{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以聚苯乙烯微球离心后形成的<span style=\"color:red\">三维</span><span style=\"color:red\">规则</span><span style=\"color:red\">排列</span>的胶晶作模板,用钛酸丁酯和正硅酸乙酯分别和水、乙醇等配制成的混合溶胶填充微球之间的间隙,然后原位形成凝胶,最后通过焙烧(＜5℃/min;300℃,5h;570℃,5～10h,空气流速1L/min)除去微球得到<span style=\"color:red\">三维</span><span style=\"color:red\">规则</span><span style=\"color:red\">排列</span>的<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>钛硅混合氧化物.样品表面可观察到五颜六色的彩光.样品的SEM图表明,球形<span style=\"color:red\">孔</span>大小均匀,<span style=\"color:red\">排列</span>整齐,<span style=\"color:red\">孔</span>壁填充完全.孔径在500nm左右,<span style=\"color:red\">孔</span>的<span style=\"color:red\">排列</span>呈面心立方结构,<span style=\"color:red\">孔</span>与<span style=\"color:red\">孔</span>之间由小孔窗相互交连.较高的溶胶浓度有利于溶胶的填充,容易形成<span style=\"color:red\">孔</span>壁较厚的坚固的<span style=\"color:red\">三维</span>骨架.低浓度得到的样品<span style=\"color:red\">孔</span>壁薄,缺陷多,易脆裂.样品的EDS表明Si/Ti的摩尔比为2.7,XRD研究表明<span style=\"color:red\">孔</span>壁具有无定形的结构.","authors":[{"authorName":"沈勇","id":"174ce1fd-ffeb-41a7-810f-6f5d84605979","originalAuthorName":"沈勇"},{"authorName":"邬泉周","id":"336e29a0-724f-4cb9-9b57-c0c178fb3d20","originalAuthorName":"邬泉周"},{"authorName":"廖菊芳","id":"8b036927-506a-4809-a23e-302384af8b01","originalAuthorName":"廖菊芳"},{"authorName":"李玉光","id":"cf07cd4b-edc7-42d7-97b3-ea230ebf0732","originalAuthorName":"李玉光"}],"doi":"10.3321/j.issn:1000-324X.2003.02.024","fpage":"401","id":"07e3dce5-4301-451c-94b4-9e5f0075a341","issue":"2","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"10b77755-39ab-4846-a592-23f59fdfa064","keyword":"钛硅混合氧化物","originalKeyword":"钛硅混合氧化物"},{"id":"4e7e552a-1851-40ab-8789-a166ca79ff31","keyword":"<span style=\"color:red\">三维</span><span style=\"color:red\">规则</span><span style=\"color:red\">排列</span><span style=\"color:red\">大</span><span style=\"color:red\">孔</span>(<span style=\"color:red\">3DOM</span>)","originalKeyword":"三维规则排列大孔(3DOM)"},{"id":"1a5171dc-7dcf-47a6-906a-1cc3d32669b8","keyword":"聚苯乙烯微球","originalKeyword":"聚苯乙烯微球"},{"id":"7fdcba0d-fe2c-4ec7-b06c-e1c301e7bd84","keyword":"胶晶","originalKeyword":"胶晶"}],"language":"zh","publisherId":"wjclxb200302024","title":"<span style=\"color:red\">三维</span><span style=\"color:red\">规则</span><span style=\"color:red\">排列</span>的<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>钛硅混合氧化物的制备与表征","volume":"18","year":"2003"},{"abstractinfo":"以聚苯乙烯微球离心后形成的<span style=\"color:red\">三维</span><span style=\"color:red\">规则</span><span style=\"color:red\">排列</span>的胶晶作模板,以正硅酸乙酯、水、乙醇和盐酸等配制的溶胶填充微球间的间隙,然后原位形成凝胶,最后通过焙烧除去微球得到<span style=\"color:red\">三维</span><span style=\"color:red\">规则</span><span style=\"color:red\">排列</span><span style=\"color:red\">大</span><span style=\"color:red\">孔</span>二氧化硅材料. 