfo":"采用实验室自制的疏水单体对正辛基苯乙烯(OBS)、<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>单体N,N-二乙基丙烯酰胺(DEAM)及亲水单体丙烯酰胺(AM),利用氧化-还原胶束<span style=\"color:red\">聚合法共聚合</span>成<span style=\"color:red\">温</span><span style=\"color:red\">敏</span><span style=\"color:red\">聚合物</span>,并对产物进行红外光谱、核磁共振结构表征,结果表明合成产物为目标<span style=\"color:red\">聚合物</span>.研究了<span style=\"color:red\">聚合物</span>溶液的温度敏感性,在不同盐浓度(NaCl,CaGl2)中的敏感性及与阴离子表面活性剂的复合效应;<span style=\"color:red\">聚合物</span>溶液随温度的升高黏度出现先增加后降低再增加的变化特点,在45℃黏度达到了最大值;<span style=\"color:red\">聚合物</span>溶液随着NaCl浓度增加,黏度逐渐增加再逐渐下降又上升的特点,最大黏度处NaCl浓度为10000 mg/L;随着CaCl2浓度的增加,出现黏度逐渐增加又下降的特点,最大黏度处为CaCl2浓度500 mg/L;阴离子表面活性剂和<span style=\"color:red\">聚合物</span>溶液复合后溶液黏度增加,而且相同浓度的表面活性剂对溶液表观黏度的贡献为:十二烷基硫酸钠＞十二烷基磺酸钠＞十二烷基苯磺酸钠.","authors":[{"authorName":"马超","id":"879ad91e-d9b2-4870-b1a8-5a58a4045bcf","originalAuthorName":"马超"},{"authorName":"万刚","id":"6829de4a-291a-4b4b-a3f6-17ac91118f36","originalAuthorName":"万刚"},{"authorName":"张熙","id":"448dedf0-f7f1-4d12-a203-a611eef83b51","originalAuthorName":"张熙"}],"doi":"10.16865/j.cnki.1000-7555.2016.11.006","fpage":"28","id":"ca71d061-2a01-433e-8701-b0523dbe5ab1","issue":"11","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"1041b84e-66c0-43d0-a884-ee83ce8c3624","keyword":"正辛基苯乙烯","originalKeyword":"正辛基苯乙烯"},{"id":"0ead0652-ab39-4a2c-a3bb-151a038aafbb","keyword":"疏水单体","originalKeyword":"疏水单体"},{"id":"579e0068-7ee3-4c72-8b54-d2a45a216b04","keyword":"胶束<span style=\"color:red\">聚合</span>","originalKeyword":"胶束聚合"},{"id":"f5bfff60-6e38-40b0-bc5d-3739f926993f","keyword":"<span style=\"color:red\">温</span><span style=\"color:red\">敏</span><span style=\"color:red\">聚合物</span>","originalKeyword":"温敏聚合物"},{"id":"9edb7623-8a43-47d9-926f-379607f04708","keyword":"表面活性剂","originalKeyword":"表面活性剂"}],"language":"zh","publisherId":"gfzclkxygc201611006","title":"<span style=\"color:red\">温</span><span style=\"color:red\">敏</span><span style=\"color:red\">聚合物</span>正辛基苯乙烯/N,N-二乙基丙烯酰胺/丙烯酰胺合成及溶液性能","volume":"32","year":"2016"},{"abstractinfo":"以含氧乙基结构的烯类单体(Macromer)和丙烯酰胺(AM)为原料,制备了具有温度敏感性的疏水缔合水溶性共聚<span style=\"color:red\">物</span>P(AM-Macromer).研究了P(AM-Macromer)溶液与不同表面活性剂的相互作用.结果表明,P(AM-Macromer)在水溶液中与表面活性剂存在明显相互作用,复合效应与<span style=\"color:red\">聚合物</span>浓度、表面活性剂结构及浓度有关.在较高浓度<span style=\"color:red\">聚合物</span>溶液中,少量表面活性剂的加入能显著提高溶液的黏度;在低浓度<span style=\"color:red\">聚合物</span>溶液中,表面活性剂的加入使溶液表观黏度下降.