{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"利用磷酸三丁酯(TBP)对<span style=\"color:red\">铱</span>(Ⅳ)<span style=\"color:red\">氯水</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>([Ir(H2O)nCl6-n]n-2,n=1,2,3)在HCl介质中的萃取行为进行了研究,考察了不同萃取剂和介质组成等因素对萃取分配比的影响.揭示这些物种在HCl介质中可萃性难易程度的变化规律,证实H2SO4具有促萃作用而HClO4起抑萃作用.通过对<span style=\"color:red\">铱</span>(Ⅳ)<span style=\"color:red\">氯水</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>经TBP萃取后所得水相、有机相的紫外-可见光谱的表征,研究了它们的萃取机理.","authors":[{"authorName":"陈丁文","id":"f40b1806-21ca-4dfa-9850-cbfe6f4c86cf","originalAuthorName":"陈丁文"},{"authorName":"董守安","id":"c8aab14e-0429-4925-a7a0-88108408e04a","originalAuthorName":"董守安"},{"authorName":"李楷中","id":"2999e729-fb31-4fd1-8a96-3512d61243ba","originalAuthorName":"李楷中"},{"authorName":"顾永万","id":"54d86f0f-ca00-442d-a753-a48758e4f02a","originalAuthorName":"顾永万"},{"authorName":"毛雪英","id":"8a33af99-464b-4f0b-ae78-95c9a304244d","originalAuthorName":"毛雪英"},{"authorName":"柴之芳","id":"e29ccd6a-9a0d-4876-99ff-d11cf0ec042b","originalAuthorName":"柴之芳"}],"doi":"10.3969/j.issn.1004-0676.2001.03.001","fpage":"1","id":"7aa59512-08c4-47f8-b2e7-e26419ba7787","issue":"3","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"dfe0d3ea-60b8-4a82-b2fa-3aa8de8d3bc5","keyword":"<span style=\"color:red\">铱</span>(Ⅳ)<span style=\"color:red\">氯水</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"铱(Ⅳ)氯水配合物"},{"id":"1c6eff64-9015-4b19-b219-02a7beaf6120","keyword":"萃取行为","originalKeyword":"萃取行为"}],"language":"zh","publisherId":"gjs200103001","title":"盐酸溶液中<span style=\"color:red\">铱</span>(Ⅳ)<span style=\"color:red\">氯水</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的萃取行为研究","volume":"22","year":"2001"},{"abstractinfo":"研究了TBP、50%TAPO-煤油溶液在HCl介质中对<span style=\"color:red\">铱</span>(Ⅲ)<span style=\"color:red\">氯水</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的萃<span style=\"color:red\">物</span>行为.结果表明:当[HCl]＜3mol/L时,<span style=\"color:red\">铱</span>(Ⅲ)<span style=\"color:red\">氯水</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>在一定程度上被50% TAPO-煤油溶液萃取,且随着HCl浓度的增加,其萃取率降低;当[HCl]＞3mol/L时,其萃取率均很低,几乎不被萃取.通过对萃取后的水相、有机相紫外-可见光谱和红外光谱的表征,研究了它们的萃取机理.","authors":[{"authorName":"陈丁文","id":"639afe19-ab67-40e9-b9a4-d60e65cbce15","originalAuthorName":"陈丁文"},{"authorName":"董守安","id":"4d88fb8c-8636-42a8-ba4a-e9f30c7596c6","originalAuthorName":"董守安"},{"authorName":"李楷中","id":"ec7d5fdd-8e96-4c5c-8f89-8d7fe4e4b1ce","originalAuthorName":"李楷中"},{"authorName":"顾永万","id":"a2497a2c-04f1-44db-85c8-2f7f2f19a69d","originalAuthorName":"顾永万"},{"authorName":"毛雪英","id":"8b49c8ab-7f86-4e68-93ae-8e8a9a8db692","originalAuthorName":"毛雪英"},{"authorName":"柴之芳","id":"66b0d29c-dd6d-4f14-a5b7-1d9f9fb53dc7","originalAuthorName":"柴之芳"}],"doi":"10.3969/j.issn.1004-0676.2001.04.005","fpage":"23","id":"78618338-ed12-43c5-925e-732521ac572e","issue":"4","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"2ced77a0-79c1-414f-ae69-7a8c459ae102","keyword":"<span