{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"研究了在HAc-NaAc-NH4Cl-柠檬酸钠-丁二酮肟-乳化剂OP体系中,用示波<span style=\"color:red\">极</span><span style=\"color:red\">谱</span>法测定锌电解液中的痕量钴.试验发现,加入适量的乳化剂OP,可使锌波峰电位向负方向移动,而对钴波峰电位几乎无影响,大大减弱了锌波对钴波的干扰.Co(Ⅱ)-丁二酮肟(DMG)络合物在-0.93V(vs.SCE)处,产生一灵敏的络合吸附波.钴浓度在0.0016～0.1μg/mL时,与峰电流有良好的线性关系,其检出限为1.2×10-6μg/mL.将本法应用于锌电解液中痕量钴的测定,方法简便、快速,结果令人满意.","authors":[{"authorName":"徐益军","id":"320340f3-66ad-42fe-935e-9652eededa14","originalAuthorName":"徐益军"},{"authorName":"唐有根","id":"601a5951-19b5-4b45-917f-ea9bc9e12703","originalAuthorName":"唐有根"},{"authorName":"杨幼平","id":"013257c5-243b-4da7-ad11-9903e4cea23a","originalAuthorName":"杨幼平"},{"authorName":"王艳","id":"a373e991-6514-4c74-a8d9-2cd84819e8bb","originalAuthorName":"王艳"}],"doi":"10.3969/j.issn.1000-7571.2003.01.001","fpage":"1","id":"2922bca0-7dfb-4c0c-b085-5d44c6ecfa90","issue":"1","journal":{"abbrevTitle":"YJFX","coverImgSrc":"journal/img/cover/YJFX.jpg","id":"71","issnPpub":"1000-7571","publisherId":"YJFX","title":"冶金分析   "},"keywords":[{"id":"aa8b5448-be67-4fe8-bda5-3fa86367e3e1","keyword":"<span style=\"color:red\">极</span><span style=\"color:red\">谱</span><span style=\"color:red\">法</span>","originalKeyword":"极谱法"},{"id":"b5d14d5c-c6e4-4f94-b9f4-5515b7fdc494","keyword":"锌电解液","originalKeyword":"锌电解液"},{"id":"d0f12172-e869-44df-9420-dfd90f5ef57b","keyword":"钴","originalKeyword":"钴"},{"id":"6951e073-a063-4a52-9490-e0a58eb15001","keyword":"乳化剂OP","originalKeyword":"乳化剂OP"}],"language":"zh","publisherId":"yjfx200301001","title":"示波<span style=\"color:red\">极</span><span style=\"color:red\">谱</span><span style=\"color:red\">法</span>快速测定锌电解液中痕量钴","volume":"23","year":"2003"},{"abstractinfo":"研究了在同一份试液中极<span style=\"color:red\">谱</span><span style=\"color:red\">法</span>连续测定Au、Pt、Ir、Rh、Ru的体系.首先在1 mol/L的氢氧化钠溶液中,于原点电位-0.20 V处扫描作Au的峰电流-质量浓度曲线;然后,改变溶液pH值,在0.75 mol/L硫酸-1.5 %氯化铵-1.5×10-3 mol/L六次甲基四胺-0.003 %硫酸肼体系中,于原点电位-0.78 V处扫描作Pt、Ir、Rh的峰电流-质量浓度曲线;最后,加入2.25 mol/L硫酸-4 %氯化铵-2.5×10-4 mol/L硫脲测定Ru.在选定的实验条件下得到令人满意的分析结果,线性范围分别为:0.1～1 000 μg/mL(Au);8×10-5～6.4×10-3 μg/mL(Pt、Ir);1.6×10-5～1.28×10-3 μg/mL(Rh);1.14×10-4～3.42×10-3 μg/mL(Ru).实际样品通过阴离子交换树脂分离富集后进行分析,回收率在93 %～106 %之间.","authors":[{"authorName":"张辉","id":"624dcfc7-8821-4ff4-bd8b-86039f1f0628","originalAuthorName":"张辉"},{"authorName":"唐杰","id":"e254b718-6a10-455e-ae4c-165140d0537c","originalAuthorName":"唐杰"},{"authorName":"张凯","id":"608f17ca-74fe-49a2-9ae2-4bde92f53f1c","originalAuthorName":"张凯"}],"doi":"10.3969/j.issn.1001-1277.2010.06.014","fpage":"57","id":"a9bb1d35-a629-480b-8f30-df82d8c7e2b3","issue":"6","journal":{"abbrevTitle":"HJ","coverImgSrc":"journal/img/cover/HJ.jpg","id":"44","issnPpub":"1001-1277","publisherId":"HJ","title":"黄金"},"keywords":[{"id":"50c0aa3d-af8f-47a9-a31a-7c6dd7c0bd63","keyword":"<span style=\"color:red\">极</span><span style=\"color:red\">谱</span><span