以苯乙烯为原料,过硫酸钾为引发剂,在70 ℃下搅拌28 h后得到含聚苯乙烯微球(直径约为600 nm)的母液. 将母液在900～1000 r/min的转速下离心12～24 h得到紧密堆积<span style=\"color:red\">排列</span>的胶晶. 以正硅酸乙酯作为硅源,按n(Si(OEt)4)∶n(EtOH)∶n(HCl)∶n(H2O)=1∶3.9∶0.3∶1.8制成透明的SiO2溶胶. 溶胶浓度控制在0.5～1.0 mol/L. 滴加在胶晶上的溶胶靠毛细管的作用力填充入微球间隙. 重复填充多次(一般不超过5次). 焙烧在流量为1 L/min的空气中进行,升温速度控制在5 ℃/min以下. 在300 ℃下恒温5 h以除去聚苯乙烯微球,在570 ℃下焙烧5 h. 焙烧后的样品表面可观察到五颜六色的彩光. SEM分析结果表明,球形<span style=\"color:red\">孔</span>(孔径约500 nm)大小均匀,<span style=\"color:red\">排列</span>整齐,保持了微球的紧密堆积<span style=\"color:red\">排列</span>结构. <span style=\"color:red\">孔</span>与<span style=\"color:red\">孔</span>之间由小孔窗相互交连,<span style=\"color:red\">孔</span>壁比较充实,壁厚约为130 nm. ","authors":[{"authorName":"沈勇","id":"6b4f8c37-f9e4-476d-9cf4-0103aa3021e7","originalAuthorName":"沈勇"},{"authorName":"邬泉周","id":"e5656baf-7a67-4f5c-9533-0239c5e1faee","originalAuthorName":"邬泉周"},{"authorName":"李玉光","id":"4503e221-0111-4264-977d-77c2ce32f4ea","originalAuthorName":"李玉光"}],"doi":"","fpage":"179","id":"b0458e37-7b16-444c-b9ff-4f2c26f327d4","issue":"2","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"8c53eaef-c1d6-41e5-bed8-ab9f7784975f","keyword":"二氧化硅","originalKeyword":"二氧化硅"},{"id":"f49a42f3-5e41-47b9-b5fe-d1cad3fdcc1e","keyword":"<span style=\"color:red\">三维</span><span style=\"color:red\">规则</span><span style=\"color:red\">排列</span><span style=\"color:red\">大</span><span style=\"color:red\">孔</span>","originalKeyword":"三维规则排列大孔"},{"id":"fcfa37ae-b1a3-4b1a-9735-5be33ee4def3","keyword":"聚苯乙烯","originalKeyword":"聚苯乙烯"},{"id":"8145a477-50eb-48e7-853b-2a0634250ca2","keyword":"微球","originalKeyword":"微球"},{"id":"30da6e05-8d5f-40b3-a434-0b9c329cb2d3","keyword":"胶晶","originalKeyword":"胶晶"}],"language":"zh","publisherId":"cuihuaxb200202023","title":"<span style=\"color:red\">三维</span><span style=\"color:red\">规则</span><span style=\"color:red\">排列</span>的<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>SiO2材料的制备及表征","volume":"23","year":"2002"},{"abstractinfo":"以聚苯乙烯微球离心后形成的<span style=\"color:red\">三维</span><span style=\"color:red\">规则</span><span style=\"color:red\">排列</span>的胶晶作模板,用钛酸丁酯和正硅酸乙酯分别和水、乙醇等配制成的混合溶胶填充微球之间的间隙,然后原位形成凝胶,最后通过焙烧(&lt;5℃/min;300℃,5h;570℃,5～10h,空气流速1L/min)除去微球得到<span style=\"color:red\">三维</span><span style=\"color:red\">规则</span><span style=\"color:red\">排列</span>的<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>钛硅混合氧化物.样品表面可观察到五颜六色的彩光.样品的SEM图表明,球形<span style=\"color:red\">孔</span>大小均匀,<span style=\"color:red\">排列</span>整齐,<span style=\"color:red\">孔</span>壁填充完全.孔径在500nm左右,<span style=\"color:red\">孔</span>的<span style=\"color:red\">排列</span>呈面心立方结构,<span style=\"color:red\">孔</span>与<span style=\"color:red\">孔</span>之间由小孔窗相互交连.较高的溶胶浓度有利于溶胶的填充,容易形成<span style=\"color:red\">孔</span>壁较厚的坚固的<span style=\"color:red\">三维</span>骨架.