材料期刊网

EFFECT OF COPPER ON THE HOT PLASTICITY OF 304HC STAINLESS STEEL

G. Z. Cui , H. S. Di , G. D. Wang , X. H. Liu

金属学报(英文版)

The plasticity map of 304HC stainless steel was determined by using tensile and compressive test. The effect of Cu on the hot plasticity of 304HC stainless steel was analyzed. The microstructure, inclusion and fracture surface were studied by using the method of optical microscopy, SEM, EDS and EPMA. The results showed that Cu has effect on the hot plasticity and the hot plasticity of 304HC stainless steel decrease with the increase of Cu content. The deformation temperature also has much effect on the hot plasticity, the suitable deformation temperature are 1100-1200℃. The reason is that the brittle compounds are Cu2S, Cu2O and PbCl etc.

关键词: 304HC stainless steel , null , null

a-Si:H/a-Si_(1-x)C_x:H 多层膜的电学和光学性质

彭启才 , 周心明 , 蔡伯埙

材料研究学报

采用等离子体辉光放电单室系统制备的a-Si:H/a-Si_(1-x)C_x:H 多层膜结构具有低的暗电导和高的光电导特性,且不同于单层膜,有明显的S-W 效应。随着子层厚度L 减小,多层膜曝光态(B)的暗电导率σdB 较退火态(A)的σdA 减小快,即光诱导衰退程度增大,而光电导无明显变化。本文还测定了此多层膜结构的光能隙E_g,得到随子层厚度减小“蓝移”的结果。用一维单量子阱模型作了讨论,实验值与理论计算符合较好。

关键词: a-Si:H/a-Si_(1-x)C_x:H , superlattice , amorphous semiconductors electrical properties , optical properties , null

XH轧制法轧制H型钢轧制力模型的研究

潘亮 , 程知松 , 范爱琴 , 蔡庆伍 , 郭新文

钢铁

对采用XH轧制法轧制H型钢的轧制力进行分析，以西姆斯公式为基础，采用多元线性回归的方法建立万能轧机轧制H型钢的轧制力数学模型。用编程的方法对数学模型的系数进行求解，给出几种规格的H型钢回归模型的系数，并将计算结果与实测的数据进行对比分析，得到的结果与实测值的误差在6％以内，表明模型具有较高的应用价值。

关键词: H型钢;数学模型;回归分析;轧制力

X-H轧制法轧制H型钢轧制力模型的研究

潘亮 , 程知松 , 范爱琴 , 蔡庆伍 , 郭新文

钢铁

对采用X-H轧制法轧制H型钢的轧制力进行分析,以西姆斯公式为基础,采用多元线性回归的方法建立万能轧机轧制H型钢的轧制力数学模型.用编程的方法对数学模型的系数进行求解,给出几种规格的H型钢回归模型的系数,并将计算结果与实测的数据进行对比分析,得到的结果与实测值的误差在6%以内,表明模型具有较高的应用价值.

关键词: H型钢 , 数学模型 , 回归分析 , 轧制力

Properties of Evaporated Si_(1-x)Sn_x and Si_(1_x)Sn_x:H Amorphous Alloys

M. Vergnat , M.Gerl+ , Laboratoire de Métallurgie Physique et Science des Maériaux (U.R.A.au C.N.R.S.No. 155) , Universite de Nancy 1 , France

材料科学技术（英文）

Amorphous Si_(1-x)Sn_x alloys have been prepared by co-evaporation onto substrates maintained at liquid nitrogen temperature. Their atomic structure is investigated using density measurements, scanning high-energy electron diffraction and Mossbauer spectroscopy. The optical and electrical properties are reported. Then, a method to hydrogenate the films during the evaporation process is described and applied to the preparation of amorphous semiconductors from pure silicon to pure tin. Finally, multilayers of type Si / Si:H / ... or Si:H / Si:D / ... are studied. The modulation of hydrogen is shown by low-angle neutron scattering and measurements of hydrogen diffusivity are presented.

关键词: amorphous alloy , null , null

First-principles investigations of the stability and electronic structure of ZrV2Hx (x=0.5, 1, 2, 3, 4, 6 and 7)

Acta Materialia

A calculation of the electronic structure and formation energy for ZrV2Hx (x = 0.5, 1, 2, 3, 4, 6 and 7) is performed using a plane-wave pseudo-potential method. It is found that in ZrV2Hx hydrogen forms stronger covalent bonds with vanadium than with zirconium if Zr atoms are in the neighborhood of V. A detailed analysis of how the densities of states change with the hydrogen count x in ZrV2Hx shows the changes in the bonding and anti-bonding interactions of H with V and Zr. However, the covalent anti-bonding interactions between H and V seem to be mainly responsible for the variation in the formation energy of ZrV2Hx with x. The value of projected density of states of V 3d at the Fermi level can be used as a rough comparative measure for these antibonding interactions and therefore allows us to predict the changes in stability of ZrV2Hx with x. (C) 2004 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