style=\"color:red\">铱</span>(Ⅲ)<span style=\"color:red\">氯水</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"铱(Ⅲ)氯水配合物"},{"id":"c18f614f-a88d-4f5e-8f27-a204d3c35f97","keyword":"萃取行为","originalKeyword":"萃取行为"}],"language":"zh","publisherId":"gjs200104005","title":"盐酸溶液中<span style=\"color:red\">铱</span>(Ⅲ)<span style=\"color:red\">氯水</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的萃取行为","volume":"22","year":"2001"},{"abstractinfo":"利用循环伏安法对Ir(Ⅲ)、Ir(Ⅳ)<span style=\"color:red\">氯水</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的电化学行为进行探索性研究.结果表明:随着<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>中水分子的增加,Ir(Ⅲ)、Ir(Ⅳ)<span style=\"color:red\">氯水</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>电对的式电位增大;Ir(Ⅲ)、Ir(Ⅳ)<span style=\"color:red\">氯水</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的氧化还原反应属于可逆反应或准可逆反应;峰电流ip与各物种浓度c之间存在较好的线性关系.","authors":[{"authorName":"陈丁文","id":"00db4eb0-bf75-44a1-aad5-499f3523bff0","originalAuthorName":"陈丁文"},{"authorName":"李斌","id":"d3d0962c-9de2-4ac0-87b9-8f7f2f598cb9","originalAuthorName":"李斌"},{"authorName":"董守安","id":"86e670eb-7158-43b3-9472-4efb1ff34134","originalAuthorName":"董守安"},{"authorName":"蒋明忠","id":"6239e64a-adb2-4157-8364-9545724a6a16","originalAuthorName":"蒋明忠"}],"doi":"10.3969/j.issn.1004-0676.2009.01.001","fpage":"1","id":"92ab59e4-3356-4db3-b1ce-4fbccfefea8a","issue":"1","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"e7b09d85-05eb-45ca-b749-5154fac641bd","keyword":"物理化学","originalKeyword":"物理化学"},{"id":"d7408d4e-3ed1-4cdd-956c-68b47ca68a7f","keyword":"循环伏安法","originalKeyword":"循环伏安法"},{"id":"a1b1ceca-b5c0-4dbf-a29e-5ba22daa3f1d","keyword":"Ir(Ⅲ)、Ir(Ⅳ)","originalKeyword":"Ir(Ⅲ)、Ir(Ⅳ)"},{"id":"749308f4-558e-42a7-9c1e-9d23e69fe469","keyword":"<span style=\"color:red\">氯水</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"氯水配合物"},{"id":"49c45772-953f-4bec-aa8c-c35d122c7e03","keyword":"电化学行为","originalKeyword":"电化学行为"}],"language":"zh","publisherId":"gjs200901001","title":"利用循环伏安法对<span style=\"color:red\">铱</span>(Ⅲ)、<span style=\"color:red\">铱</span>(Ⅳ)<span style=\"color:red\">氯水</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的电化学行为研究","volume":"30","year":"2009"},{"abstractinfo":"采用封管氯化的方法[1],制得铑的标准溶液.在一定条件下处理H3[RhCl6]溶液,获得K2[Rh(H2O)Cl5]、K3[RhCl6]和[Rh(H2O)6]@(ClO4)3种态.以K2[Rh(H2O)Cl5]和K3[RhCl6]为起始<span style=\"color:red\">物</span>,利用国产717阴离子树脂,分别得到trans-[Ph(H2O)4Cl2]+、cis-[Rh(H2O)4Cl2]+、mer-[Rh(H2O)3Cl3]、fac-Rh(H2O)3Cl3]和cis-[Rh(H2O)4Cl4]-种态.研究它们的紫外-可见吸收光谱发现,随着配位内界水分子数的增加,其特征吸收峰表现为紫移.