低浓度得到的样品<span style=\"color:red\">孔</span>壁薄,缺陷多,易脆裂.样品的EDS表明Si/Ti的摩尔比为2.7,XRD研究表明<span style=\"color:red\">孔</span>壁具有无定形的结构.","authors":[{"authorName":"沈勇","id":"35e4421f-65ff-4686-a28e-b1e8e6651d28","originalAuthorName":"沈勇"},{"authorName":"邬泉周","id":"a496c4f5-a977-4c68-87c8-8a82e38eddaf","originalAuthorName":"邬泉周"},{"authorName":"廖菊芳","id":"73aba1fb-7764-401f-a530-4c4470e1ae26","originalAuthorName":"廖菊芳"},{"authorName":"李玉光","id":"8ac9af91-6d68-4c4a-97f7-c0f9aa1bc251","originalAuthorName":"李玉光"}],"categoryName":"|","doi":"","fpage":"401","id":"1ad1c79a-92cc-42be-978e-2d758c584673","issue":"2","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"1e0581f6-187e-434c-ad59-70d86cef5d89","keyword":"钛硅混合氧化物","originalKeyword":"钛硅混合氧化物"},{"id":"04baa83b-aaaf-4360-b3aa-9ebfd166c309","keyword":" three-dimensionally ordered macroporous","originalKeyword":" three-dimensionally ordered macroporous"},{"id":"851a35b6-eef4-496a-ba52-53bcc35219e4","keyword":" polystyrene sphere","originalKeyword":" polystyrene sphere"},{"id":"60d549a0-ebaa-45ec-8aa5-424c1ed04030","keyword":" colloid crystal","originalKeyword":" colloid crystal"}],"language":"zh","publisherId":"1000-324X_2003_2_20","title":"<span style=\"color:red\">三维</span><span style=\"color:red\">规则</span><span style=\"color:red\">排列</span>的<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>钛硅混合氧化物的制备与表征","volume":"18","year":"2003"},{"abstractinfo":"主要介绍了胶晶模板法制备<span style=\"color:red\">三维</span>有序<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>材料(<span style=\"color:red\">3DOM</span>),详细阐述了单分散微球的合成、胶晶模板的<span style=\"color:red\">排列</span>、前驱物的填充以及胶晶模板的去除,同时还归纳了<span style=\"color:red\">3DOM</span>材料在催化剂载体、过滤及分离材料、光子晶体和光学传感器等方面的应用,并指出了目前急需要解决的问题.","authors":[{"authorName":"于景媛","id":"f34065b3-a85e-444b-afcd-3eb8123b4763","originalAuthorName":"于景媛"},{"authorName":"李强","id":"183ba383-30c3-4926-a3f1-8dcb31a44dba","originalAuthorName":"李强"},{"authorName":"马晓红","id":"39063c64-b818-4e01-8761-0fa48d32ba69","originalAuthorName":"马晓红"},{"authorName":"孙旭东","id":"1671a070-ab43-46b3-b383-ea9354fd73e1","originalAuthorName":"孙旭东"}],"doi":"","fpage":"21","id":"c7d463e5-27d2-4d6b-808e-d9809b21e1e1","issue":"4","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"a4508a76-0f69-4d1d-a918-ebd6b78814da","keyword":"<span style=\"color:red\">三维</span>有序<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>材料","originalKeyword":"三维有序大孔材料"},{"id":"e994f359-becb-4b6a-882c-3a7c15264498","keyword":"胶晶模板法","originalKeyword":"胶晶模板法"},{"id":"fce64214-137e-4f66-a0a7-b4a74d70a8d0","keyword":"应用","originalKeyword":"应用"}],"language":"zh","publisherId":"cldb200604007","title":"<span style=\"color:red\">三维</span>有序<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>材料的制备及应用","volume":"20","year":"2006"},{"abstractinfo":"以自然沉积的聚甲基丙烯酸甲酯(PMMA)胶体晶体为模板,用一定浓度的氧氯化锆乙醇溶液为前驱体进行填充,最后通过煅烧除去模板得到了<span style=\"color:red\">三维</span>有序<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>(<span style=\"color:red\">3DOM</span>)ZrO2材料.