表面活性剂对共聚<span style=\"color:red\">物</span>P(AM-Macromer)溶液黏度的影响强弱顺序为:SDBSCTABOP-10.","authors":[{"authorName":"胡静","id":"946b0c75-3cef-4b88-a6d3-5139f1893a86","originalAuthorName":"胡静"},{"authorName":"张晓飞","id":"b8b20465-26b6-4e19-aa6e-28aa26c28a2c","originalAuthorName":"张晓飞"},{"authorName":"张熙","id":"236be63c-1a83-47d0-b25b-8b2966cff534","originalAuthorName":"张熙"},{"authorName":"代华","id":"0802f636-a787-44e4-bc95-24e67cabe4fa","originalAuthorName":"代华"}],"doi":"","fpage":"82","id":"5eeb3b8d-7da1-4f4f-a992-564f0c469cc9","issue":"8","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"d6714e6b-f3da-4084-93f6-657757ef999a","keyword":"<span style=\"color:red\">温</span><span style=\"color:red\">敏</span><span style=\"color:red\">聚合物</span>","originalKeyword":"温敏聚合物"},{"id":"f1257659-d108-45ff-872c-7e59a03a4618","keyword":"表面活性剂","originalKeyword":"表面活性剂"},{"id":"d2336859-f75a-480d-b08a-f8044003c7d3","keyword":"表观黏度","originalKeyword":"表观黏度"},{"id":"06410fb3-679b-4321-87d6-eb34b36d433f","keyword":"流变性","originalKeyword":"流变性"}],"language":"zh","publisherId":"gfzclkxygc200808021","title":"<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>性<span style=\"color:red\">聚合物</span>P(AM-Macromer)及其与表面活性剂的复合性能","volume":"24","year":"2008"},{"abstractinfo":"利用溶液<span style=\"color:red\">聚合</span>法合成了一系列不同质量配比的N一异丙基丙烯酰胺(NIPA)/甲基丙烯酸甲酯(MMA)、甲基丙烯酸乙酯(MEA)或甲基丙烯酸丁酯(MBA)线型共聚<span style=\"color:red\">物</span>,用傅立叶红外光谱(FT-IR)和热重分析(TG)对共聚<span style=\"color:red\">物</span>进行了表征.采用紫外可见分光光度计(UV)测定了共聚<span style=\"color:red\">物</span>水溶液的低临界溶解温度(LCST),研究表明,通过改变共聚单体的配比LCST可在18～32℃范围内调节.对<span style=\"color:red\">聚合物</span>水溶液进行UV测试发现,共聚<span style=\"color:red\">物</span>水溶液在LCST附近光透过率变化显著,共聚<span style=\"color:red\">物</span>水溶液在LCST温度之上为白浊状态而在该温度下为清澈透明状,在LCST以下,溶液的透光率受到浓度、单体投料比等因素影响.该变化过程呈现可逆性,且变化迅速,灵敏性高,重复性好,在智能调光材料领域有广泛的应用前景.","authors":[{"authorName":"丁萍萍","id":"64fd6355-57f2-473d-a677-d16799abe08b","originalAuthorName":"丁萍萍"},{"authorName":"傅相锴","id":"91c563cb-fc07-4e46-9609-f4b9322a8f31","originalAuthorName":"傅相锴"},{"authorName":"陈祝君","id":"5ace7a5b-5f31-48f1-823d-57fb7b76e1c8","originalAuthorName":"陈祝君"},{"authorName":"涂小波","id":"776277e1-b51a-47d7-acd3-c64c263cde71","originalAuthorName":"涂小波"}],"doi":"","fpage":"663","id":"0513fd17-9d34-40a7-ad80-51c0e9579892","issue":"4","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"d2d08801-c3c8-4792-a3ec-402cf9192973","keyword":"聚(N一异丙基丙烯酰胺/甲基丙烯酸酯)","originalKeyword":"聚(N一异丙基丙烯酰胺/甲基丙烯酸酯)"},{"id":"5e6c6c5c-e865-4ca3-8f4e-aa9f1646f665","keyword":"共聚<span style=\"color:red\">物</span>水溶液","originalKeyword":"共聚物水溶液"},{"id":"a2949501-0ef0-470b-87a4-07f4114deb21","keyword":"LCST温度","originalKeyword":"LCST温度"},{"id":"bacd684e-8bc5-4146-a986-4211754830ff","keyword":"<span style=\"color:red\">温</span><span style=\"color:red\">敏</span><span style=\"color:red\">聚合物</span>","originalKeyword":"温敏聚合物"},{"id":"489af7b6-830c-4d2a-b2d2-61e30c9c2901","keyword":"调光材料","originalKeyword":"调光材料"}],"language":"zh","publisherId":"gncl200904040","title":"N-异丙基丙烯酰胺-甲基丙烯酸酯类共聚<span style=\"color:red\">物</span><span style=\"color:red\">温</span><span style=\"color:red\">敏</span>性能及应用的研究","volume":"40","year":"2009"},{"abstractinfo":"本文通过对甲壳素脱乙酰制得壳聚糖,并利用“冷冻爆破法”制备了壳聚糖溶液,在该溶液体系中采用环氧丙烷作为醚化剂,在碱催化下与壳聚糖进行反应,成功地在均相反应体系中制备了羟丙基壳聚糖.