Tingxi LI
,
Long FU
,
Wenwen YU
,
Renhe HUANG
材料科学技术（英文）
Novel pyridine-containing macrocyclic compounds, such as 6,12,19,25-tetramethyl-7,11,20,24-dinitrilo-dibenzo[b,m]1,4,12,15-tetra-azacyclodoc osine (TMCD), were synthesized and used as electron transport layer in organic electroluminescent devices. Devices with a structure of glass/indium-tin oxide/arylamine derivative/tris(quinolinolato)aluminum(III) (Alq)/TMCD/LiF/Al exhibited green emission from the Alq layer with external quantum efficiency of 0.84% and luminous efficiency of 1.3 lm/W. The derivatives of TMCD were synthesized and characterized as well. These compounds were also found to be useful as the electron-transporting materials in organic electroluminescent devices.
关键词:
Pyridine-containing macrocyclic compound
,
有机电致发光
,
电子传输材
万小峰
,
张久兴
,
周文元
,
李湘波
,
周美玲
稀有金属材料与工程
研究了FU105大功率广播发射管用碳化镧钼阴极,参照碳化钍钨阴极FU105管的制备工艺,实现了镧钼阴极的碳化以及镧钼阴极FU105管的排气和老炼.通过镧钼阴极FU105管的性能测试,对碳化镧钼阴极的发射能力和稳定性进行了分析.结果认为:FU105管碳化镧钼阴极的发射能力可以达到碳化钍钨阴极的水平,但其稳定性还有待改进.
关键词:
镧钼阴极
,
FU105发射管
,
碳化
,
稀土
钟文远
,
崔永春
,
范春兰
,
胡智兴
,
李玛琳
贵金属
doi:10.3969/j.issn.1004-0676.2004.02.005
为寻求高效低毒的新型顺铂类抗肿瘤药物,用K2PtCl4、乙二胺(en)、氟尿嘧啶(5-Fu)为原料,设计合成了顺铂类似物[pt(en)(5-Fu)2]C12配合物,由元素分析、红外光谱和质谱分析初步证实了其化学结构,用改良MTT、SRB法,选用K562、A549、Bel-7402、BIU-87、Bcap-37细胞株对其进行体外抗肿瘤活性测定.结果表明,所合成的配合物除在浓度为0.01、0.1 μg/mL时对K562细胞株抗肿瘤活性大于顺铂和氟尿嘧啶外,其它情况下的抗肿瘤活性均小于顺铂和氟尿嘧啶.该配合物仍有进一步研究的价值.
关键词:
药学
,
铂(Ⅱ)配合物
,
合成
,
抗肿瘤活性
Physical Review B
Longitudinal electron transport is investigated for a long-period semiconductor superlattice in the presence of a magnetic field applied along the growth direction of the superlattice. It is shown that the longitudinal magnetoresistance exhibits a complicated dependence on the magnetic-field strength. In contrast with the conventional Shubnikov-de Haas oscillations, the magnetoresistance shows periodic oscillations only in the region of low reciprocal magnetic field.
关键词:
magnetoresistance
F.M.Chu David P.Pope Dept.of Materials Science and Engineering
,
University of Pennsylvania
,
Philadelphia
,
PA 19104
,
USA
材料科学技术（英文）
In this paper the geometric description and general theory of mechanical twinning are reviewed, the twins in general lattices and superlattices are summarized, and the kinetic process by which mechanical twins form is revisited. A case study of mechanical twinning of HfV2+Nb, (cubic) Laves phase, is presented and the synchroshear of selected atomic layers is proposed to explain the physical process of twin formation. If the twins form in this way, then long shear vectors and / or atomicshuffles are not really necessary.
关键词:
twin
,
null
,
null
,
null
J.M. Gong
,
S.T. Tu
,
J. Xia and X. Ling (School of Mechanical Engineering
,
Nanjing University of Chemical Technology
,
Nanjing 210009
,
China)
金属学报(英文版)
Creep deformation localization is generally found in structures at high temperamture,typically in weldments. As the heat affected zone (HAZ) in a weldment is very narrow, deformation in HAZ region can hardly be measured by conventional displacement gauge. A new method for measuring long-term local creep deformation was developed by quartz optical fiber and technique of digital image analysis. The creep deformations of base metal, weld metal and HAZ in weldments are thereby determined with crossweld specimens.
关键词:
creep deformation
,
null
,
null
,
null
材料科学技术（英文）
A new type of long periodic structure has been found in ZrO2-Y2O3 ceramics in annealed states. High resolution electron microscopy (HREM), selected area electron diffraction, and computer simulation have been used to reveal the presence of the long periodic structure. The unit cell of the long periodic structure consists of a cubic ZrO2 unit cell and L1(0)- like phase one.
关键词:
ceramics;electron diffraction;electron microscopy;crystal structure;microstructure
Jiancun RAO
,
Yu ZHOU
,
Douxing LI
材料科学技术（英文）
A new type of long periodic structure has been found in ZrO2-Y2O3 ceramics in annealed states. High resolution electron microscopy (HREM), selected area electron diffraction, and computer simulation have been used to reveal the presence of the long periodic structure. The unit cell of the long periodic structure consists of a cubic ZrO2 unit cell and L10- like phase one.
关键词:
Ceramics
,
null
,
null
,
null
,
null
Applied Physics Letters
The dipole configuration of relaxor ferroelectrics (RFs) is investigated by numerically solving the time-dependent Ginzburg-Landau equation based on the dipole defect model. The domain structure of RFs is revealed to consist of dipole ordered clusters embedded in the paraelectric matrix. We demonstrate that the role of long-range elastic energy in RFs is much less important than in normal ferroelectrics, although the shape of the dipole clusters depends on the elastic energy. Based on the numerical results, a phase diagram of temperature-defect density for RFs is constructed, which identifies four distinct phase regimes. (c) 2006 American Institute of Physics.
关键词:
monte-carlo-simulation;dielectric-properties;computer-simulation;domain formation;defects;field;model;glass