从SEM照片观察到,<span style=\"color:red\">3DOM</span> ZrO2可以看成是PMMA模板的逆复制,孔径大小均匀,<span style=\"color:red\">排列</span>整齐,整体上呈面心立方结构.孔径在260 nm左右,收缩率约为28%,<span style=\"color:red\">孔</span>壁填充完全.XRD结果表明,制备的<span style=\"color:red\">3DOM</span> ZrO2<span style=\"color:red\">孔</span>壁为单斜晶型,晶粒大小为26 nm.","authors":[{"authorName":"赵玉翠","id":"83381f2b-c877-4709-b609-b117bdc0967c","originalAuthorName":"赵玉翠"},{"authorName":"郑经堂","id":"f5c013e1-8667-43b2-a42f-eabd698d928a","originalAuthorName":"郑经堂"},{"authorName":"李石","id":"e7046cb0-805b-4b36-abd6-00ab39a5d10e","originalAuthorName":"李石"},{"authorName":"刘颖","id":"c96985f8-f2ce-44c1-a992-ad96de9cc137","originalAuthorName":"刘颖"}],"doi":"","fpage":"28","id":"ef74f8da-fd69-450d-b0e9-deee74c59b9a","issue":"6","journal":{"abbrevTitle":"ZGCLJZ","coverImgSrc":"journal/img/cover/中国材料进展.jpg","id":"80","issnPpub":"1674-3962","publisherId":"ZGCLJZ","title":"中国材料进展"},"keywords":[{"id":"be558d1a-b844-417d-ab69-a4aa35648721","keyword":"胶体晶体","originalKeyword":"胶体晶体"},{"id":"0db3b31e-abcd-4a7e-9b9f-9549f97d0481","keyword":"面心立方结构","originalKeyword":"面心立方结构"},{"id":"b5683664-63d6-4ef2-9b37-86dd1a37fd06","keyword":"<span style=\"color:red\">三维</span>有序<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>材料","originalKeyword":"三维有序大孔材料"},{"id":"b6f588ae-f5c7-432a-a558-412e3cf782a2","keyword":"二氧化锆","originalKeyword":"二氧化锆"}],"language":"zh","publisherId":"zgcljz200806007","title":"<span style=\"color:red\">三维</span>有序<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>ZrO2的制备与表征","volume":"27","year":"2008"},{"abstractinfo":"用自然沉降法组装成<span style=\"color:red\">规则</span><span style=\"color:red\">排列</span>的聚苯乙烯胶晶,并以此作为模板剂,用Keggin结构的杂多酸SiW12 和正硅酸乙酯组成溶胶作为先驱物,成功制备了<span style=\"color:red\">三维</span>有序<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>(<span style=\"color:red\">3DOM</span>)SiW12/SiO2杂化材料. XRD和IR等测试结果表明,所得样品中的杂多酸SiW12 能够保持其Keggin结构,SEM观察显示,样品具有<span style=\"color:red\">三维</span><span style=\"color:red\">大</span><span style=\"color:red\">孔</span><span style=\"color:red\">规则</span><span style=\"color:red\">排列</span>的结构. 研究发现,溶胶组成对杂化材料的<span style=\"color:red\">3DOM</span>结构影响很大,纯SiW12 难以形成<span style=\"color:red\">3DOM</span>结构,随着SiO2含量的增加,样品的<span style=\"color:red\">孔</span>结构<span