利用核磁共振氢谱(1 H-NMR)和傅里叶变换红外光谱(FT-IR)表征了产物的结构,并利用紫外可见分光光度计(UV-vis)测试了羟丙基壳聚糖的<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>性能.结果表明,壳聚糖脱乙酰度为75％左右,制备得到的羟丙基壳聚糖取代度(DS)为2.47,具有可逆的温度响应性.","authors":[{"authorName":"江志强","id":"530f58b1-80ca-4e72-a42e-ec53644d4355","originalAuthorName":"江志强"},{"authorName":"王征科","id":"e75abb62-c69b-4019-ad0a-fed28fc91c57","originalAuthorName":"王征科"},{"authorName":"张柯","id":"9bad784d-98f6-4a76-a17b-0cd7d48d0d47","originalAuthorName":"张柯"},{"authorName":"李友良","id":"4d490a3a-f4be-4d6a-9636-5a823fe25298","originalAuthorName":"李友良"},{"authorName":"胡巧玲","id":"befa032a-fe75-4d84-8a00-e4426d650f3e","originalAuthorName":"胡巧玲"}],"doi":"","fpage":"687","id":"81668857-4ba7-4f1b-93e9-82caf801c4cc","issue":"5","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"11ccebbf-8dcb-40ab-9a30-293b6e4bd2cc","keyword":"羟丙基壳聚糖","originalKeyword":"羟丙基壳聚糖"},{"id":"d08751ab-587a-40da-9998-1d8a30dbd87d","keyword":"<span style=\"color:red\">温</span><span style=\"color:red\">敏</span><span style=\"color:red\">聚合物</span>","originalKeyword":"温敏聚合物"},{"id":"a690bfd9-b4ab-41bc-9010-77f9047f3535","keyword":"均相反应","originalKeyword":"均相反应"},{"id":"34a7688f-8d9e-42c4-b4c2-22065a0e8d0f","keyword":"氢氧化锂","originalKeyword":"氢氧化锂"}],"language":"zh","publisherId":"clkxygc201305014","title":"<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>性羟丙基壳聚糖的制备及其性能","volume":"31","year":"2013"},{"abstractinfo":"基于纤维素的水凝胶用途广泛,但其溶胀调控规律少见报道.文中以羟丙基甲基纤维素(HPMC)和羟乙基纤维素(HEC)为原料,以环氧氯丙烷(ECH)为交联剂,制备了系列纤维素基<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>水凝胶,研究了在温度作用下HPMC及ECH含量、pH、无机盐对水凝胶溶胀性能的影响.结果表明,制备的纤维素基水凝胶具有随温度变化可调的溶胀性能;HPMC含量越高,水凝胶收缩能力越强;ECH含量越高,水凝胶收缩能力越弱;达到溶胀平衡的水凝胶具有良好的力学性能以及pH和无机盐稳定性.","authors":[{"authorName":"程金梁","id":"48e89caa-a9af-44a3-837a-3ed05496b1b7","originalAuthorName":"程金梁"},{"authorName":"殷鸿尧","id":"3547b694-1ca9-483c-b1dc-1762c1ea9d18","originalAuthorName":"殷鸿尧"},{"authorName":"冯玉军","id":"e2cfa874-0f11-45d7-bed2-bbe9c4b2c86b","originalAuthorName":"冯玉军"},{"authorName":"全红平","id":"6f4faf8a-8c0a-4141-b48c-c812e7f2d6ee","originalAuthorName":"全红平"}],"doi":"10.16865/j.cnki.1000-7555.2016.06.023","fpage":"118","id":"93d3a5b5-053d-4cdd-af00-ffcf13596d9f","issue":"6","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"ace9370e-a1a9-4686-a98f-1c09f0ea81b4","keyword":"<span style=\"color:red\">温</span><span