style=\"color:red\">法</span>","originalKeyword":"极谱法"},{"id":"f0271145-8867-4eaf-9d9c-bd743a912cac","keyword":"分离富集","originalKeyword":"分离富集"},{"id":"9659acb3-4a4d-4f26-9a9a-50eab407b39e","keyword":"贵金属","originalKeyword":"贵金属"},{"id":"76018af3-0a39-4985-825c-a3dea14885f6","keyword":"连续测定","originalKeyword":"连续测定"}],"language":"zh","publisherId":"huangj201006014","title":"离子交换分离富集<span style=\"color:red\">极</span><span style=\"color:red\">谱</span><span style=\"color:red\">法</span>连续测定金、铂、铱、铑、钌","volume":"31","year":"2010"},{"abstractinfo":"研究了各种高锗物料中微量砷的催化<span style=\"color:red\">极</span>谱分析方法,若试样中存在大量Pb(Ⅱ),Cd(Ⅱ),Cu(Ⅱ)等干扰物质时,采用强碱分离.根据在H2SO4-Te（Ⅳ）-I--As(Ⅴ)催化<span style=\"color:red\">极</span><span style=\"color:red\">谱</span>测定体系中,锗无极<span style=\"color:red\">谱</span>活性的特点,不需分离锗而直接测定高锗物料中的微量砷,结果满意.","authors":[{"authorName":"梁云生","id":"64151fad-954d-436e-a3e1-3df80a89740f","originalAuthorName":"梁云生"},{"authorName":"毛禹平","id":"fb43c295-528c-4dac-aaef-e1affc246d45","originalAuthorName":"毛禹平"},{"authorName":"朱煜","id":"4c1abc6c-b51a-4107-86dd-119d39e43706","originalAuthorName":"朱煜"}],"doi":"10.3969/j.issn.1000-7571.2003.04.015","fpage":"41","id":"5a971b6f-033d-4aa7-a038-ddb17ed261f2","issue":"4","journal":{"abbrevTitle":"YJFX","coverImgSrc":"journal/img/cover/YJFX.jpg","id":"71","issnPpub":"1000-7571","publisherId":"YJFX","title":"冶金分析   "},"keywords":[{"id":"ab0aef2d-a806-43ee-8479-e9b41fc12de8","keyword":"<span style=\"color:red\">极</span><span style=\"color:red\">谱</span><span style=\"color:red\">法</span>","originalKeyword":"极谱法"},{"id":"fd760ceb-e6bf-44bf-87a1-aa1e26e9b0b2","keyword":"锗物料","originalKeyword":"锗物料"},{"id":"6347a07f-93e0-4058-8a34-080d7d7fef58","keyword":"微量砷","originalKeyword":"微量砷"}],"language":"zh","publisherId":"yjfx200304015","title":"催化<span style=\"color:red\">极</span><span style=\"color:red\">谱</span><span style=\"color:red\">法</span>快速测定高锗物料中的微量砷","volume":"23","year":"2003"},{"abstractinfo":"以导数微分脉冲<span style=\"color:red\">极</span><span style=\"color:red\">谱</span><span style=\"color:red\">法</span>对锌和镍共存液的重叠<span style=\"color:red\">极</span><span style=\"color:red\">谱</span>波进行了解析处理,较好地消除了背景残余电流的干扰,采用零交点法对电镀镍液中少量杂质锌进行了测定,方法简便,相对偏差小于2%.","authors":[{"authorName":"严金龙","id":"61ab733b-270a-4698-a15b-f9b9ce3ccbf6","originalAuthorName":"严金龙"}],"doi":"10.3969/j.issn.1001-1560.2002.10.014","fpage":"32","id":"790166c5-3199-4b80-a4c8-db6475f4c4e1","issue":"10","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"a2a23c04-fe35-40bc-bbc3-1d39812f34c9","keyword":"测定","originalKeyword":"测定"},{"id":"185dd001-1aef-48a4-adc1-e5af60c6537b","keyword":"锌","originalKeyword":"锌"},{"id":"5b8c89c8-9a62-4c0f-af4a-a4b2b18dd1d9","keyword":"导数<span style=\"color:red\">法</span>","originalKeyword":"导数法"},{"id":"4f633384-438a-4e8a-b008-11ea3fc48b1b","keyword":"<span style=\"color:red\">极</span><span style=\"color:red\">谱</span><span style=\"color:red\">法</span>","originalKeyword":"极谱法"}],"language":"zh","publisherId":"clbh200210014","title":"电镀镍液中锌的导数微分脉冲<span style=\"color:red\">极</span><span style=\"color:red\">谱</span>法测定","volume":"35","year":"2002"},{"abstractinfo":"研究了钴、镍、铜、镉对测定锌的干扰情况和消除干扰的方法.