style=\"color:red\">三维</span>规整性和强度明显增强,而且引入SiO2可有效提高杂多酸的热稳定性.","authors":[{"authorName":"尹强","id":"598000ed-f780-47e1-bffe-1e006f277ed1","originalAuthorName":"尹强"},{"authorName":"邬泉周","id":"4c9f6394-cb67-47d6-85e0-ab203734b5fe","originalAuthorName":"邬泉周"},{"authorName":"廖菊芳","id":"fee55052-ef2c-4046-98cb-9dc713a1746b","originalAuthorName":"廖菊芳"},{"authorName":"邓景衡","id":"294fe2fe-d8ad-4be4-bf63-f391b469da86","originalAuthorName":"邓景衡"},{"authorName":"李玉光","id":"d4d7c51b-b0c0-423c-b399-38ace3e4c8bb","originalAuthorName":"李玉光"}],"doi":"","fpage":"889","id":"afbb73ce-3035-45e4-aff7-61fdab86eb96","issue":"10","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"54b6b445-0d2a-4284-b45b-16bd392784d4","keyword":"杂多酸","originalKeyword":"杂多酸"},{"id":"22616b78-94e5-4056-9a1b-40f0d19ff301","keyword":"Keggin结构","originalKeyword":"Keggin结构"},{"id":"9af2cb73-4993-45a3-af73-3e29ddc89d21","keyword":"<span style=\"color:red\">三维</span>有序<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>","originalKeyword":"三维有序大孔"},{"id":"0da751b1-788d-4dec-94d2-7ec3fd75edc9","keyword":"聚苯乙烯","originalKeyword":"聚苯乙烯"},{"id":"9428fe94-d8ef-4948-a1b2-e8d578e6d4d0","keyword":"胶晶","originalKeyword":"胶晶"}],"language":"zh","publisherId":"cuihuaxb200510015","title":"<span style=\"color:red\">三维</span>有序<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>SiW12/SiO2杂化材料的制备及表征","volume":"26","year":"2005"},{"abstractinfo":"<span style=\"color:red\">三维</span>有序<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>(<span style=\"color:red\">3DOM</span>)材料具有高度有序的<span style=\"color:red\">孔</span>结构和较大的比表面积,这些特点有利于气体在材料表面的传输与扩散,可以作为良好的气敏材料.本文通过聚苯乙烯模板结合煅烧处理的方法制备了<span style=\"color:red\">3DOM</span> WO<span style=\"color:red\">3</span>气敏材料,并运用XRD、SEM、BET、XPS等手段对其物相、形貌、比表面积和表面成分等进行了表征.气敏测试结果表明,所制备的<span style=\"color:red\">3DOM</span>材料对丙酮灵敏度高(在丙酮浓度10 ppm时,S=10),检测限可低至0.2 ppm.此外,<span style=\"color:red\">3DOM</span> WO<span style=\"color:red\">3</span>材料对丙酮还具有良好的选择性和长期稳定性.最后,对所制备的<span style=\"color:red\">3DOM</span> WO<span style=\"color:red\">3</span>材料进行了气敏机理解释.","authors":[{"authorName":"刘志强","id":"9bd3819a-b865-4c47-b531-706af863c0f0","originalAuthorName":"刘志强"},{"authorName":"要红昌","id":"32664e4f-2e9e-481e-866a-c666a42dd3d1","originalAuthorName":"要红昌"},{"authorName":"申小清","id":"fbbe5339-ea23-47ea-9ac0-14b078c8da58","originalAuthorName":"申小清"},{"authorName":"陈金周","id":"66424bed-b756-4748-bd3b-9de0e66ca7f6","originalAuthorName":"陈金周"}],"doi":"","fpage":"2626","id":"a1567894-e074-49eb-af9f-8afeb2863bd8","issue":"11","journal":{"abbrevTitle":"RGJTXB","coverImgSrc":"journal/img/cover/RGJTXB.jpg","id":"57","issnPpub":"1000-985X","publisherId":"RGJTXB","title":"人工晶体学报"},"keywords":[{"id":"0df083ea-d1c9-4194-a01e-aea405a9d468","keyword":"WO<span style=\"color:red\">3</span>","originalKeyword":"WO3"},{"id":"c8591715-f80b-499c-86c7-26f671931e60","keyword":"<span style=\"color:red\">三维</span>有序<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>","originalKeyword":"三维有序大孔"},{"id":"e0bdef71-2dfc-4ff1-a3e8-a24ca4dbc9d0","keyword":"气敏","originalKeyword":"气敏"}],"language":"zh","publisherId":"rgjtxb98201611011","title":"<span