通过分析和研究它们的极性及特性吸收峰,提出了铑(Ⅲ)<span style=\"color:red\">氯水</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>新的鉴别方法.","authors":[{"authorName":"顾永万","id":"8bee41d8-52d6-48e3-93f4-92cf295fb841","originalAuthorName":"顾永万"},{"authorName":"董守安","id":"757a969c-5ce6-442c-aac4-babba1e27ee3","originalAuthorName":"董守安"},{"authorName":"王仕兴","id":"f83f1971-e485-4284-ae9b-b366b8f0a27a","originalAuthorName":"王仕兴"},{"authorName":"李楷中","id":"147fae0d-7c2b-4958-817b-00f2bb3f69e2","originalAuthorName":"李楷中"},{"authorName":"吴刚","id":"e600e033-646c-48f9-bcf6-7261b2133d8a","originalAuthorName":"吴刚"},{"authorName":"张慧颖","id":"5c21bf6b-f66e-4838-9aa4-21f22a5c9078","originalAuthorName":"张慧颖"}],"doi":"10.3969/j.issn.1004-0676.2003.02.003","fpage":"11","id":"1eb16ba6-7531-490d-971d-ef2c6880dbba","issue":"2","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"247afabf-4dcb-473a-80e3-c3cfa6be434f","keyword":"配位化学","originalKeyword":"配位化学"},{"id":"ce351f16-d3ac-4db8-8ab1-3e6d45b24e05","keyword":"铑(Ⅲ)<span style=\"color:red\">氯水</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"铑(Ⅲ)氯水配合物"},{"id":"394223db-fb7e-45a6-9fda-98bb55de8caa","keyword":"制备","originalKeyword":"制备"},{"id":"85083a02-665a-4ad7-a7c7-bdfa4160c5a0","keyword":"分光光度法","originalKeyword":"分光光度法"}],"language":"zh","publisherId":"gjs200302003","title":"铑(Ⅲ)<span style=\"color:red\">氯水</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的制备及紫外可见光谱的研究","volume":"24","year":"2003"},{"abstractinfo":"作者详细研究了各铑(III)<span style=\"color:red\">氯水</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>在水溶液中随时间、温度变化而变化的规律,获得的结果表明,Cl-浓度是影响铑(III)在各种态中分布的主要因数,但是,对于阴离子种态,其放置的时间和温度也是不可忽略的.对于下面这个短的平衡反应链:fac-[RhCl3(H2O)3]cis-[RhCl4(H2O)2]-[RhCl5(H2O)]2-[RhCl6]3-作者系统的研究了在不同温度下其各种态的分布,结果发现fac-[RhCl3(H2O)3]的含量随温度的升高而增加,而cis-[RhCl4(H2O)2]-、[RhCl5(H2O)]2-和[RhCl6]3-却随温度的升高而降低.氯代和水合作为铑(III)<span style=\"color:red\">氯水</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>在溶液中的竞争反应,在放置开始,氯代占优势,但随时间的延长,水合逐渐趋于优势.","authors":[{"authorName":"顾永万","id":"0a558f63-a5d5-4e98-82c3-d98f38dc8de9","originalAuthorName":"顾永万"},{"authorName":"董守安","id":"b5556daa-7afb-4086-ba27-5231afccbe35","originalAuthorName":"董守安"},{"authorName":"罗一江","id":"21d192fc-0dfc-41d6-865f-77da0bb45104","originalAuthorName":"罗一江"},{"authorName":"王仕兴","id":"6d84f924-62e1-45a9-b75c-fa953379f860","originalAuthorName":"王仕兴"},{"authorName":"段德良","id":"4fa8d4e7-1abd-4eec-a97d-162cc0d44863","originalAuthorName":"段德良"}],"doi":"10.3969/j.issn.1004-0676.2004.01.003","fpage":"11","id":"4a26e075-c41c-46dd-9f8e-1f212b7b7b07","issue":"1","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"64f56b65-368c-4d30-9601-a7b217f7d7db","keyword":"物理化学","originalKeyword":"物理化学"},{"id":"e2548289-e8f1-40d6-9223-7d72e1908982","keyword":"铑(III)<span style=\"color:red\">氯水</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"铑(III)氯水配合物"},{"id":"d27eb6aa-86be-46d8-b525-37c9d9c2124e","keyword":"动力学","originalKeyword":"动力学"},{"id":"b0f74334-7525-4ce9-ba2c-a6cffac2e48d","keyword":"热力学","originalKeyword":"热力学"}],"language":"zh","publisherId":"gjs200401003","title":"铑(Ⅲ)<span style=\"color:red\">氯水</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>在水溶液中的热力学和动力学平衡行为研究","volume":"25","year":"2004"},{"abstractinfo":"以氯<span style=\"color:red\">铱</span>酸和乙酰丙酮为原料,通过水溶液沉淀法制备乙酰丙酮<span style=\"color:red\">铱</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>,通过苯-己烷体系对乙酰丙酮<span style=\"color:red\">铱</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>进行重结晶提纯.