在NaOH-H2O2介质中沉淀分离钴、镍、铜、镉后,于NH4OH-NH4Cl底液中用<span style=\"color:red\">极</span><span style=\"color:red\">谱</span>法测定锌.本法不需用有机试剂,实际样品分析,效果良好.","authors":[{"authorName":"李菁菁","id":"4d4fd1f8-ab46-4278-a29f-2551da04563a","originalAuthorName":"李菁菁"}],"doi":"10.3969/j.issn.1000-7571.2000.05.017","fpage":"51","id":"1a83abf7-789c-41e0-9fdf-d1c588c76985","issue":"5","journal":{"abbrevTitle":"YJFX","coverImgSrc":"journal/img/cover/YJFX.jpg","id":"71","issnPpub":"1000-7571","publisherId":"YJFX","title":"冶金分析   "},"keywords":[{"id":"d30dc608-f572-407e-b6c3-a242520c7afd","keyword":"含钴、镍试料","originalKeyword":"含钴、镍试料"},{"id":"5dec299a-e1a7-4476-958b-bc8739199ee8","keyword":"锌","originalKeyword":"锌"},{"id":"91ffb336-9317-48d4-9b77-866e307413f7","keyword":"<span style=\"color:red\">极</span><span style=\"color:red\">谱</span><span style=\"color:red\">法</span>","originalKeyword":"极谱法"}],"language":"zh","publisherId":"yjfx200005017","title":"<span style=\"color:red\">极</span><span style=\"color:red\">谱</span>法测定含大量钴、镍试料中微量锌","volume":"20","year":"2000"},{"abstractinfo":"在0.003 mol.L-1 (CH2)6N4-HCl缓冲底液中, 偶氮溴磺 (Ⅲ) 在示波<span style=\"color:red\">极</span><span style=\"color:red\">谱</span>仪上产生三个良好的还原波: P1 (-0.25 V)、 P2 (-0.35 V) 和 P3 (-0.57 V), 加入稀土离子后, 试剂峰高降低, 并在更负的电位处产生络合吸附波P4 (-0.62 V). P4峰高与稀土离子的浓度有良好的线性关系, 用来测定Ce3+, 检测下限可达2×10-8 mol.L-1. 轻、重稀土有类似的响应.","authors":[{"authorName":"陈红","id":"fedb8a71-d3c6-4e56-b75f-a91dfb48f270","originalAuthorName":"陈红"},{"authorName":"康敬万","id":"9d7bbb42-5221-463b-8cf4-269cd22602a0","originalAuthorName":"康敬万"},{"authorName":"莫尊理","id":"148e5135-cacf-4a41-a56e-ebc66b25cadf","originalAuthorName":"莫尊理"},{"authorName":"高锦章","id":"cdd50c00-89df-47e3-aa63-0b74d0036a78","originalAuthorName":"高锦章"}],"doi":"10.3969/j.issn.0258-7076.1998.05.003","fpage":"331","id":"9d893b3f-09b7-4763-8ca9-38f4ab7e29b8","issue":"5","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"12bd71e1-6608-4a20-b294-cdb991480b2f","keyword":"偶氮溴磺(Ⅲ)","originalKeyword":"偶氮溴磺(Ⅲ)"},{"id":"45d53a70-1e23-4018-816e-59233912ee2b","keyword":"铈","originalKeyword":"铈"},{"id":"3ffe19dc-4513-47a6-915e-cfea9d53dcde","keyword":"<span style=\"color:red\">极</span><span style=\"color:red\">谱</span><span style=\"color:red\">法</span>","originalKeyword":"极谱法"}],"language":"zh","publisherId":"xyjs199805003","title":"稀土-偶氮溴磺 (Ⅲ) <span style=\"color:red\">极</span><span style=\"color:red\">谱</span>络合吸附波的研究","volume":"22","year":"1998"},{"abstractinfo":"采用线性扫描<span style=\"color:red\">极</span><span style=\"color:red\">谱</span><span style=\"color:red\">法</span>研究了抗心率失常药物普罗帕酮在汞电极上的电还原行为,建立了测定实际样品中普罗帕酮的新方法. 