style=\"color:red\">敏</span><span style=\"color:red\">聚合物</span>","originalKeyword":"温敏聚合物"},{"id":"3d1c9b62-be46-49ba-9302-37100a715114","keyword":"羟丙基甲基纤维素","originalKeyword":"羟丙基甲基纤维素"},{"id":"7ea507fd-ae8b-4d63-9081-56559c97d09e","keyword":"水凝胶","originalKeyword":"水凝胶"},{"id":"6745e273-a8d3-469e-a3eb-f9a66e2b30ee","keyword":"溶胀性能","originalKeyword":"溶胀性能"}],"language":"zh","publisherId":"gfzclkxygc201606023","title":"具有可调溶胀性能的纤维素基<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>水凝胶","volume":"32","year":"2016"},{"abstractinfo":"利用聚甲基丙烯酸甲酯(PMMA)包覆空心Fe3O4磁粒制备了<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>性Fe3O4@PMMA复合粒子,并采用对氨基水杨酸(Mr=153.14)作为模拟负载药物,考察了不同温度与pH对复合粒子的接枝、包覆、载药与控释的影响.载药与控释研究结果表明,磁粒空心结构及PMMA膜与药物之间的氢键作用与<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>效应,显著提高了药物负载量,每0.0100g复合磁粒可负载1468μg(0.959×10-5 mol)药物.同时,超过80％的药物在3h～4h内释放,具有局部高浓度药物释放性能,并且药物最大释放量与时间呈线性关系.这种复合空心磁粒载药体系的构建有效提高了药物负载效率,配合磁靶向性能,将在癌症载药治疗方面展现巨大的应用前景.","authors":[{"authorName":"贺全国","id":"9a43bd45-2fc2-46c2-845b-fc1568937407","originalAuthorName":"贺全国"},{"authorName":"黄春艳","id":"69db14bc-b7a0-43d2-9e71-16ab4b73169e","originalAuthorName":"黄春艳"},{"authorName":"刘军","id":"6f948e2a-6441-49c0-ab42-1e6608863310","originalAuthorName":"刘军"},{"authorName":"吴朝辉","id":"138f7766-d2c4-4462-931c-562f07dca5e0","originalAuthorName":"吴朝辉"}],"doi":"","fpage":"63","id":"917bba78-def3-4316-8583-ab18d12e1065","issue":"8","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"ce380c16-73c5-4408-9d91-addfca10afff","keyword":"空心Fe3O4纳米粒子","originalKeyword":"空心Fe3O4纳米粒子"},{"id":"2020dbe5-8d79-4394-baf5-ac2ec73c597a","keyword":"Fe3O4@PMMA复合粒子","originalKeyword":"Fe3O4@PMMA复合粒子"},{"id":"8dc35f64-52be-4645-9e3b-e89b2c5c3ed8","keyword":"<span style=\"color:red\">温</span><span style=\"color:red\">敏</span><span style=\"color:red\">聚合物</span>","originalKeyword":"温敏聚合物"},{"id":"41d8fd3d-ad8c-48d8-a609-1d745eb88829","keyword":"药物负载率","originalKeyword":"药物负载率"},{"id":"81e835fd-af22-44f5-8c10-cf7947305e72","keyword":"药物释放量","originalKeyword":"药物释放量"}],"language":"zh","publisherId":"gfzclkxygc201308016","title":"<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>聚甲基丙烯酸甲酯包覆空心Fe3O4纳米粒子的载药控释性能","volume":"29","year":"2013"},{"abstractinfo":"基于二维相关光谱的多维分子光谱技术是近些年发展起来的先进光谱分析手段，特别适合于在分子水平上研究各种外扰作用下的物理化学体系的结构变化.本文就二维相关光谱及其衍生的外扰相关移动窗口技术对<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>水溶性<span style=\"color:red\">聚合物</span>体系尤其是LCST型<span style=\"color:red\">聚合物</span>体系的研究进展进行了综述.LCST型<span style=\"color:red\">聚合物</span>水溶液在LCST（低临界溶解温度）变化前后会发生线团－胶束的分子链构象变化，而在凝胶体系内则表现为体积的塌缩与溶胀.