元素分析确定乙酰丙酮<span style=\"color:red\">铱</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>结构中的碳氢含量.红外光谱结果表明,1549,1523 cm-1处出现的吸收峰为乙酰丙酮<span style=\"color:red\">铱</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>中六元环结构中C-O键和C-C键的伸缩振动吸收蜂.核磁共振氢谱分析表明<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>中的氢的化学位移的位置和个数比与结构中的分子式相一致.根据对乙酰丙酮<span style=\"color:red\">铱</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的质谱结果进行分析,提出乙酰丙酮<span style=\"color:red\">铱</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>可能的热分解机制.","authors":[{"authorName":"阎鑫","id":"7f666358-53b5-404f-a091-58c9d22f9643","originalAuthorName":"阎鑫"},{"authorName":"张秋禹","id":"8d0b55b1-d7ec-4909-9948-afba015fef5d","originalAuthorName":"张秋禹"}],"doi":"10.3969/j.issn.0258-7076.2010.04.021","fpage":"585","id":"0811253b-fdbd-4888-99a8-c7bbef35ce95","issue":"4","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"c9f70ccd-2798-48ee-a6e0-193aade53ea2","keyword":"<span style=\"color:red\">铱</span>","originalKeyword":"铱"},{"id":"0ed3b391-30a8-4380-8bd6-a982a4b6c7d3","keyword":"乙酰丙酮","originalKeyword":"乙酰丙酮"},{"id":"31837f71-8cd9-40ed-8277-00b733bb6bda","keyword":"合成","originalKeyword":"合成"},{"id":"14d39c7d-790d-4522-a906-0d67b5992d05","keyword":"热分解机制","originalKeyword":"热分解机制"}],"language":"zh","publisherId":"xyjs201004021","title":"乙酰丙酮<span style=\"color:red\">铱</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的合成及热分解机制研究","volume":"34","year":"2010"},{"abstractinfo":"采用微波辐射加热方法,将2,3-二苯基喹喔啉(DPQ)与水合三氯化<span style=\"color:red\">铱</span>(IrCl3·H2O)反应,合成了一种新型三环喹喔啉<span style=\"color:red\">铱</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>[Ir(DPQ)3],通过元素分析、1H NMR和质谱方法对<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>结构进行了表征,并初步研究了<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的吸收光谱和荧光光谱. 结果表明,<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>Ir(DPQ)3在387和458 nm处存在单线态1MLCT和三线态3MLCT(金属到配体的电荷跃迁)的吸收;在634 nm处有较强的金属<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>三线态的磷光发射.","authors":[{"authorName":"吴秋华","id":"81dc4955-f528-4c13-b2fe-4d824ecb4f50","originalAuthorName":"吴秋华"},{"authorName":"王传红","id":"92c902bf-a8d1-45b7-8729-cd0802855b88","originalAuthorName":"王传红"},{"authorName":"宋溪明","id":"8c08ddf4-3454-4cc2-b5b7-91f10c13616a","originalAuthorName":"宋溪明"},{"authorName":"吴抒遥","id":"e878ee01-7972-4078-8527-d35a6320fa82","originalAuthorName":"吴抒遥"},{"authorName":"姜玉春","id":"1f04b3fe-1aca-40fe-b92a-7a84a60594fb","originalAuthorName":"姜玉春"},{"authorName":"张国林","id":"28c465b2-0532-4283-b5ff-062398182259","originalAuthorName":"张国林"}],"doi":"10.3969/j.issn.1000-0518.2009.07.027","fpage":"863","id":"4aacda90-3145-44f3-9d8d-2ab55a82e324","issue":"7","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"31d09b9d-b712-46e1-9aa4-49767d6858d7","keyword":"磷光材料","originalKeyword":"磷光材料"},{"id":"c6077970-09ea-4765-9373-d6df5b0548e1","keyword":"喹喔啉<span