在pH＜11.6底液中,普罗帕酮产生1个还原波;在底液pH≥11.6条件下,普罗帕酮产生P1和P2 2个还原波. 研究表明,P1波为普罗帕酮产生的催化氢波,P2波为普罗帕酮分子中羰基的电化学还原波. 在pH=12.3的Britton-Robinson缓冲溶液中,二阶导数<span style=\"color:red\">极</span><span style=\"color:red\">谱</span>图上P2波的峰电流与普罗帕酮的浓度在9.6×10-8 ～4.0×10-6 mol/L范围内呈线性关系,检出限为5×10-8 mol/L. 对1.0×10-6 mol/L普罗帕酮测定6次的RSD=1.2%. 用二阶导数<span style=\"color:red\">极</span><span style=\"color:red\">谱</span>法测定片剂中普罗帕酮的含量结果与药典方法测得结果一致,血清中不同浓度普罗帕酮测定的回收率在98.6%～102%.","authors":[{"authorName":"张宏芳","id":"12d32c3b-d39e-4927-8ec4-8fbaca0f3770","originalAuthorName":"张宏芳"},{"authorName":"张亚","id":"28c930f3-ed87-4f4d-a1eb-ccb811bdc77f","originalAuthorName":"张亚"},{"authorName":"杨瑞丽","id":"6a639365-10e3-4a41-80e1-8f93c9e54e4d","originalAuthorName":"杨瑞丽"},{"authorName":"郑建斌","id":"ab594d5f-40d6-470d-b8da-6669daffbbd4","originalAuthorName":"郑建斌"}],"doi":"10.3969/j.issn.1000-0518.2009.01.023","fpage":"104","id":"cbf097cd-e176-4241-b397-4a684a5be8dc","issue":"1","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"f4f730df-a397-4b7e-9ad8-cf0bbba813d2","keyword":"<span style=\"color:red\">极</span><span style=\"color:red\">谱</span><span style=\"color:red\">法</span>","originalKeyword":"极谱法"},{"id":"f8b01b5a-b231-43e1-b7b4-ab166bc0183d","keyword":"电还原行为","originalKeyword":"电还原行为"},{"id":"1789c112-af65-47a1-a56a-c1aaf6fcd197","keyword":"催化氢波","originalKeyword":"催化氢波"},{"id":"e7dcfe4b-cdf0-4b6e-817a-d12f0c88b94d","keyword":"普罗帕酮","originalKeyword":"普罗帕酮"}],"language":"zh","publisherId":"yyhx200901023","title":"普罗帕酮的电还原行为及其应用","volume":"26","year":"2009"},{"abstractinfo":"提出了一个连续测定精锑中微量镍和钴的新方法,在丁二酮肟-NaNO2-NH3H2O-NH4Cl体系中,示波<span style=\"color:red\">极</span><span style=\"color:red\">谱</span><span style=\"color:red\">法</span>同时测定了精锑中微量镍和钴,结果良好.","authors":[{"authorName":"陈丽春","id":"043897b7-65a1-4185-9ff6-5683bc224bef","originalAuthorName":"陈丽春"},{"authorName":"毛禹平","id":"96019f57-5539-4aa8-b5fe-bee6fe8713a5","originalAuthorName":"毛禹平"}],"doi":"10.3969/j.issn.1000-7571.2002.03.014","fpage":"42","id":"3339b7cf-c0d6-4161-bd5f-9b9194c6df88","issue":"3","journal":{"abbrevTitle":"YJFX","coverImgSrc":"journal/img/cover/YJFX.jpg","id":"71","issnPpub":"1000-7571","publisherId":"YJFX","title":"冶金分析   "},"keywords":[{"id":"e68f6550-766f-4847-8377-ee771b81efbe","keyword":"精锑","originalKeyword":"精锑"},{"id":"4dfc84ba-fc30-44ff-a9a6-9a713c219136","keyword":"镍","originalKeyword":"镍"},{"id":"93ae6d5a-dc40-4493-9d46-818d1b2f9ea5","keyword":"钴","originalKeyword":"钴"},{"id":"9755b2ba-2b4f-4fcf-bf9c-750580494317","keyword":"示波<span style=\"color:red\">极</span><span style=\"color:red\">谱</span><span style=\"color:red\">法</span>","originalKeyword":"示波极谱法"}],"language":"zh","publisherId":"yjfx200203014","title":"示波<span style=\"color:red\">极</span><span style=\"color:red\">谱</span><span style=\"color:red\">法</span>连续测定精锑中微量钴和镍","volume":"22","year":"2002"},{"abstractinfo":"概述了催化<span style=\"color:red\">极</span><span style=\"color:red\">谱</span>法测定矿石样品中铂的方法,并讨论了有效提高测定铂灵敏度的途径.