红外光谱可以很好地跟踪这一温度变化的过程，而一维及二维相关光谱分析可以方便地确定相转变温度、转变温度区间、响应程度及各基团的响应次序，非常有助于诠释<span style=\"color:red\">温</span><span style=\"color:red\">敏</span><span style=\"color:red\">聚合物</span>体系的响应机制.本文综述了二维相关光谱分析在LCST型均聚<span style=\"color:red\">物</span>、共聚<span style=\"color:red\">物</span>和共混<span style=\"color:red\">物</span>、凝胶以及<span style=\"color:red\">聚合物</span>刷体系中的典型应用.","authors":[{"authorName":"孙胜童","id":"c3efd46f-44ba-4894-afc0-3ec748790de6","originalAuthorName":"孙胜童"},{"authorName":"武培怡","id":"cdad67c3-9ab9-4d8f-8b79-08e8916cfdc6","originalAuthorName":"武培怡"}],"doi":"10.11951/j.issn.1005-0299.20160386","fpage":"1","id":"5a7e874e-363d-4105-8e7d-db29bee56110","issue":"1","journal":{"abbrevTitle":"CLKXYGY","coverImgSrc":"journal/img/cover/CLKXYGY.jpg","id":"14","issnPpub":"1005-0299","publisherId":"CLKXYGY","title":"材料科学与工艺"},"keywords":[{"id":"256615be-e172-4a27-9039-62a23c38a61b","keyword":"<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>水溶性<span style=\"color:red\">聚合物</span>","originalKeyword":"温敏水溶性聚合物"},{"id":"449fde73-ccc0-41b1-a8c0-1c59a616f841","keyword":"LCST","originalKeyword":"LCST"},{"id":"ac926d05-7e7d-4fe3-825d-01c497537219","keyword":"相转变","originalKeyword":"相转变"},{"id":"b041192f-a516-423b-8ab8-c7860de22819","keyword":"二维相关光谱","originalKeyword":"二维相关光谱"},{"id":"23f5ce35-ab07-4f90-bf6a-399a1088a504","keyword":"外扰相关移动窗口","originalKeyword":"外扰相关移动窗口"}],"language":"zh","publisherId":"clkxygy201701001","title":"<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>水溶性<span style=\"color:red\">聚合物</span>的二维分子光谱表征","volume":"25","year":"2017"},{"abstractinfo":"利用链转移自由基<span style=\"color:red\">聚合</span>制得了端羟基化的聚N,N-二乙基丙烯酰胺（PDEAm-OH）低聚<span style=\"color:red\">物</span>,进而与丙烯酰氯缩合得到<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>性的PDEAm大分子单体,利用FT-IR、1 H NMR和UV对该大分子单体的结构、末端双键含量和<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>性进行了表征,测得该大分子单体的最低临界溶解温度（LCST）为36.4℃。将PDEAm大分子单体与丙烯腈（AN）、苯乙烯（St）在乙醇/水混合介质中进行三元分散共聚,制得了PDEAm接枝聚丙烯腈/聚苯乙烯（PDEAm-g-PAN/PSt）<span style=\"color:red\">聚合物</span>微球,由扫描电子显微镜SEM观察到的结果表明,<span style=\"color:red\">聚合物</span>微球表面具有明显的突起形态,其粒径均一,分散稳定性好,改变<span style=\"color:red\">聚合</span>反应条件可控制所得<span style=\"color:red\">聚合物</span>微球的形貌和粒径。该<span style=\"color:red\">聚合物</span>微球的粒径随温度的升高而减小,表明其具有温度敏感性。","authors":[{"authorName":"隋静","id":"7345fc05-8ebf-45cb-a03d-bf49821d04ab","originalAuthorName":"隋静"},{"authorName":"胡娜","id":"2289cdc4-0949-421e-a5d8-e67b988dbfd3","originalAuthorName":"胡娜"},{"authorName":"施冬健","id":"a33667ed-13fd-41c2-a421-fe0a13e21115","originalAuthorName":"施冬健"},{"authorName":"尚跃再","id":"416a3c5d-5211-4d8c-b9c3-15f09ed4678e","originalAuthorName":"尚跃再"},{"authorName":"陈明清","id":"a82894e5-694e-42b7-9510-168e1dbfdfb5","originalAuthorName":"陈明清"}],"doi":