style=\"color:red\">铱</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"喹喔啉铱配合物"},{"id":"c3b04e25-65c5-44c7-a90a-623736ff8854","keyword":"三线态","originalKeyword":"三线态"},{"id":"c96a29bd-48c0-4caf-8b98-fc8081f25212","keyword":"微波合成","originalKeyword":"微波合成"}],"language":"zh","publisherId":"yyhx200907027","title":"微波辐射法合成喹喔啉<span style=\"color:red\">铱</span>(Ⅲ)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>及其发光性质","volume":"26","year":"2009"},{"abstractinfo":"采用分步溶液法,在碱性条件下合成出了3,5-二<span style=\"color:red\">氯水</span>杨醛缩异亮氨酸邻菲啰啉铜(Ⅱ)三元<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>,并培养出[Cu3L3(Phen)3].5H2O单晶(其中H2L=3,5-二<span style=\"color:red\">氯水</span>杨醛席夫碱缩异亮氨酸),其晶体结构经元素分析,红外光谱及X射线单晶衍射表征.","authors":[{"authorName":"刘峥","id":"14d5315e-6753-4958-95e2-a92cd5da039a","originalAuthorName":"刘峥"},{"authorName":"夏金虹","id":"5f0872f2-28f3-45bb-8b54-1926fecde8c0","originalAuthorName":"夏金虹"},{"authorName":"王永燎","id":"59a89acf-9aef-4777-a58d-1b8a1b192023","originalAuthorName":"王永燎"},{"authorName":"韦春","id":"1d441e6e-e120-4235-a199-ce6f6395ddf3","originalAuthorName":"韦春"}],"doi":"","fpage":"1542","id":"34046864-9abb-48f0-9999-eb1f4ce8ad5a","issue":"6","journal":{"abbrevTitle":"RGJTXB","coverImgSrc":"journal/img/cover/RGJTXB.jpg","id":"57","issnPpub":"1000-985X","publisherId":"RGJTXB","title":"人工晶体学报"},"keywords":[{"id":"26ab6da0-d198-4b30-af9e-2dd000be43e6","keyword":"氨基酸席夫碱","originalKeyword":"氨基酸席夫碱"},{"id":"44a54302-fd6d-4a6e-911e-54fa498b8c3e","keyword":"合成","originalKeyword":"合成"},{"id":"347ff975-21ab-4770-9a78-987eda1ddbeb","keyword":"晶体结构","originalKeyword":"晶体结构"}],"language":"zh","publisherId":"rgjtxb98200806048","title":"3,5-二<span style=\"color:red\">氯水</span>杨醛缩异亮氨酸邻菲啰啉铜(Ⅱ)三元<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的合成与晶体结构表征","volume":"37","year":"2008"},{"abstractinfo":"基于一种氟代的配体2-(4'-氟苯基)-1-苯基-苯并咪唑,在高温(＞200℃)条件下直接合成了经式绿光<span style=\"color:red\">铱</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>mer-Ir(FPBI)3,并通过1 H NMR和单晶X射线衍射分析确定了其经式构型.不同于以前报道的具有经式构型的<span style=\"color:red\">铱</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>(＜0.1),mer-Ir (FPBI)3在甲苯溶液中的光致发光量子效率高达0.46.