实验结果表明,铂在硫酸-六次甲基四胺混合溶液中有很好的催化波,且在该底液中测定铂,其抗干扰能力强;铂的质量浓度在0.01 ng/mL～10 μg/mL范围内呈线性关系.该方法对标准样品GBW 07291、GBW 07292和 GBW 07293进行测试,分析结果令人满意.","authors":[{"authorName":"王君玉","id":"9bd05d13-0921-47b4-b645-179304bf5512","originalAuthorName":"王君玉"},{"authorName":"李志伟","id":"1761a044-f09f-47f5-8b6f-cf34eca92c44","originalAuthorName":"李志伟"},{"authorName":"韩敏","id":"6dc8e161-125c-4d39-a286-b44f4f3aa5ee","originalAuthorName":"韩敏"},{"authorName":"程祎","id":"a1d505c1-0d10-40bc-a00e-8f2ee88b7646","originalAuthorName":"程祎"}],"doi":"10.3969/j.issn.1001-1277.2011.02.015","fpage":"63","id":"0fd9d090-a038-499b-a8ea-788c9a9af991","issue":"2","journal":{"abbrevTitle":"HJ","coverImgSrc":"journal/img/cover/HJ.jpg","id":"44","issnPpub":"1001-1277","publisherId":"HJ","title":"黄金"},"keywords":[{"id":"48897192-3937-4e83-8251-52d9b192a0ba","keyword":"催化<span style=\"color:red\">极</span><span style=\"color:red\">谱</span><span style=\"color:red\">法</span>","originalKeyword":"催化极谱法"},{"id":"376f1f2b-bf23-4fad-abd8-17578100cbd0","keyword":"矿石","originalKeyword":"矿石"},{"id":"2ad09104-afa8-4d82-a1a8-2af059c2f492","keyword":"微量铂","originalKeyword":"微量铂"},{"id":"9ee87051-c217-4c7a-9f14-d218ddfbc057","keyword":"直接测定","originalKeyword":"直接测定"}],"language":"zh","publisherId":"huangj201102015","title":"碱熔-催化<span style=\"color:red\">极</span><span style=\"color:red\">谱</span><span style=\"color:red\">法</span>直接测定矿石中微量铂","volume":"32","year":"2011"},{"abstractinfo":"在0.10mol／L乙酸（pH2.8）及硫酸联胺底液中，锌在滴汞电极上产生一个灵敏的<span style=\"color:red\">极</span><span style=\"color:red\">谱</span>还原波，峰电位（Ep）为-1.06V（vs.SCE）。锌浓度在0.03～2.0μg／mL范围内与波高呈良好的线性关系。方法的选择性高、重复性好。用于铝制食具、食品用橡胶制品中锌的测定，回收率为95.6％～110.4％，RSD＜5％，结果令人满意。","authors":[{"authorName":"张文德","id":"56e9c8eb-9922-4fd9-ae47-a7900b0f50ee","originalAuthorName":"张文德"}],"doi":"10.3969/j.issn.1000-7571.2001.01.016","fpage":"47","id":"dd149248-eac0-4097-8353-8a233891eb0a","issue":"1","journal":{"abbrevTitle":"YJFX","coverImgSrc":"journal/img/cover/YJFX.jpg","id":"71","issnPpub":"1000-7571","publisherId":"YJFX","title":"冶金分析   "},"keywords":[{"id":"828516b0-c301-48d2-8a48-40ea86fd736b","keyword":"示波<span style=\"color:red\">极</span><span style=\"color:red\">谱</span><span style=\"color:red\">法</span>","originalKeyword":"示波极谱法"},{"id":"a356d436-d908-4295-98e3-b3d413a59b60","keyword":"铝制食具、橡胶制品","originalKeyword":"铝制食具、橡胶制品"},{"id":"f0c6f46c-fe1e-4dda-aa62-8f6100362b16","keyword":"锌","originalKeyword":"锌"}],"language":"zh","publisherId":"yjfx200101016","title":"铝制食具和橡胶制品中锌的快速示波<span style=\"color:red\">极</span><span style=\"color:red\">谱</span><span style=\"color:red\">法</span>","volume":"21","year":"2001"}],"totalpage":4472,"totalrecord":44716}