"","fpage":"133","id":"9c8a5354-355b-489e-a9bf-417dca50a3f8","issue":"1","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"8ee5cfe4-5e6d-48fe-8c3e-ffd0f479d7d2","keyword":"大分子单体","originalKeyword":"大分子单体"},{"id":"ecc5465b-b764-4692-83d1-69e56c2ced8a","keyword":"<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>性","originalKeyword":"温敏性"},{"id":"c940eb0f-8c25-4dcd-9a93-eb07341e1b93","keyword":"分散共聚","originalKeyword":"分散共聚"},{"id":"875de987-31a6-46e2-b9eb-33103f54b387","keyword":"<span style=\"color:red\">聚合物</span>微球","originalKeyword":"聚合物微球"}],"language":"zh","publisherId":"gncl201201036","title":"PDEAm接枝PAN/PSt<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>性<span style=\"color:red\">聚合物</span>微球的制备及表征","volume":"43","year":"2012"},{"abstractinfo":"以4-氯-7-硝基-2,1,3-苯并口恶唑（NBD-Cl）为原料,首先合成了荧光单体4-（2-丙烯酸胺乙基酯）-7-硝基-2,1,3-苯并口恶唑（NBDAE）,然后以2-溴异丁酸乙酯（t-EBiB）为引发剂,CuCl/Me6TREN为催化剂,采用原子转移自由基<span style=\"color:red\">聚合</span>（ATRP）,与<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>性单体N-异丙基丙烯酰胺（NIPAM）共聚,得到水溶性无规共聚<span style=\"color:red\">物</span>P（NIPAM-co-NBDAE）。对产物进行了1H-NMR,GPC,UV-Vis及荧光光谱仪（FL）表征。结果表明,成功制备了多分散系数小于1.20的窄分布荧光水溶性共聚<span style=\"color:red\">物</span>,并研究了该<span style=\"color:red\">聚合物</span>荧光强度随温度的变化。在PNIPAM的相变温度（30℃）以下,该<span style=\"color:red\">聚合物</span>在水溶液中荧光较弱;而在PNIPAM的相变温度（30℃）以上,该<span style=\"color:red\">聚合物</span>的荧光强度随PNIPAM疏水转变而显著增强。","authors":[{"authorName":"马海红","id":"ca996701-6a93-46a3-8dbd-f1620cb248f9","originalAuthorName":"马海红"},{"authorName":"周正发","id":"3b5218f4-fe2e-45f0-b3d6-5ad2d8a48d0f","originalAuthorName":"周正发"},{"authorName":"汪枭睿","id":"902fe379-dcd8-4691-b243-46a6622a36cc","originalAuthorName":"汪枭睿"},{"authorName":"胡进明","id":"6ced3bba-f4d1-415d-8e19-7c9fe9e83f64","originalAuthorName":"胡进明"},{"authorName":"徐卫兵","id":"a5530f28-10a9-47de-bf54-a23fd625f3d4","originalAuthorName":"徐卫兵"}],"doi":"","fpage":"9","id":"5d0d2dee-c8e9-42ad-af30-40b40f4762d2","issue":"3","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"0da67d0b-40f7-424c-a2b1-cab84520f070","keyword":"原子转移自由基<span style=\"color:red\">聚合</span>","originalKeyword":"原子转移自由基聚合"},{"id":"58045599-9dba-4ca4-bd45-15e60ba643a4","keyword":"荧光<span style=\"color:red\">温</span><span style=\"color:red\">敏</span>","originalKeyword":"荧光温敏"},{"id":"269e05f6-59b5-4ace-a099-f3abea5ee644","keyword":"水溶性<span style=\"color:red\">聚合物</span>","originalKeyword":"水溶性聚合物"}],"language":"zh","publisherId":"gfzclkxygc201203003","title":"ATRP法制备水溶性荧光<span style=\"color:red\">温</span><span style=\"color:red\">敏</span><span style=\"color:red\">聚合物</span>P（NIPAM-co-NBDAE）","volume":"28","year":"2012"}],"totalpage":4602,"totalrecord":46020}