关键词: electronic structure;formation energy;plane-wave pseudo potential;hydrogen storage alloy;intermetallic compounds;convergence acceleration;population analysis;laves phases;total-energy;transition;hydrides;superconductivity;magnetism

Magnetomechanical properties of epoxy-bonded (Tb(0.3)Dy(0.7))(1-x)Pr(x)Fe(1.55) (0 <= x <= 0.4) pseudo-1-3 magnetostrictive composites

Journal of Physics D-Applied Physics

Pseudo-1-3 magnetostrictive composites consisting of stabilizer ( B, Co)-free, light rare earth (Pr)-containing magnetostrictive (Tb(0.3)Dy(0.7))(1-x) Pr(x) Fe(1.55) (0 <= x <= 0.4) particles with a size distribution of 10-300 mu m embedded and aligned in a passive epoxy matrix using 0.5 volume fraction are fabricated. The quasistatic magnetomechanical properties of the composites are investigated and compared with their monolithic (Tb(0.3)Dy(0.7))(1-x) Pr(x) Fe(1.55) alloys, as a function of the Pr content x. The composites show similar qualitative trends in properties with the alloys for all x. The (Tb(0.3)Dy(0.7))(0.75)Pr(0.25)Fe(1.55) composite and alloy exhibit the smallest coercivity H(c), the largest magnetostriction lambda and the highest piezomagnetic coefficient d(33) due to the successful compensation for magnetocrystalline anisotropy. The ( Tb0.3Dy0.7) 0.75Pr0.25Fe1.55 composite demonstrates a large saturation magnetostriction lambda(s) of 793 ppm at 700 kAm(-1) and a high d(33) of 3.2 nmA(-1) at 140 kAm(-1). These values approach 81% and 85% of its alloy values at the same field levels. The good properties make the (Tb(0.3)Dy(0.7))(0.75)Pr(0.25)Fe(1.55) composite and alloy a promising magnetostrictive material system.

关键词: terfenol-d;magnetic-properties;alloys;boron

显微组织对X65～X70管线钢抗H2S性能的影响

张雁 , 蔡庆伍 , 谢广宇

腐蚀学报（英文）

通过扫描电镜（SEM）、透射电镜（TEM）等方法，研究了X65～X70级别管线钢在饱和H2S溶液中的氢致开裂行为，及不同显微组织、位错与析出对氢致开裂（HIC）的作用.结果表明：组织均匀的珠光体/铁素体型X65管线钢和铁素体/针状铁素体型X70管线钢均具有良好的抗H2S腐蚀性能；带状组织是裂纹萌生和扩展的主要途径；合金元素的弥散析出作用可以提高管线钢的抗硫化氢腐蚀性能.

关键词: 管线钢 , null , null

显微组织对X65～X70管线钢抗H2S性能的影响

张雁 , 蔡庆伍 , 谢广宇

腐蚀学报（英文） doi:10.3969/j.issn.1002-6495.2007.06.004

通过扫描电镜(SEM)、透射电镜(TEM)等方法,研究了X65～X70级别管线钢在饱和H2S溶液中的氢致开裂行为,及不同显微组织、位错与析出对氢致开裂(HIC)的作用.结果表明:组织均匀的珠光体/铁素体型X65管线钢和铁素体/针状铁素体型X70管线钢均具有良好的抗H2S腐蚀性能;带状组织是裂纹萌生和扩展的主要途径;合金元素的弥散析出作用可以提高管线钢的抗硫化氢腐蚀性能.

关键词: 管线钢 , 显微组织 , 带状组织 , 氢致开裂(HIC) , 硫化氢(H2S)

掺铒a-SixC1-x-H薄膜的发光特性

卞留芳 , 张春光 , 陈维德 , 许振嘉 , 屈玉华 , 刁宏伟

中国稀土学报

用等离子体增强化学气相沉积(PECVD) 的方法,以固定的氢气(H2)流量和不同的硅烷(SiH4)和甲烷(CH4)流量比沉积了一系列的氢化非晶SiC(a-SixC1-x-H)膜.用这种宽带隙的a-SixC1-x-H材料作为掺铒的基体材料,通过离子注入的方法得到掺铒的a-SixC1-x-H(a-SixC1-x-H:Er)膜.注入以后的样品经过不同温度的退火.用X射线光电子能谱(XPS)、红外吸收光谱(IR)、拉曼散射谱(Raman)等技术研究不同的SiH4/CH4流量比和退火温度对a-SixC1-x-H:Er发光强度的影响.结果表明,高温退火引起了膜中C的分凝,对铒的发光是不利的.通过低温和室温下铒发光强度的比较,表明这种材料具有较弱的温度猝灭效应.

关键词: Er , SiC , 硅基材料 , 发光 , 稀土