style=\"color:red\">三维</span>有序<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>WO<span style=\"color:red\">3</span>的制备及其对丙酮的气敏响应","volume":"45","year":"2016"},{"abstractinfo":"以自然沉积的聚苯乙烯(PS)胶体晶体为模板,分别以正硅酸乙酯(TEOS)的醇盐溶液和溶胶溶液为前驱体对PS模板进行填充,通过煅烧除去模板,得到了<span style=\"color:red\">三维</span>有序<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>(<span style=\"color:red\">3DOM</span>) SiO2材料.由SEM照片观察发现,当以TEOS的醇盐溶液为前驱体时,获得的<span style=\"color:red\">3DOM</span> SiO2结构不易控制,缺陷较多.而以TEOS的溶胶溶液为前驱体时获得的<span style=\"color:red\">3DOM</span> SiO2结构良好,孔径大小均匀,<span style=\"color:red\">排列</span>整齐,可以看成是PS模板的逆复制,说明前驱体溶液的选择对<span style=\"color:red\">3</span>DOMSiO2材料的微观结构有显著的影响.XRD分析显示,制备的<span style=\"color:red\">3DOM</span> SiO2<span style=\"color:red\">孔</span>壁为无定形结构.","authors":[{"authorName":"李石","id":"6461cf45-406e-4b49-aee5-dc032fdf4808","originalAuthorName":"李石"},{"authorName":"赵东风","id":"6b0b08e9-f06a-4807-a311-629d9b781110","originalAuthorName":"赵东风"},{"authorName":"郑经堂","id":"e59b1800-1bfe-48f8-a530-328d070cb3b1","originalAuthorName":"郑经堂"},{"authorName":"薛建良","id":"a116cee5-4457-4c6e-a7a1-fc36dc614dfe","originalAuthorName":"薛建良"},{"authorName":"孙慧","id":"86e58cb6-2d77-47d3-bc99-5181872adc69","originalAuthorName":"孙慧"},{"authorName":"刘伟","id":"b153187d-bfb7-46cc-8f03-9ebd684db34d","originalAuthorName":"刘伟"}],"doi":"","fpage":"865","id":"1eb87d2e-5bcb-475a-bc52-3c00a318fe06","issue":"4","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报   "},"keywords":[{"id":"add22a1f-9d3c-4b9f-bb7e-d60619ec85f2","keyword":"胶体晶体","originalKeyword":"胶体晶体"},{"id":"2db3f983-3204-409d-a77f-eef993024cb9","keyword":"前驱体","originalKeyword":"前驱体"},{"id":"72e33a42-a25e-429c-be96-7b409a07bef5","keyword":"<span style=\"color:red\">三维</span>有序<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>材料","originalKeyword":"三维有序大孔材料"},{"id":"6ea482db-b82d-48ef-8c06-71c76a077349","keyword":"二氧化硅","originalKeyword":"二氧化硅"}],"language":"zh","publisherId":"gsytb201104024","title":"前驱体对合成<span style=\"color:red\">3DOM</span> SiO2材料微观结构的影响","volume":"30","year":"2011"},{"abstractinfo":"以聚苯乙烯胶晶为模板,<span style=\"color:red\">3</span>-氨基-丙基-<span style=\"color:red\">三</span>乙氧基硅烷和正硅酸乙酯为前驱物,合成了<span style=\"color:red\">三维</span>有序<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>(<span style=\"color:red\">3DOM</span>)氨基功能化SiO2-NH2材料. SEM观察表明,合成的<span style=\"color:red\">3DOM</span>材料具有<span style=\"color:red\">规则</span>整齐的<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>通<span style=\"color:red\">孔</span>结构,平均孔径在535～596 nm之间,孔径收缩率为4.8%～14.5%. FTIR分析表明,材料中含有氨基等有机基团. BET分析表明,材料的比表面积为10.2 m2/g. 