应用该<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>制备了高效磷光有机电致发光器件,最大电流效率和外量子效率分别为38.5 cd/A和11.8％,色坐标为(0.29,0.58).","authors":[{"authorName":"吕剑虹","id":"43dd4aa7-ee59-47db-85ef-832a23e6d84a","originalAuthorName":"吕剑虹"},{"authorName":"马志华","id":"85ce470f-dca0-4ab9-bfb6-0ae73467ed94","originalAuthorName":"马志华"},{"authorName":"丁军桥","id":"44d3fbda-1637-4c78-b62f-f38691eb948f","originalAuthorName":"丁军桥"},{"authorName":"王利祥","id":"bc7ab439-5f88-4785-931a-7d84f1a8179f","originalAuthorName":"王利祥"}],"doi":"10.3724/SP.J.1095.2014.40050","fpage":"1177","id":"e5085ce6-16f2-4028-ae84-2772151f0262","issue":"10","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"a71e5f8e-ec9e-4568-ba7a-cdedd11162fb","keyword":"经式构型","originalKeyword":"经式构型"},{"id":"b2312545-ebff-42d9-9b2a-184aa92e89f1","keyword":"<span style=\"color:red\">铱</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"铱配合物"},{"id":"db629583-140a-4742-b86b-68ff74dcecc2","keyword":"光致发光量子效率","originalKeyword":"光致发光量子效率"},{"id":"dd2796b2-3470-43e5-beb1-7a22f34749be","keyword":"磷光有机电致发光器件","originalKeyword":"磷光有机电致发光器件"}],"language":"zh","publisherId":"yyhx201410009","title":"基于氟代苯并咪唑配体的绿光<span style=\"color:red\">铱</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的合成与表征","volume":"31","year":"2014"},{"abstractinfo":"设计合成了一种双核环金属<span style=\"color:red\">铱</span>，铂<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>二[ N，N-2-（2，4-二氟苯基吡啶） C3，N1]（吡啶甲酸）合<span style=\"color:red\">铱</span>（Ⅲ）-C6-[苯基吡啶-C3，N1]（吡啶甲酸）合铂（Ⅱ）（FIrPPyPt）。通过核磁共振仪、元素分析仪、紫外-可见吸收光谱仪和光致发光光谱仪对其结构和性能进行了表征。结果表明，<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>FIrPPyPt的紫外-可见吸收位于250～450 nm之间，荧光发射峰位于465和493 nm。将<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>FIrPPyPt以质量分数1％～8％掺杂到主体材料聚乙烯基咔唑（PVK）＋2-（联苯-4-芳基）-5-（4-叔丁基苯）-1，3，4-噁二唑（PBD）（30％）中制作了电致发光器件，在不同电压下电致发光光谱中，显现出<span style=\"color:red\">铱</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>和铂<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的特征峰，波峰位于400、500和530 nm蓝绿光区发射区。该双核<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>用于单掺杂有机白光电致发光器件具有制作简单、色稳定性和重复性好等特点，为单掺杂白光发光器件提供了一种好的思路。","authors":[{"authorName":"胡峥勇","id":"207953eb-e23e-422a-810a-5be541653955","originalAuthorName":"胡峥勇"},{"authorName":"李善佳","id":"0756d87b-c72e-4f56-901c-1837816009a6","originalAuthorName":"李善佳"},{"authorName":"董新荣","id":"8d1a6442-bf8a-4a6e-9125-289e78b4c119","originalAuthorName":"董新荣"}],"doi":"10.11944/j.issn.1000-0518.2016.12.160119","fpage":"1428","id":"646325b2-7eab-4414-a569-6bb559a01ad9","issue":"12","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"4f58f013-ba9a-4d40-b313-2359f17a4538","keyword":"<span style=\"color:red\">铱</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"铱配合物"},{"id":"c8bd24ee-97b0-4050-b5d4-9d9407d351e2","keyword":"铂<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"铂配合物"},{"id":"2b5376e3-0dbc-496b-9042-8e3417430a3c","keyword":"有机电致发光器件","originalKeyword":"有机电致发光器件"}],"language":"zh","publisherId":"yyhx201612012","title":"一种环金属<span style=\"color:red\">铱</span>、铂双核<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的合成及光电性能","volume":"33","year":"2016"}],"totalpage":3974,"totalrecord":39737}