合成的<span style=\"color:red\">3DOM</span> SiO2-NH2材料对Cr(Ⅵ)离子的吸附能力随着材料中氨基含量的增加而增大,最大吸附量为4.31 mmol/g.","authors":[{"authorName":"邬泉周","id":"37babc96-71c3-4021-ad6d-af31de72679b","originalAuthorName":"邬泉周"},{"authorName":"何建峰","id":"2450657a-3be7-421d-98a5-d1efbdb8eb8d","originalAuthorName":"何建峰"},{"authorName":"李玉光","id":"49abe366-522c-430d-b0b2-27302515f735","originalAuthorName":"李玉光"}],"doi":"10.3969/j.issn.1000-0518.2009.03.029","fpage":"367","id":"781e1136-e6b7-4770-b292-2b6b8cde16c8","issue":"3","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"da7318de-3370-49dd-9701-d170886ac3eb","keyword":"<span style=\"color:red\">三维</span>有序<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>","originalKeyword":"三维有序大孔"},{"id":"2328d012-9eb6-4697-abee-e9168d91c3d8","keyword":"氨基","originalKeyword":"氨基"},{"id":"9630d833-cebf-4531-8c62-b0351cef7e9e","keyword":"功能化","originalKeyword":"功能化"},{"id":"227779c1-de71-4ea7-a32a-ef25a30e9c87","keyword":"材料","originalKeyword":"材料"}],"language":"zh","publisherId":"yyhx200903029","title":"<span style=\"color:red\">三维</span>有序<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>氨基功能化材料的制备及其对Cr(Ⅵ)的吸附性能","volume":"26","year":"2009"},{"abstractinfo":"<span style=\"color:red\">三维</span>有序<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>材料具有整齐有序的孔道、分布均一的<span style=\"color:red\">孔</span>形孔径,因而在催化剂载体、过滤和分离材料、电极材料以及热阻材料等有着非常重要的作用.模板法是制备<span style=\"color:red\">三维</span>有序<span style=\"color:red\">大</span><span style=\"color:red\">孔</span>(<span style=\"color:red\">3DOM</span>)材料最常用的方法.其制备过程包括模板的制备、组装,往模板微球间的间隙填充前驱物溶液及模板的去除这几个步骤.结合近年来对这方面材料的研究工作及文献作一简要系统的综述.","authors":[{"authorName":"洪秀秀","id":"bd701039-1860-47fb-a2ca-34f463bfa32f","originalAuthorName":"洪秀秀"},{"authorName":"黄慧民","id":"900d640f-3344-4bf7-b225-9264115f1e43","originalAuthorName":"黄慧民"},{"authorName":"温立哲","id":"6a5f3388-c3ba-4d30-b716-b2460667db30","originalAuthorName":"温立哲"},{"authorName":"姬文晋","id":"65682b0a-d4f6-41c7-98fc-e23c688bcac9","originalAuthorName":"姬文晋"},{"authorName":"刘德飞","id":"facc035a-8e99-4e61-aeb8-62aa199874c3","originalAuthorName":"刘德飞"}],"doi":"","fpage":"16","id":"e2439d57-e778-4d6e-962d-b44b89f17f50","issue":"z1","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"0671aa14-5e97-4ac6-9868-c80da367aa8a","keyword":"<span style=\"color:red\">3DOM</span>","originalKeyword":"3DOM"},{"id":"1ae4e4de-2e8a-4621-8e32-068f4609fa2d","keyword":"聚苯乙烯","originalKeyword":"聚苯乙烯"},{"id":"36533866-79e3-4797-a4b9-1934f9843fd2","keyword":"微球","originalKeyword":"微球"},{"id":"b7eff06a-76c6-453b-a2ae-7f391931c1b7","keyword":"组装","originalKeyword":"组装"}],"language":"zh","publisherId":"cldb2008z1005","title":"胶晶模板法制备<span style=\"color:red\">3DOM</span>材料","volume":"22","year":"2008"}],"totalpage":9006,"totalrecord":90053}